[ CAS No. 14040-11-0 ] {[proInfo.proName]}

Name: 14040-11-0|Tungsten hexacarbonyl|98%
Brand: Ambeed
SKU: A346359
Rating: 91 (35 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type	HazMat fee for 500 gram (Estimated)
Excepted Quantity	USD 0.00
Limited Quantity	USD 15-60
Inaccessible (Haz class 6.1), Domestic	USD 80+
Inaccessible (Haz class 6.1), International	USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic	USD 100+
Accessible (Haz class 3, 4, 5 or 8), International	USD 200+

2D 3D

Structure of 14040-11-0 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 14040-11-0 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 14040-11-0 ]

SDS Specification

Alternatived Products of [ 14040-11-0 ]

Product Details of [ 14040-11-0 ]

CAS No. :	14040-11-0	MDL No. :	MFCD00011462
Formula :	C₆O₆W	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	351.90	Pubchem ID :	-
Synonyms :

Safety of [ 14040-11-0 ]

Signal Word:	Danger	Class:	6.1
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P310-P302+P352-P304+P340-P311-P330-P361-P363-P403+P233-P405-P501	UN#:	3466
Hazard Statements:	H301+H311+H331	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 14040-11-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 14040-11-0 ]

[ 14040-11-0 ] Synthesis Path-Downstream 1~88

1
[ 14040-11-0 ]
[ 2071-20-7 ]
[ 41830-14-2 ]

Yield	Reaction Conditions	Operation in experiment
91%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.

Reference： [1]Inorganic Chemistry,1987,vol. 26,p. 3727 - 3732
[2]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71
[3]Organometallics,2004,vol. 23,p. 5219 - 5225
[4]Journal of Organometallic Chemistry,2004,vol. 689,p. 2429 - 2435
[5]Organometallics,2000,vol. 19,p. 2397 - 2399
[6]Organometallics,2000,vol. 19,p. 2397 - 2399
[7]Organometallics,1992,vol. 11,p. 1033 - 1043

2
[ 273-09-6 ]
[ 14040-11-0 ]
[ 97774-99-7 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,
Zeitschrift fuer Anorganische und Allgemeine Chemie,1989,vol. 575,p. 97 - 114

3
[ 273-09-6 ]
[ 14040-11-0 ]
[ 82918-16-9 ]

Reference： [1]Journal of Organometallic Chemistry,1984,vol. 264,p. 317 - 326

4
[ 273-09-6 ]
[ 14040-11-0 ]
[ 107990-26-1 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,
Zeitschrift fuer Anorganische und Allgemeine Chemie,1989,vol. 575,p. 97 - 114

5
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 75-05-8 ]
[ 15228-32-7 ]
[ 15096-68-1 ]

Reference： [1]Inorganic Chemistry,1990,vol. 29,p. 713 - 722

6
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 75-05-8 ]
[ 15096-68-1 ]

Reference： [1]Organometallics,1990,vol. 9,p. 793 - 798

7
[ 14040-11-0 ]
[ 6737-42-4 ]
[ 50860-43-0 ]

Yield	Reaction Conditions	Operation in experiment
94%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.

Reference： [1]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71
[2]Organometallics,2004,vol. 23,p. 5219 - 5225
[3]Organometallics,1992,vol. 11,p. 1033 - 1043

8
[ 14040-11-0 ]
[ 1179-06-2 ]
[ 126830-40-8 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,
Zeitschrift fuer Anorganische und Allgemeine Chemie,1989,vol. 579,p. 47 - 56

9
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 2071-20-7 ]
[ 41830-14-2 ]

Reference： [1]Inorganica Chimica Acta,1988,vol. 143,p. 3 - 6

10
[ 66-71-7 ]
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 14729-20-5 ]

Reference： [1]Inorganica Chimica Acta,1987,vol. 128,p. L3 - L4

11
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 15444-65-2 ]

Reference： [1]Inorganica Chimica Acta,1988,vol. 143,p. 3 - 6

12
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 14586-49-3 ]

Reference： [1]Inorganica Chimica Acta,1988,vol. 143,p. 3 - 6

13
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 1135-32-6 ]
1,2-bis(4-pyridyl)ethylene ditungsten decacarbonyl [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1988,vol. 143,p. 3 - 6

14
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 603-35-0 ]
[ 15444-65-2 ]

Reference： [1]Thermochimica Acta,1988,vol. 128,p. 175 - 184

15
[ 14040-11-0 ]
[ 56-34-8 ]
[ 14780-97-3 ]

Yield	Reaction Conditions	Operation in experiment
	In diethylene glycol dimethyl ether; at 120℃;	General procedure: Tetraethyl ammonium chloride (0.5 g) was heated with anexcess (1 g) of M(CO)6 (M = Cr, Mo, W) in diethylene glycol ether at 120 C until the steady evolution of carbon monoxide ceased. The mixture was filtered hot under an atmosphere of nitrogen. Adding light petroleum to the cooled filtrate gave yellow crystals of the product. After removal of the excessive solvent by decantation, the crystals were rapidly washed with light petroleum, and the excess of solvent was removed at reduced pressure.

