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Chemical Structure| 14125-76-9 Chemical Structure| 14125-76-9

Structure of 14125-76-9

Chemical Structure| 14125-76-9

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Product Details of [ 14125-76-9 ]

CAS No. :14125-76-9
Formula : C11H14O7
M.W : 258.22
SMILES Code : CC(O[C@@H]1COC=C(OC(C)=O)[C@H]1OC(C)=O)=O

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Application In Synthesis of [ 14125-76-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14125-76-9 ]

[ 14125-76-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 16375-88-5 ]
  • [ 14125-76-9 ]
  • 2(S)-(4-acetamidobenzyloxy)-2H-pyran-3(6H)-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
22% With tin(IV) chloride; In dichloromethane; at -18℃; for 1h; A solution of 1 (100 mg, 0.39 mmol) and <strong>[16375-88-5]4-acetamidobenzyl alcohol</strong>(97 mg, 0.58 mmol) in anhydrous CH2Cl2 (4 mL) was cooled at -18 C.Upon addition of SnCl4 (0.06 mL, 0.51 mmol), the reaction mixture wasstirred at -18 C for 1 h and then was diluted with CH2Cl2 and washedwith sat aq NaHCO3, water and brine. After drying (MgSO4) and concentration,the residue was purified by column chromatography(hexane/EtOAc, 7:3?1:1) to afford 27S (22 mg, 22%); [alpha]D -132.8 (c0.8, CHCl3); ee=80%.
 

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