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Chemical Structure| 140926-94-9 Chemical Structure| 140926-94-9

Structure of 140926-94-9

Chemical Structure| 140926-94-9

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Product Details of [ 140926-94-9 ]

CAS No. :140926-94-9
Formula : C35H39NO5
M.W : 553.69
SMILES Code : O[C@@]1(COCC2=CC=CC=C2)[C@@H](OCC3=CC=CC=C3)[C@H](OCC4=CC=CC=C4)[C@@H](OCC5=CC=CC=C5)[C@@H](N)C1

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Application In Synthesis of [ 140926-94-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 140926-94-9 ]

[ 140926-94-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 140926-94-9 ]
  • [ 83465-22-9 ]
YieldReaction ConditionsOperation in experiment
With hydrogenchloride; hydrogen;palladium 10% on activated carbon; In tetrahydrofuran; methanol; water; at 40℃; under 1838.93 - 2206.72 Torr; for 4.5h; To a solution of (lS)- (l (OH), 2,4, 5/1, 3) -2,3, 4-tri-O-benzyl-5-amino-1-C- [benzyloxymethyl]-1, 2,3, 4-cyclohexanetetrol (2.26 g, 4.1 mmol) in mixtures of methanol and tetrahydrofuran (1: 1,50 mL) were added 10% palladium carbon (1.4 g) and 4% hydrochloric acid solution (16.5 mL). The mixture was hydrogenated with shaking for 4.5 hours at 2.5-3. 0 kg/cm2 at 40 C. The reaction mixture was filtered and washed with methanol. The combined filtrate was concentrated and the resulted residue was chromatographed using ion exchange resin (Indion 225 H+) to give the title compound. Yield: 0.65 g HPLC Purity: 98.76 % 1H NMR (D2O, 6) : 1.94 (lH, dd, 6Hax. ), 2.11 (lH, dd, 6Heq. ), 3.48 (lH, q, 5H), 3.53 (lH, d, 2H), 3.56&3. 59 (each IH,-CH20-), 3.61 (lH, dd, 4H), 3.86 (lH, t, 3H)
 

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