Reference： [1]Journal of Organometallic Chemistry,1980,vol. 190,p. 177 - 186
[2]European Journal of Medicinal Chemistry,2014,vol. 74,p. 199 - 215
[3]Applied Organometallic Chemistry,2014,vol. 28,p. 169 - 179
[4]Chinese Journal of Chemistry,2015,vol. 33,p. 739 - 748

16
[ 14040-11-0 ]
[ 2426-94-0 ]
[ 96211-91-5 ]

Reference： [1]Journal of the American Chemical Society,1986,vol. 108,p. 3578 - 3586

17
[ 14040-11-0 ]
[ 2426-94-0 ]
[ 96211-96-0 ]

Reference： [1]Journal of the American Chemical Society,1986,vol. 108,p. 3578 - 3586

18
[ 2044-08-8 ]
[ 14040-11-0 ]
(CH((CH₂)4)C(OCH₃))tungsten(carbonyl)5 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1990,vol. 112,p. 3642 - 3659

19
[ 14040-11-0 ]
[ 1618-26-4 ]
[ 84062-77-1 ]

Reference： [1]Journal of Organometallic Chemistry,1992,vol. 437,p. 191 - 199
[2]Journal of the Chemical Society, Dalton Transactions,1988,p. 1489 - 1492

20
[ 4199-89-7 ]
[ 14040-11-0 ]
[ 59136-53-7 ]
[ 201230-82-2 ]

Reference： [1]Journal of Physical Chemistry,1988,vol. 92,p. 2219 - 2223

21
[ 4199-89-7 ]
[ 14040-11-0 ]
[ 59136-53-7 ]

Reference： [1]Inorganic Chemistry,1986,vol. 25,p. 1354 - 1359
[2]Inorganic Chemistry,1986,vol. 25,p. 672 - 677

22
[ 14040-11-0 ]
[ 84494-89-3 ]
[ 84534-91-8 ]

Reference： [1]Inorganica Chimica Acta,1986,vol. 122,p. 207 - 212
[2]Journal of the Chemical Society, Dalton Transactions,1982,p. 2353 - 2358

23
[ 14040-11-0 ]
[ 62637-93-8 ]
[ 2071-20-7 ]
[ 35324-78-8 ]

Reference： [1]Journal of Thermal Analysis,1987,vol. 32,p. 1115 - 1126
[2]Inorganic Chemistry,1993,vol. 32,p. 2421 - 2425

24
[ 12150-46-8 ]
[ 14040-11-0 ]
[ 62637-93-8 ]
W(CO)4(1,1'-bis(diphenylphosphino)ferrocene) [ No CAS ]
W₂(CO)10(1,1'-bis(diphenylphosphino)ferrocene)*0.33hexane [ No CAS ]
W(CO)5(1,1'-bis(diphenylphosphino)ferrocene) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 373,p. 319 - 324

25
[ 12150-46-8 ]
[ 14040-11-0 ]
[ 62637-93-8 ]
W(CO)4(1,1'-bis(diphenylphosphino)ferrocene) [ No CAS ]
W(CO)5(1,1'-bis(diphenylphosphino)ferrocene) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 373,p. 319 - 324
[2]Journal of Organometallic Chemistry,1989,vol. 373,p. 319 - 324

26
[ 322-46-3 ]
[ 14040-11-0 ]
[ 107990-32-9 ]
[ 107990-23-8 ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 369,p. 83 - 104

27
[ 322-46-3 ]
[ 14040-11-0 ]
[ 122780-32-9 ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 369,p. 83 - 104

28
[ 14040-11-0 ]
[ 7688-25-7 ]
[ 54111-75-0 ]

Yield	Reaction Conditions	Operation in experiment
75%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2?4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled ?10 °C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95percent yield.

Reference： [1]Organometallics,2004,vol. 23,p. 5219 - 5225
[2]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71
[3]Organometallics,1992,vol. 11,p. 1033 - 1043
[4]Acta Crystallographica, Section C: Crystal Structure Communications,1992,vol. 48,p. 988 - 991

29
[ 14040-11-0 ]
[ 19845-69-3 ]
[ 120950-74-5 ]

Reference： [1]Inorganica Chimica Acta,1989,vol. 158,p. 5 - 6

30
[ 14040-11-0 ]
[ 27721-02-4 ]
[ 122991-86-0 ]

Reference： [1]Organometallics,1992,vol. 11,p. 1033 - 1043

31
[ 14040-11-0 ]
[ 27721-02-4 ]
[ 120950-73-4 ]

Reference： [1]Inorganica Chimica Acta,1989,vol. 158,p. 5 - 6

32
[ 14040-11-0 ]
(η1-1,1'-bis(diphenylphosphino)ferrocene)Fe(CO)4 [ No CAS ]
[ 62637-93-8 ]
(CO)4Fe(μ-1,1'-bis(diphenylphosphino)ferrocene)W(CO)5 [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1990,vol. 390,p. 345 - 350

