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CAS No. : | 1429436-06-5 | MDL No. : | N/A |
Formula : | C19H13NO4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | DMZIXVHACOAZQC-UHFFFAOYSA-N |
M.W : | 319.31 | Pubchem ID : | 102206428 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | With 4-nitro-benzoic acid; In N,N-dimethyl acetamide; at 160℃; for 72h; | A mixture of H2pddb (0.0128g, 0.04mmol), Zn(NO3)2·6H2O (0.0297g, 0.1mmol), 4-nitrobenzoic acid (0.0146g, 0.10mmol), water (6mL), and DMA (1mL) was heated in 25mL Teflon-lined stainless steel container at 160C for three days, and slowly cooled to room temperature at a rate of 5C/h. Then colorless block crystals 1 were obtained with a 75% yield (based on H2pddb) after being washed several times by water. Elemental analysis: Anal. Calc. for C19H13NO5Zn: C, 56.95; H, 3.17; N, 3.50. Found: C, 56.79; H, 3.34; N, 3.33%. IR (KBr, cm-1): 3421 (bw), 3053 (bw), 1612 (w), 1542 (s), 1397 (s), 1277 (w), 1172 (w), 820 (w), 766 (m), 690 (m). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | With N,N-dimethyl acetamide; 4-nitro-benzoic acid; In N,N-dimethyl acetamide; acetonitrile; at 160℃; for 72h; | A mixture of H2pddb (0.0128g, 0.04mmol), CdI2 (0.0366g, 0.1mmol), 4-nitrobenzoic acid (0.0146g, 0.10mmol), water (6mL), and MeCN (2mL) was heated in 25mL Teflon-lined stainless steel container at 160C for three days, and slowly cooled to room temperature at a rate of 5C/h. Thus, colorless block crystals 3 were achieved with a pure yield of 70% (based on H2pddb). Elemental analysis: Anal. Calc. for C38H24N2O9Cd2: C, 52.12; H, 2.76; N, 3.19. Found: C, 52.21; H, 2.93; N, 3.02%. IR (KBr, cm-1): 3433 (bw), 3081 (w), 2928 (w), 2484 (w), 2249 (w), 1704 (w), 1604 (m), 1557 (s), 1455 (m), 1395 (s), 1349 (s), 1260 (w), 926 (w), 764 (m), 684 (m). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
58% | With N,N-dimethyl acetamide; In N,N-dimethyl acetamide; acetonitrile; at 160℃; for 72h; | A mixture of H2pddb (0.0128g, 0.04mmol), CdI2 (0.0366g, 0.1mmol), water (6mL), and MeCN (2mL) was heated in 25mL Teflon-lined stainless steel container at 160C for three days, and slowly cooled to room temperature at a rate of 5C/h. Colorless block crystal 4 were collected, and then filtered to get a yield of 58% (based on H2pddb). Elemental analysis: Anal. Calc. for C19H15NO6Cd: C, 49.00; H, 3.25; N, 3.01. Found: C, 48.82; H, 3.40; N, 3.08%. IR (KBr, cm-1): 3391 (bw), 3080 (w), 2926 (w), 1696 (w), 1605 (m), 1557 (s), 1435 (m), 1351 (s), 1253 (w), 1174 (w), 892 (bw), 765 (m), 688 (m), 567 (w). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | With N,N-dimethyl acetamide; In N,N-dimethyl acetamide; water; at 160℃; for 72h; | A mixture of H2pddb (0.0128g, 0.04mmol), Zn(NO3)2·6H2O (0.0297g, 0.1mmol), water (6mL), and DMA (1mL) was heated in 25mL Teflon-lined stainless steel container at 160C for three days, and slowly cooled to room temperature at a rate of 5C/h. Meanwhile, colorless stick crystals were collected, with yield of 60% (based on H2pddb). Elemental analysis: Anal. Calc. for C19H11NO4Zn: C, 59.63; H, 2.90; N, 3.66. Found: C, 59.74; H, 2.82; N, 3.76%. IR (KBr, cm-1): 3049 (w), 2360 (w), 1608 (w), 1540 (s), 1395 (s), 820 (w), 764 (m), 682 (m). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | In acetonitrile; at 120℃; for 72h; | With regard to complex 1, the mixture of Cu(NO3)2·3H2O (24mg, 0.1mmol), MeCN (1mL), H2L1 (26mg, 0.08mmol), and water (4mL) was heated for 3 days under 120C in Teon-lined stainless steel container of 25mL. and at a speed of 5C/h slow cooling them to room temperature. Accordingly, blue block crystals 1·H2O were obtained that its pure yield was 56% (on the basis of H2L1). Elemental analysis: Anal. Calc. for C19H13CuNO5: N, 3.51; H, 3.29; C, 57.22. Found: N, 3.32%; H, 3.25; C, 57.21. IR (KBr, cm-1): IR (4000-400cm-1): 3825 (w), 3752 (w), 3427 (brs), 2123 (s), 1616 (s), 1366 (s), 1024 (w), 774 (s), 546 (s). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | In acetonitrile; at 120℃; for 72h;Autoclave; | With regard to the synthesis of complex 1, the mixture of Co(NO3)2*3H2O (30 mg, 0.1 mmol), MeCN (1 mL), H2L1 (26 mg, 0.08 mmol), and water (4 mL) was heated for 3 days at 120 C in a Teflonlined stainless steel container of 25 mL, and heated at a speed of 5 C/h followed by their slow cooling to room temperature. Accordingly, pink block crystals 1 were obtained with a pure yield of 56% (on the basis of H2L1). Elemental analysis calc. for C19H13CoNO5 (%): N 3.12, H 3.18, C 57.49. Found (%): N 3.32, H 3.25, C 57.21. |