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Chemical Structure| 149054-39-7 Chemical Structure| 149054-39-7

Structure of 149054-39-7

Chemical Structure| 149054-39-7

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Product Details of [ 149054-39-7 ]

CAS No. :149054-39-7
Formula : C18H11BrN2
M.W : 335.20
SMILES Code : BrC1=CC=C(C2=CC=C3C=CC4=CC=CN=C4C3=N2)C=C1
MDL No. :MFCD22571710

Safety of [ 149054-39-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 149054-39-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 149054-39-7 ]

[ 149054-39-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 654664-63-8 ]
  • [ 149054-39-7 ]
  • 2-(4-(triphenylen-3-yl)phenyl)-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
70% With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In ethanol; toluene; for 12h;Inert atmosphere; Reflux; 2-(4-bromophenyl)-1,10-phenanthroline (10 g, 29.83 mmol), triphenylenyl-2-boronic acid (9.74 g, 35.8 mmol), tetrakistriphenylphosphine palladium(0) (1.72 g, 1.49 mmol), 10 ml of 4M potassium carbonate solution, 200 ml of toluene, and 20 ml of ethanol were put under a nitrogen atmosphere, and then refluxed and stirred for 12 hours. After the reaction, 50 ml of distilled water was added, and the mixture was stirred for 3 hours, then vacuum-filtered, and then subjected to column chromatography for separation using methylene chloride/hexane as the eluent, followed by MC recrystallization, to obtain Compound A, i.e, 2-(4-(triphenylen-3-yl)phenyl)-1,10-phenanthroline (10 g, yield: 70%).
 

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