33
[ 14040-11-0 ]
[ 557-93-7 ]
[ 64-20-0 ]
[ 132698-96-5 ]

Reference： [1]Organometallics,1991,vol. 10,p. 737 - 746

34
[ 14040-11-0 ]
[ 136-93-6 ]
[ 62637-93-8 ]
2(W(S₂CN(C₂H₅)2)4)⁽¹⁺⁾*(W₆O₁₉)^(2-)=(W(S₂CN(C₂H₅)2)4)2(W₆O₁₉) [ No CAS ]

Reference： [1]Polyhedron,1992,vol. 11,p. 1959 - 1964

35
[ 14040-11-0 ]
[ 136-92-5 ]
[ 62637-93-8 ]
2(W(S₂CN(C₂H₅)2)4)⁽¹⁺⁾*(W₆O₁₉)^(2-)=(W(S₂CN(C₂H₅)2)4)2(W₆O₁₉) [ No CAS ]
WSe₂(S₂CN(C₂H₅)2)3*0.5H₂O [ No CAS ]

Reference： [1]Polyhedron,1992,vol. 11,p. 1959 - 1964

36
[ 4434-13-3 ]
[ 14040-11-0 ]
[ 96412-31-6 ]
[ 96412-29-2 ]
[ 96427-24-6 ]
[ 96412-28-1 ]
[ 96427-17-7 ]

Reference： [1]Inorganic Chemistry,1985,vol. 24,p. 1997 - 2003

37
[ 14040-11-0 ]
[ 96556-05-7 ]
[ 98838-67-6 ]

Yield	Reaction Conditions	Operation in experiment
65%	In 1,3,5-trimethyl-benzene; for 2h;Reflux; Inert atmosphere; Schlenk technique;	General procedure: 1a was prepared by a modification of the literature method [20,21]. [W(CO)6] (1.5g, 4.3mmol) and Me3tacn (950mg, 5.5mmol) were refluxed in mesitylene (25mL) for 2h under micro-negative pressure, and the reaction was accompanied by the release of CO gas. The reaction flask needs to be covered with a layer of cotton in case of the sublimation of [W(CO)6]. The solution was gradually cooled to room temperature, the yellow solid was filtered off, washed with hot toluene (2×5mL), ethanol (2×5mL), and diethyl ether (2×5mL), successively. The product was recrystallized in dichloromethane and light yellow needle crystals suitable for X-ray crystallographic analysis were collected in two days. Yield: 1.2g (65%). IR (KBr pellets, cm-1): nu(-CH3) 2945(m), nu(-CH2) 2913(m), 2861(s), nu(C?O) 1885(vs), 1750(vs), 1731(vs), nu(C-N) 1449(m). 1H NMR (400MHz, DMSO-d6): delta (ppm) 2.98 (s, 9H, -NCH3), 2.83~2.96 (m, 12H, -NCH2CH2). Anal. (%) Calcd. for C12H21N3O3W: C, 32.79; H, 4.78; N, 9.56. Found: C, 32.80; H, 4.75; N, 9.53.

Reference： [1]Inorganica Chimica Acta,2020,vol. 507
[2]Inorganic Chemistry,1985,vol. 24,p. 4044 - 4049

38
[ 13688-68-1 ]
[ 14040-11-0 ]
[ 119057-76-0 ]

Reference： [1]Journal of general chemistry of the USSR,1987,vol. 57,p. 2253 - 2258
J.Gen.Chem.USSR (Engl.Transl.),1987,vol. 57,p. 2531 - 2537

39
[ 1120-88-3 ]
[ 14040-11-0 ]
(4-methylpyridazine)pentacarbonyltungsten [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1994,vol. 464,p. 163 - 170

40
[ 1132-37-2 ]
[ 14040-11-0 ]
[ 88814-39-5 ]

Reference： [1]Organometallics,1986,vol. 5,p. 2072 - 2074

41
[ 1132-37-2 ]
[ 14040-11-0 ]
[ 103639-29-8 ]

Reference： [1]Organometallics,1986,vol. 5,p. 2072 - 2074

42
[ 14040-11-0 ]
[ 1226-46-6 ]
[ 76160-56-0 ]

Reference： [1]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1980,vol. 29,p. 1360 - 1362
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1980,p. 1886 - 1889

43
[ 14040-11-0 ]
[ 6622-92-0 ]
W₂(2,4-dimethyl-6-oxopyrimidinate)4 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1981,vol. 103,p. 5078 - 5086

44
[ 14040-11-0 ]
[ 4455-09-8 ]
[ 82615-27-8 ]

Reference： [1]Organometallics,1983,vol. 2,p. 1296 - 1301

45
[ 14040-11-0 ]
[ 665-46-3 ]
3(C₂H₅)4N⁽¹⁺⁾*W₂(CO)6F₃^(3-)=((C₂H₅)4N)3[W₂(CO)6F₃] [ No CAS ]

