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[ CAS No. 14609-51-9 ]

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Chemical Structure| 14609-51-9
Chemical Structure| 14609-51-9
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Product Details of [ 14609-51-9 ]

CAS No. :14609-51-9 MDL No. :MFCD00600964
Formula : C48H26N8 Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :714.77 g/mol Pubchem ID :-
Synonyms :

Safety of [ 14609-51-9 ]

Signal Word:Warning Class:
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 UN#:
Hazard Statements:H315-H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 14609-51-9 ]

  • Downstream synthetic route of [ 14609-51-9 ]

[ 14609-51-9 ] Synthesis Path-Downstream   1~17

  • 4
  • [ 14609-51-9 ]
  • [ 780722-26-1 ]
  • 5,10,15,20-tetrakis(4-(2,4-diaminotriazine)phenyl)porphyrin [ No CAS ]
  • 5
  • [ 14609-51-9 ]
  • C48H24N8(2-)*Br2Sb(3+)*Br(1-) [ No CAS ]
  • 6
  • [ 109-97-7 ]
  • [ 105-07-7 ]
  • [ 14609-51-9 ]
YieldReaction ConditionsOperation in experiment
Under a N 2 atmosphere, 0.565 g of p-cyanobenzaldehyde was added to 500 mL of dry CH 2 Cl 2 and stirred for 20 minutes to remove the air contained in the solution. Then 0.3 ml of pyrrole was added to the above mixture, and the mixture was stirred well. After refluxing at 130 degrees Celsius for 30 minutes, 52.5 [mu]L of BF3.OEt2 (0.85 nmol) was added and the reaction mixture was protected from light with tin foil. After stirring for 2 hours, 0.78 g of p-chlorophenylhydrazine (0.37 mmol) was further added as a solid, and the solution was refluxed for 4 hours and slowly cooled to room temperature. The residue was purified by column chromatography on silica gel eluting with CHCl3 to give (CNTCPP).
With propionic acid; for 12h;Reflux; To a solution of substituted 4-formylbenzonitrile (1 eqv.)in propionic acid (50 mL) was added pyrrole (1 eqv.) andthe reaction mixture was refluxed 12 h in dark, then it wasfiltered and column purified to obtain the desired product.1H NMR (CDCl3, 600 MHz), (ppm): -2.94 (s, 2H), 8.02(d, 8H, J = 8.4 Hz), 8.25 (d, 8H, J = 8.4 Hz), 8.72 (s,8H), ESI-MS (m/z) calcd. 714.2, found 715.3 (M+H+
In propionic acid; at 145.0℃; for 2h;Inert atmosphere; Darkness; General procedure: In the typical procedureof porphyrin syntheses, benzaldehyde or its derivatives(150mmol) was heated to refluxing (145 C) with stirring in propionic acid (450mL) under the nitrogen protection,followed by the addition of redistilled pyrrole (150mmol)dropwise under refluxing conditions. After refluxing for2.0h in the shield from ambient light, the resultant mixturewas cooled in air to room temperature and kept standinguntil a large amount of solid appeared. Then the solid wascollected through suction filtration and suspended in methanol(200mL) with stirring for 6.0h. The collected purplishred precipitate was washed successively using methanol(2 × 100mL) and purified through silica column chromatographyseparation with cyclohexane and dichloromethaneas eluent (10:1-4:1, volume/volume).
  • 7
  • [ 14609-51-9 ]
  • 5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin [ No CAS ]
  • 8
  • [ 14609-51-9 ]
  • {5,10,15,20-tetrakis[4-cyanophenyl]porphyrinato}manganese(III) chloride [ No CAS ]
  • 9
  • [ 109-97-7 ]
  • [ 105-07-7 ]
  • [ 14609-51-9 ]
  • C48H26N8 [ No CAS ]
  • 10
  • [ 14609-51-9 ]
  • C72H42N12O3 [ No CAS ]
  • 12
  • [ 105-07-7 ]
  • DL-cysteine-hydrochloride [ No CAS ]
  • [ 14609-51-9 ]
  • 15
  • [ 14609-51-9 ]
  • [ 60430-21-9 ]
  • 16
  • [ 124-41-4 ]
  • [ 14609-51-9 ]
  • C52H42N8O4 [ No CAS ]
  • 17
  • [ 14609-51-9 ]
  • C52H40N8O4Zn [ No CAS ]
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