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Chemical Structure| 1416881-51-0 Chemical Structure| 1416881-51-0

Structure of 1416881-51-0

Chemical Structure| 1416881-51-0

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Product Details of [ 1416881-51-0 ]

CAS No. :1416881-51-0
Formula : C56H32N6
M.W : 788.89
SMILES Code : N#CC1=C(N2C3=C(C4=C2C=CC=C4)C=CC=C3)C(N5C6=C(C7=C5C=CC=C7)C=CC=C6)=C(N8C9=C(C%10=C8C=CC=C%10)C=CC=C9)C(N%11C%12=C(C%13=C%11C=CC=C%13)C=CC=C%12)=C1C#N
MDL No. :MFCD28369265
InChI Key :QMXFUIUEGUOSEV-UHFFFAOYSA-N
Pubchem ID :101136487

Safety of [ 1416881-51-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P280

Application In Synthesis of [ 1416881-51-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1416881-51-0 ]

[ 1416881-51-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1835-65-0 ]
  • [ 86-74-8 ]
  • [ 1416881-51-0 ]
YieldReaction ConditionsOperation in experiment
28.5% 480 mg (12.0 mmol) of 60percent sodium hydride was placed in a 1 00-mE three-neck flask, the interior of the flask was substituted with nitrogen, and 40 mE of N,N-dimethylfor55 mamide was added thereto, followed by stirring. 1.67 g(10.0 mmol) of 9H-carbazole was added to the mixture, which was stirred under a nitrogen stream at room temperature for 30 minutes. Afier stirring, 400 mg (2.00 mmol) of <strong>[1835-65-0]tetrafluorophthalonitrile</strong> was added to the mixture, and themixture was stirred under a nitrogen atmonphere at 60° C. for 10 hours. After stirring, 5.0 ml of water was added to the mixture, which was then stirred. After stirring, N,N-dimethylformamide was removed from the mixture. After the removal, 200 mE of water was added to the mixture, towhich ultrasonic waves were applied. After the application, the mixture was suction-filtered to provide a solid matter.The resulting solid matter was purified by silica gel column chromatography. In the column chromatography, chloroform was firstly used as a developing solvent, and then a mixed solvent of acetone and chloroform (1/2) was used as a developing solvent. The resulting fraction was concentrated to provide a solid matter, which was then recrystallized from a mixed solvent of chloroform and methanol, thereby providing a yellow powdered solid matter in a yield amount of 450 mg and a yield of 28.5percent.
 

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