Reference： [1]Inorganic Chemistry,1995,vol. 34,p. 4933 - 4934
Inorg. Chem.,

46
[ 14040-11-0 ]
[ 36802-41-2 ]
[ 310871-88-6 ]

Reference： [1]Inorganica Chimica Acta,2000,vol. 307,p. 48 - 57

47
[ 14040-11-0 ]
[ 81120-72-1 ]
[ 23582-03-8 ]
[ 62637-93-8 ]
[ 165196-74-7 ]

Reference： [1]Inorganica Chimica Acta,1995,vol. 232,p. 175 - 182
Inorg. Chim. Acta,

48
[ 14040-11-0 ]
[ 12146-36-0 ]
[ 62637-93-8 ]
[ 23582-02-7 ]
[ 165196-71-4 ]

Reference： [1]Inorganica Chimica Acta,1995,vol. 232,p. 175 - 182
Inorg. Chim. Acta,

49
[ 14040-11-0 ]
[ 14667-55-1 ]
[ 222017-43-8 ]

Reference： [1]Inorganica Chimica Acta,1999,vol. 285,p. 157 - 169

50
[ 14040-11-0 ]
[ 4731-65-1 ]
[ 310871-89-7 ]

Reference： [1]Inorganica Chimica Acta,2000,vol. 307,p. 47 - 56

51
[ 67-56-1 ]
[ 14040-11-0 ]
sodium antimonate [ No CAS ]
[ 429-06-1 ]
[(C2H5)4N]2[(carbonyl)5WSbW3(carbonyl)9(μ3-methoxy)2(μ3-O)WO2(methoxy)] [ No CAS ]
[(C2H5)4N]2[(carbonyl)5WSbW3(carbonyl)9(μ3-methoxy)3WO3] [ No CAS ]

Reference： [1]Organometallics,2002,vol. 21,p. 2581 - 2583

52
[ 14040-11-0 ]
[ 1867-73-8 ]
[ 67-64-1 ]
[W(CO)5((N⁽⁶⁾-methyladenosine)] [ No CAS ]

Reference： [1]Inorganica Chimica Acta,2003,vol. 343,p. 156 - 168

53
[ 3438-48-0 ]
[ 14040-11-0 ]
(4-phenylpyrimidine)pentacarbonyltungsten [ No CAS ]

Reference： [1]Inorganic Chemistry,1998,vol. 37,p. 2438 - 2442

54
[ 14040-11-0 ]
[ 148461-14-7 ]
[W(CO)4((C₆H₅)2PC₆H₄CNOCH₂CHC₃H₇)] [ No CAS ]

Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,1995,vol. 50,p. 361 - 367

55
[ 14040-11-0 ]
[ 1226-64-8 ]
[ 796047-42-2 ]

Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2004,vol. 59,p. 554 - 558
[2]Zeitschrift fur Naturforschung, B: Chemical Sciences,2004,vol. 59,p. 554 - 558

56
[ 36477-75-5 ]
[ 368-39-8 ]
[ 111770-86-6 ]
[ 14040-11-0 ]
pentacarbonyl(N-ethyl-3-hydropyridine-1,2-propadienylidene)tungsten [ No CAS ]
pentacarbonyl(5-bromo-N-ethyl-3-hydropyridine-1,2-propadienylidene)tungsten [ No CAS ]

Reference： [1]Organometallics,2006,vol. 25,p. 5774 - 5787

57
[ 39028-25-6 ]
[ 14040-11-0 ]
sodium cyclopentadienide [ No CAS ]
[ 866529-77-3 ]

Reference： [1]Organic and Biomolecular Chemistry,2005,vol. 3,p. 3091 - 3093

58
[ 274-87-3 ]
[ 14040-11-0 ]
W*NC₅H₄N₃*5CO=W(NC₅H₄N₃)(CO)5 [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999),1978,p. 1155 - 1160

59
[ 14040-11-0 ]
[ 1067-53-4 ]
[ 870299-13-1 ]
[ 870299-14-2 ]

Reference： [1]Journal of Organometallic Chemistry,2005,vol. 690,p. 4656 - 4665

60
[ 14040-11-0 ]
[ 580-13-2 ]
[ 64-20-0 ]
NMe₄[(CO)5WC(O)(2-naphthyl)] [ No CAS ]

Reference： [1]Inorganic Chemistry,1996,vol. 35,p. 7769 - 7775

61
[ 14040-11-0 ]
[ 831-81-2 ]
pentacarbonyl[p-chlorophenyl(phenyl)vinylidene]tungsten [ No CAS ]

Reference： [1]Organometallics,2007,vol. 26,p. 3791 - 3801

62
[ 14040-11-0 ]
[ 131211-27-3 ]
[ 152776-77-7 ]

Reference： [1]Polyhedron,1993,vol. 12,p. 2279 - 2290

63
[ 14040-11-0 ]
[ 18212-21-0 ]
[ 77056-53-2 ]

Reference： [1]Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie,1981,vol. 36,p. 172 - 179

64
[ 14040-11-0 ]
[ 16753-62-1 ]
[ 870299-09-5 ]
[ 870299-10-8 ]

Reference： [1]Journal of Organometallic Chemistry,2005,vol. 690,p. 4656 - 4665

65
[ 20112-79-2 ]
[ 14040-11-0 ]
W(CO)5(2-methylthio-2-imidazoline) [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1981,vol. 50,p. 215 - 220

66
[ 7152-24-1 ]
[ 14040-11-0 ]
W(CO)5(2-methylthiobenzimidazole) [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1981,vol. 50,p. 215 - 220

67
[ 1826-11-5 ]
[ 14040-11-0 ]
[ 1225285-45-9 ]

Reference： [1]New Journal of Chemistry,2010,vol. 34,p. 458 - 469

68
[ 108-86-1 ]
[ 14040-11-0 ]
[ 6638-79-5 ]
[ 88070-48-8 ]
[ 6919-61-5 ]

Reference： [1]Journal of Organic Chemistry,2011,vol. 76,p. 978 - 981

69
[ 104-92-7 ]
[ 14040-11-0 ]
[ 6638-79-5 ]
[ 52898-49-4 ]
[ 3400-22-4 ]

Reference： [1]Journal of Organic Chemistry,2011,vol. 76,p. 978 - 981

70
[ 14040-11-0 ]
[ 580-13-2 ]
[ 6638-79-5 ]
[ 113443-62-2 ]

Reference： [1]Journal of Organic Chemistry,2011,vol. 76,p. 978 - 981

71
[ 14040-11-0 ]
[ 2551-83-9 ]
W(CO)5(E-η2-1-propenylSi(OMe)3) [ No CAS ]
W(CO)5(Z-η2-1-propenylSi(OMe)3) [ No CAS ]
[ 1194524-63-4 ]
[ 1194524-67-8 ]

Reference： [1]Journal of Molecular Catalysis A: Chemical,2009,vol. 297,p. 118 - 124

72
[ 14040-11-0 ]
[ 2551-83-9 ]
[ 1194524-63-4 ]
[ 1194524-67-8 ]

Reference： [1]Journal of Molecular Catalysis A: Chemical,2009,vol. 297,p. 118 - 124
[2]Journal of Molecular Catalysis A: Chemical,2009,vol. 297,p. 118 - 124

73
[ 14040-11-0 ]
[ 110-54-3 ]
[ 146960-90-9 ]
W(CO)4(1,1'-bis(dicyclohexylphosphino)ferrocene)*0.5(hexane) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,2012,vol. 712,p. 37 - 45

74
[ 97239-80-0 ]
[ 14040-11-0 ]
[ 1380506-74-0 ]

Reference： [1]Journal of Organometallic Chemistry,2012,vol. 712,p. 37 - 45

75
[ 29421-92-9 ]
[ 14040-11-0 ]
[ 368-39-8 ]
[W(CO)₅{C(OEt)C₄H₂(Me)S}] [ No CAS ]
[W(CO)₅{C(OEt)C₄HBr(Me)S}] [ No CAS ]
[W(CO)₄{C(OEt)}₂C₄H(Me)S] [ No CAS ]

Reference： [1]Organometallics,2012,vol. 31,p. 5371 - 5383

76
[ 14040-11-0 ]
[ 2071-20-7 ]
[ 41830-14-2 ]

Yield	Reaction Conditions	Operation in experiment
91%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.

Reference： [1]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71

77
[ 14040-11-0 ]
[ 6737-42-4 ]
[ 50860-43-0 ]

Yield	Reaction Conditions	Operation in experiment
94%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.

Reference： [1]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71

78
[ 14040-11-0 ]
[ 7688-25-7 ]
[ 54111-75-0 ]

Yield	Reaction Conditions	Operation in experiment
75%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2?4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled ?10 °C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95percent yield.

Reference： [1]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71

79
[ 14040-11-0 ]
[ 2071-20-7 ]
[ 41830-14-2 ]

Yield	Reaction Conditions	Operation in experiment
91%	With sodium tetrahydroborate; at 120℃; under 760.051 Torr; for 0.666667h;Microwave irradiation; Inert atmosphere; Green chemistry;	General procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.

Reference： [1]Inorganic Chemistry Communications,2012,vol. 26,p. 69 - 71

80
[ 109-72-8 ]
[ 14040-11-0 ]
[ 5518-52-5 ]
[ 368-39-8 ]
[ethoxy(2-furyl)carbene]pentacarbonyltungsten⁽⁰⁾ [ No CAS ]
((CO)5WC(OC₂H₅))2C₄H₂O [ No CAS ]
C₂₈H₁₇O₁₅PW₂ [ No CAS ]
C₃₆H₂₁O₂₁PW₃ [ No CAS ]
C₂₀H₁₉O₈PW [ No CAS ]
C₂₀H₁₃O₉PW [ No CAS ]

Reference： [1]Organometallics,2015,vol. 34,p. 696 - 710

81
[ 109-72-8 ]
[ 14040-11-0 ]
[ 5518-52-5 ]
[ 368-39-8 ]
[ethoxy(2-furyl)carbene]pentacarbonyltungsten⁽⁰⁾ [ No CAS ]
C₂₈H₁₇O₁₅PW₂ [ No CAS ]
C₃₆H₂₁O₂₁PW₃ [ No CAS ]
C₂₀H₁₉O₈PW [ No CAS ]
C₂₀H₁₃O₉PW [ No CAS ]

Reference： [1]Organometallics,2015,vol. 34,p. 696 - 710

82
[ 109-72-8 ]
[ 14040-11-0 ]
[ 5518-52-5 ]
[ 368-39-8 ]
[ethoxy(2-furyl)carbene]pentacarbonyltungsten⁽⁰⁾ [ No CAS ]
C₂₀H₁₉O₈PW [ No CAS ]
C₂₀H₁₃O₉PW [ No CAS ]

Reference： [1]Organometallics,2015,vol. 34,p. 696 - 710

83
[ 14040-11-0 ]
[ 696-62-8 ]
[ 64-20-0 ]
N(CH₃)4⁽¹⁺⁾*W(CO)5(C(O)C₆H₄OCH₃)^(1-)=(N(CH₃)4){W(CO)5(C(O)C₆H₄OCH₃)} [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2015,vol. 54,p. 12814 - 12818
Angew. Chem.,2015,vol. 127,p. 13005 - 13009,5

84
[ 14040-11-0 ]
[ 368-39-8 ]
[ 3958-03-0 ]
5,5,5,5-tetracarbonyl-4,6-diethoxy-5-tungsta⁽⁰⁾cyclopentatrieno[b]thiophene [ No CAS ]
C₈S(OC₂H₅)4W₂(CO)8 [ No CAS ]

Reference： [1]Dalton Transactions,2015,vol. 44,p. 19218 - 19231

85
[ 14040-11-0 ]
[ 3958-03-0 ]
[ 4111-54-0 ]
C₁₆Br₂O₁₂SW₂^(2-)*2Li⁽¹⁺⁾ [ No CAS ]
C₁₀HBr₂O₆SW^(1-)*Li⁽¹⁺⁾ [ No CAS ]

Reference： [1]Dalton Transactions,2015,vol. 44,p. 19218 - 19231

86
[ 3172-56-3 ]
[ 14040-11-0 ]
[ 368-39-8 ]
[ 199620-14-9 ]
C₂₄H₁₄CrO₁₂S₂W [ No CAS ]
C₂₄H₁₄CrO₁₂S₂W [ No CAS ]
C₁₆H₁₀O₆S₂W [ No CAS ]
C₁₆H₁₀CrO₆S₂ [ No CAS ]
C₁₆H₁₀O₆S₂W [ No CAS ]
C₁₆H₁₀CrO₆S₂ [ No CAS ]
C₂₄H₁₄Cr₂O₁₂S₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
57%; 15%; 1%		0.75 g (4.5 mmol) of 3,30-bithiophenewas dissolved in 30 mL THF, 3.10 mL (5.0 mmol) of n-BuLiwas added at -78 C and the reaction mixture stirred for 30 min.Solid portions of 1.58 g (4.5 mmol) W(CO)6 were then added. After15 min of stirring, the solution was removed from the cold bathand stirred for a further 40 min at room temperature. The solutionwas then cooled to -78 C and 3.10 mL (5.0 mmol) of n-BuLi wasadded and the mixture was allowed to stir for 30 min. Solid portionsof 0.99 g (4.5 mmol) Cr(CO)6 were then added. After 15 minof stirring, the solution was removed from the cold bath and stirredfor a further 40 min at room temperature. The solvent wasremoved in vacuo, the reaction residue was dissolved in 10 mLDCM and cooled to -30 C. 1.70 g (9.0 mmol) of [Et3O][BF4] wasdissolved in 10 mL DCM and added to the cold reaction mixturethat was then allowed to rise to room temperature. The mixturewas filtered through a silica gel plug with DCM and the solventremoved at a reduced pressure. Column chromatography yieldedseven complexes. The monocarbene complexes (2b, 1b, 2a and1a) eluted first, followed by the biscarbene complexes (13ab/baand 10b).13ab: Yield: 1.48 g (1.86 mmol, 57%), purple-red crystals.nuCO(hexane)/cm-1 2072w and 2064w (A1(1), W), 2057 m (A1(1), Cr),1987vw (B1, Cr), 1984vw (B1, W), 1961sh (A1(2)), 1955vs (E). delta1H(400.13 MHz; CDCl3; Me4Si): 8.04 (1H, s, H4), 7.19 (1H, dd, 4J2',5' 2.9 and 4J2',4' 1.1, H2'), 6.96 (1H, dd, 3J4',5' 5.0 and 4J4',2' 1.0, H4'),7.36 (1H, dd, 3J5',4' 5.0 and 4J5',2' 3.0, H5'), 4.73 (2H, q, 3J 7.0,C2CH2), 5.21 (2H, q, 3J 7.0, C5CH2), 1.27 (3H, t, 3J 7.1, C2CH3) 1.70(3H, t, 3J 7.0, C5CH3). delta13C(100.613 MHz; CDCl3; Me4Si) 304.6 (CcarbW), 317.7 (Ccarb Cr), 203.0 (COtrans W), 196.6 (COcis W), 223.4(COtrans Cr), 216.6 (COcis Cr), 155.4 (C2), 136.1 (C3), 140.1 (C4),155.4 (C5), 123.1 (C2'), 131.6 (C3'), 127.9 (C4'), 126.0 (C5'), 79.4(CH2 W), 76.4 (CH2 Cr), 14.1 (CH3 W). 15.1 (CH3 Cr). m/z(C24H14O12-S2WCr, 793.88 g/mol) 624.8883 (9%, [M-H-6CO]-), 596.8881(72%, [M-H-7CO]-), 568.8915 (100%, [M-H-8CO]-).13ba: Yield: 0.39 g (0.49 mmol, 15%), purple-red crystals). delta1H(400.13 MHz; CDCl3; Me4Si): 7.97 (1H, s, H4), 7.16 (1H, dd, 4J2',5'2.8 and 4J2',4' 1.0, H2'), 7.00 (1H, dd, 3J4',5' 4.9 and 4J4',2' 1.1, H4'),7.38 (1H, dd, 3J5',4' 5.0 and 4J5',2' 3.0, H5'), 4.73 (2H, q, 3J 7.0,C2CH2), 5.01 (2H, q, 3J 7.0, C5CH2), 1.39 (3H, t, 3J 7.1, C2CH3) 1.68(3H, t, 3J 7.2, C5CH3). delta13C(100.613 MHz; CDCl3; Me4Si) 290.7 (CcarbW), 317.7 (Ccarb Cr), 202.4 (COtrans W), 197.3 (COcis W), 223.8(COtrans Cr), 215.3 (COcis Cr), n.o. (C2), n.o. (C3), 140.0 (C4), n.o.(C5), 123.2 (C2'), n.o. (C3'), 127.5 (C4'), 126.5 (C5'), 78.8 (CH2 W),76.4 (CH2 Cr), 14.9 (CH3 W). 14.6 (CH3 Cr).

Reference： [1]Polyhedron,2019,vol. 158,p. 193 - 207

87
[ 3172-56-3 ]
[ 14040-11-0 ]
[ 368-39-8 ]
C₂₄H₁₄O₁₂S₂W₂ [ No CAS ]
C₂₄H₁₄O₁₂S₂W₂ [ No CAS ]
C₁₉H₁₄O₈S₂W [ No CAS ]
C₁₆H₁₀O₆S₂W [ No CAS ]
C₁₆H₁₀O₆S₂W [ No CAS ]
C₂₄H₁₄O₁₂S₂W₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
< 3%; < 3%; < 3%; 34%; 17%; 28%		0.34 g (2.0 mmol) of <strong>[3172-56-3]3,3'-bithiophene</strong> was dissolved in 15 mLTHF, 1.90 mL (3.0 mmol) of n-BuLi and 1.06 g (3.0 mmol) W(CO)6were added. The reaction mixture was later dissolved in 10 mLDCM and 0.8 g (4.0 mmol) [Et3O][BF4], dissolved in 10 mL DCM,was added. Column chromatography yielded six complexes. Compound2a first eluted, followed by 1a, 12a, 11a, 10a and 17a.1a: Yield: 0.37 g (0.68 mmol, 34%), red crystals. nuCO(hexane)/cm-1 2068 m (A1(1)), 1983vw (B1), 1954sh (A1(2)), 1944vs (E). delta1H(300.13 MHz; CDCl3; Me4Si): 7.12 (1H, d, 3J4,5 5.0, H4), 7.71 (1H,d, 3J5,4 5.0, H5), 7.15 (1H, dd, 4J2',5' 3.0 and 4J2',4' 1.3, H2'), 6.94(1H, dd, 3J4',5' 5.0 and 4J4',2' 1.3, H4'), 7.32 (1H, dd, 3J5',4' 5.0 and4J5',2' 3.0, H5'), 4.71 (2H, q, 3J 7.1, CH2), 1.14 (3H, t, 3J 7.1, CH3).delta13C(75.468 MHz; CDCl3; Me4Si) 298.6 (Ccarb), 202.6 (COtrans),197.4 (COcis), 156.8 (C2), 137.8 (C3), 131.6 (C4), 134.1 (C5), 122.4(C2'), 133.5 (C3'), 128.5 (C4'), 125.2 (C5'), 79.0 (CH2), 14.0 (CH3).m/z(C16H10O6S2W, 545.94 g/mol) 566.8801 (96%, [M+Na-2H]-),538.8760 (63%, [M+Na-2H-CO]), 482.9084 (100%, [M+Na-2H-3CO]-).2a: Yield: 0.19 g (0.35 mmol, 17%), red-purple crystals.nuCO(hexane)/cm-1 2067 m (A1(1)), 1981vw (B1), 1954sh (A1(2)),1944vs (E). delta1H(300.13 MHz; CDCl3; Me4Si): 7.83 (1H, d, 4J2,41.3, H2), 8.30 (1H, d, 4J4,2 1.4, H4), 7.46 (1H, dd, 4J2',5' 2.9 and4J2',4' 1.3, H2'), 7.33 (1H, d, 3J4',5' 5.0, H4'), 7.41 (1H, dd, 3J5',4'5.0 and 4J5',2' 2.9, H5'), 5.01 (2H, q, 3J 7.1, CH2), 1.68 (3H, t, 3J7.1, CH3). delta13C(75.468 MHz; CDCl3; Me4Si) 290.6 (Ccarb), 202.4(COtrans), 197.6 (COcis), 130.2 (C2), 139.2 (C3), 138.9 (C4), 158.5(C5), 120.8 (C2'), 136.0 (C3'), 126.0 (C4'), 126.8 (C5'), 78.6(CH2), 15.0 (CH3). m/z(C16H10O6S2W, 545.94 g/mol) 566.8880(75%, [M+Na-2H]-), 538.8806 (45%, [M+Na-2H-CO]-), 482.9099(100%, [M+Na-2H-3CO].10a: Yield: 0.52 g (0.56 mmol, 28%), purple-red crystals.nuCO(hexane)/cm-1 2064 m (A1(1)), 1982vw (B1), 1955sh (A1(2)),1946vs (E). delta1H(300.13 MHz; CDCl3; Me4Si) 7.87 (2H, d, 4J2,4 1.2,H2), 8.30 (2H, d, 4J4,2 1.2, H4), 5.03 (4H, q, 3J 7.0, CH2), 1.69 (6H, t,3J 7.0, CH3). delta13C(75.468 MHz; CDCl3; Me4Si) 290.8 (Ccarb), 202.3(COtrans), 197.5 (COcis), 130.4 (C2), 137.5 (C3), 138.8 (C4), 158.9(C5), 78.7 (CH2), 14.9 (CH3). m/z(C24H14O12S2W2, 925.89 g/mol)924.8770 (20%, [MH]), 868.8815 (48%, [MH2CO]),840.9309 (99%, [MH3CO]), 812.8959 (100%, [MH4CO]-).11a: Yield: <3%, purple-red crystals. delta1H(400.13 MHz; CDCl3;Me4Si): 7.48 (1H, d, 3J4,5 4.3, H4), 8.09 (1H, d, 3J5,4 4.3, H5), 4.99(2H, q, 3J7.1, CH2), 1.68 (3H, t, 3J7.1, CH3).12a: Yield: <3%, purple-red crystals. delta1H(400.13 MHz; CDCl3;Me4Si) 7.10 (1H, d, 3J4,5 5.0, H4), 7.78 (1H, d, 3J5,4 5.0, H5), 7.56(1H, d, 4J2',4' 1.2, H20), 7.90 (1H, d, 4J4',2' 1.2, H40), 4.72 (2H, q, 3J7.1, C2CH2), 5.01 (2H, q, 3J 6.9, C50CH2), 1.16 (3H, t, 3J 7.1,C2CH3), 1.67 (3H, t, 3J 6.9, C50CH3).17a: Yield: <3%, red crystals. delta1H(400.13 MHz; CDCl3; Me4Si)8.02 (1H, s, H4), 7.61 (1H, dd, 4J2',5' 2.9 and 4J2',4' 1.3, H2'), 7.32(1H, dd, 3J4',5' 5.0 and 4J4',2' 1.2, H4'), 7.37 (1H, dd, 3J5',4' 5.0 and4J5',2' 3.0, H5'), 4.32 (2H, q, 3J 7.0, C2-CH2), 5.02 (2H, q, 3J 7.0, C5-CH2), 1.33 (3H, t, 3J 7.2, C2-CH3), 1.70 (3H, t, 3J 7.1, C5-CH3).

Reference： [1]Polyhedron,2019,vol. 158,p. 193 - 207

88
[ 14040-11-0 ]
[ 4848-43-5 ]
tetracarbonyl(2-(diphenylphosphino)-ethylamine)tungsten⁽⁰⁾ [ No CAS ]

Reference： [1]Organometallics,2020,vol. 39,p. 4535 - 4543

Same Skeleton Products

Related Products

Historical Records

Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
{[ item.p_purity ]}	{[ item.pr_size ]}	{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]}	{[ getRatePrice(item.pr_usd, 1,1) ]}	Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]}	{[ item.pr_usastock ]}	Inquiry -	{[ item.pr_chinastock ]}	Inquiry -

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 14040-11-0 ] {[proInfo.proName]}

Quality Control of [ 14040-11-0 ]

Related Doc. of [ 14040-11-0 ]

Product Details of [ 14040-11-0 ]

Safety of [ 14040-11-0 ]

Application In Synthesis of [ 14040-11-0 ]

[ 14040-11-0 ] Synthesis Path-Downstream 1~88

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry