Alternatived Products of [ 152270-00-3 ]
Product Details of [ 152270-00-3 ]
CAS No. : | 152270-00-3 |
MDL No. : | N/A |
Formula : |
C34H54O2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | WWYFSQMGZADESA-UHFFFAOYSA-N |
M.W : |
494.79
|
Pubchem ID : | 15429803 |
Synonyms : |
|
Safety of [ 152270-00-3 ]
Application In Synthesis of [ 152270-00-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 152270-00-3 ]
- 1
-
4'-[{(trifluoromethyl)sulfonyl}oxy]-2,2':6',6''-terpyridine
[ No CAS ]
-
[ 152270-00-3 ]
-
[ 243835-41-8 ]
- 2
-
[ 15862-19-8 ]
-
[ 152270-00-3 ]
-
1,4-bis(2',2"-bipyridine-5"-ylethinyl)-2,5-di(dodecyloxy)benzene
[ No CAS ]
- 3
-
[ 134653-69-3 ]
-
[ 152270-00-3 ]
-
[ 243835-41-8 ]
- 4
-
[ 137436-30-7 ]
-
[ 152270-00-3 ]
-
[ 243835-39-4 ]
- 5
-
[ 152270-00-3 ]
-
[ 287478-28-8 ]
-
C142H182N8O6
[ No CAS ]
- 6
-
[ 277316-22-0 ]
-
[ 152270-00-3 ]
Reference:
[1]Journal of Nanoscience and Nanotechnology,2010,vol. 10,p. 6800 - 6804
[2]Chemistry - A European Journal,2011,vol. 17,p. 13247 - 13257
[3]Journal of Organic Chemistry,2000,vol. 65,p. 3126 - 3134
[4]Tetrahedron Letters,2000,vol. 41,p. 3837 - 3841
- 7
-
[ 1120-87-2 ]
-
[ 152270-00-3 ]
-
[ 302897-91-2 ]
- 8
-
[ 4595-59-9 ]
-
[ 152270-00-3 ]
-
2,5-bis(pyrimidine-5-yl-ethynyl)-1,4-didodecyloxybenzene
[ No CAS ]
- 9
-
[ 196316-31-1 ]
-
[ 152270-00-3 ]
-
ϖ-conjugated [2.2]paracyclophane-containing polymer, Mn = 8000, Mw = 14000, degree of polymerization = 11.5; Monomer(s): pseudo-p-dibromo[2.2]paracyclophane
[ No CAS ]
- 10
-
[ 145483-66-5 ]
-
[ 1066-54-2 ]
-
[ 152270-00-3 ]
- 11
-
[ 110-89-4 ]
-
[ 152270-00-3 ]
-
α-(2-piperidin-1-yl-2-thioxo-ethyl)-, ω-[2,5-bis-dodecyloxy-4-(2-piperidin-1-yl-2-thioxo-ethyl)phenyl]-terminated poly[(2,5-bis-dodecyloxy-1,4-phenylene)-[1,3]dithiol-4-yl-2-ylidenemethylene], Mn: 8870
[ No CAS ]
- 12
-
[ 110-89-4 ]
-
[ 152270-00-3 ]
-
α-(2-piperidin-1-yl-2-selenoxo-ethyl)-, ω-[2,5-bis-dodecyloxy-4-(2-piperidin-1-yl-2-selenoxo-ethyl)phenyl]-terminated poly[(2,5-bis-dodecyloxy-1,4-phenylene)-[1,3]diselenol-4-yl-2-ylidenemethylene], Mn: 5220 (CHCl3-soluble part)
[ No CAS ]
- 13
-
[ 15155-41-6 ]
-
[ 152270-00-3 ]
-
polymer, product of polycondensation, Mn = 18.4 kDa, Mw/Mn = 2.7; monomer(s): 1,4-didodecyloxy-2,5-diethynylbenzene; 4,7-dibromo-2,1,3-benzothiadiazole
[ No CAS ]
- 14
-
[ 152270-00-3 ]
-
[ 300814-30-6 ]
-
poly[p-(phenyleneethynylene)-alt-(thienyleneethynylene)], Mn = 1.8E4, Mw/Mn = 2.5; monomer(s): 5-2[(2,5-dibromo-thiophen-3-yl)-vinyl]-2,2-bipyridine; 1,4-diethynyl-2,5-didodecyloxybenzene
[ No CAS ]
- 15
-
[ 152270-00-3 ]
-
2,5-diiodo-3-dodecylthiophene
[ No CAS ]
-
poly[p-(phenyleneethynylene)-alt-(thienyleneethynylene)], Mn = 3.2E5, Mw/Mn = 2.8; monomer(s): 2,5-diiodo-3-dodecylthiophene; 1,4-diethynyl-2,5-didodecyloxybenzene
[ No CAS ]
- 16
-
[ 152270-00-3 ]
-
[ 208348-06-5 ]
-
poly[p-(phenyleneethynylene)-alt-(thienyleneethynylene)], Mw = 1.7E5, Mw/Mn = 1.4; monomer(s): 1,4-diethynyl-2,5-didodecyloxybenzene; 4-{4-[2-(2,5-dibromothiophen-3-yl)-vinyl]phenyl}-2,2::622'-terpyridine
[ No CAS ]
- 17
-
[ 152270-00-3 ]
-
[ 398507-94-3 ]
-
polymer, Mn = 1.9E5, Mw/Mn = 1.5; monomer(s): 1,4-diethynyl-2,5-didodecyloxybenzene; 4-[4-(2,5-dibromothiophen-3-yl-methoxymethyl)phenyl]-2,2::622'-terpyridine
[ No CAS ]
- 18
-
[ 152270-00-3 ]
-
[ 521947-37-5 ]
-
polymer, regioregular, product of Heck-Sonogashira coupling, Mw 14000 Da, Mn 10000 Da, Mw/Mn 1.4 by GPC; monomer(s): 2-phenyl-1,3-bis(p-bromophenyl)-4,5,6,7-tetrahydro-2H-isophosphindole; 2,5-didodecyloxy-1,4-diethynylbenzene
[ No CAS ]
- 19
-
[ 115-19-5 ]
-
[ 137436-30-7 ]
-
[ 152270-00-3 ]
- 20
-
[ 882175-43-1 ]
-
[ 152270-00-3 ]
-
polymer, product of Sonogashira polycondensation, Mw 6900, Mn 3000; monomer(s): 6,15-dibromo-2,11-dithia[3,3](2,6)pyridinophane; 2,5-di(dodecyloxy)-1,4-diethynylbenzene
[ No CAS ]
- 21
-
[ 629661-05-8 ]
-
[ 152270-00-3 ]
-
polymer, Mw 1.20E5, Mn 6.18E4, PDI 1.76 (GPC), degree of polymerization 206; monomer(s): 2,5-dibromothiophen-3-ylmethyldiethylamine; 1,4-diethynyl-2,5-didodecyloxybenzene
[ No CAS ]
- 22
-
[ 810672-03-8 ]
-
[ 152270-00-3 ]
-
polymer, Mw 1.00E5, Mn 3.676E4, PDI 2.73 (GPC), degree of polymerization 106; monomer(s): N-(2,5-dibromothiophen-3-ylmethyl)-N,N,N\-trimethylethane-1,2-diamine; 1,4-diethynyl-2,5-didodecyloxybenzene
[ No CAS ]
- 23
-
[ 55981-29-8 ]
-
[ 152270-00-3 ]
-
polymer, CHCl3 soluble part Mn 29700, Mw/Mn 2.4 by GPC, Mn 38896 calculated from Br content; monomer(s): 2,5-dibromo-1,3,4-thiadiazole; 1,4-didodecyloxy-2,5-diethynylbenzene
[ No CAS ]
- 24
-
[ 52431-30-8 ]
-
[ 152270-00-3 ]
-
polymer, THF soluble part Mn 7000, Mw/Mn 1.2 by GPC; monomer(s): 2,5-dibromo-3,4-dinitrothiophene; 1,4-didodecyloxy-2,5-diethynylbenzene
[ No CAS ]
- 25
-
[ 848419-03-4 ]
-
[ 152270-00-3 ]
-
polymer, CHCl3 soluble part Mn 8200, Mw/Mn 2.0 by GPC, Mn 7492 calculated from Br content; monomer(s): 3,5-dibromo-4-propyl-1,2,4-triazole; 1,4-didodecyloxy-2,5-diethynylbenzene
[ No CAS ]
- 26
-
[ 848419-06-7 ]
-
[ 152270-00-3 ]
-
polymer, CHCl3 soluble part Mn 17200, Mw/Mn 2.5 by GPC, Mn 29809 calculated from Br content; monomer(s): 3,5-dibromo-4-dodecyl-1,2,4-triazole; 1,4-didodecyloxy-2,5-diethynylbenzene
[ No CAS ]
- 27
-
2,5-bis(tert-butoxycarbonyl-methylamino-methyl)-1,4-diiodobenzene
[ No CAS ]
-
[ 152270-00-3 ]
-
poly(2,5-bis[(tert-butoxycarbonyl)methylaminomethyl]-1,4-phenylenethynyl-2,5-bis(dodecyloxy)-1,4-phenylenethynyl)
[ No CAS ]
- 28
-
[ 152270-00-3 ]
-
[ 606126-86-7 ]
-
polymer, Mn = 4280, PDI = 1.75; monomer(s): 1,4-bis(dodecyloxy)-2,5-diethynylbenzene; 5,8-dibromo-2,3-di(1H-2-pyrrolyl)quinoxaline
[ No CAS ]
- 29
-
[ 152270-00-3 ]
-
[ 606126-86-7 ]
-
polymer, Mn = 7720, PDI = 3.26; monomer(s): 1,4-bis(dodecyloxy)-2,5-diethynylbenzene; 5,8-dibromo-2,3-di(1H-2-pyrrolyl)quinoxaline
[ No CAS ]
- 30
-
1-bromo-4-formyl-2,5-didodecyloxybenzene
[ No CAS ]
-
[ 152270-00-3 ]
-
C96H158O8
[ No CAS ]
- 31
-
C31H55BrO2
[ No CAS ]
-
[ 152270-00-3 ]
-
C96H162O6
[ No CAS ]
- 32
-
6,13-bis(triisopropylsilylethynyl)-2,9-dibromopentacene
[ No CAS ]
-
6,13-bis(triisopropylsilylethynyl)-2,10-dibromopentacene
[ No CAS ]
-
[ 152270-00-3 ]
-
copolymer, Mn = 11344, Mw/Mn = 2.21; monomer(s): 6,13-bis(triisopropylsilylethynyl)-2,9-dibromopentacene; 6,13-bis(triisopropylsilylethynyl)-2,10-dibromopentacene; 1,4-diethynyl-2,5-bis(dodecyloxy)benzene
[ No CAS ]
- 33
-
[ 3230-09-9 ]
-
[ 152270-00-3 ]
Reference:
[1]Journal of Organic Chemistry,2000,vol. 65,p. 3126 - 3134
[2]Journal of the American Chemical Society,2011,vol. 133,p. 15412 - 15424
[3]Organometallics,2014,vol. 33,p. 665 - 676
[4]Dyes and Pigments,2016,vol. 133,p. 406 - 414
- 34
-
[ 137436-30-7 ]
-
[ 152270-00-3 ]
- 35
-
[ 1052690-33-1 ]
-
[ 152270-00-3 ]
-
[ 1052690-40-0 ]
- 36
-
[ 1110618-59-1 ]
-
[ 152270-00-3 ]
-
[ 1110618-65-9 ]
- 37
-
[ 152270-19-4 ]
-
[ 152270-00-3 ]
Yield | Reaction Conditions | Operation in experiment |
75% |
With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20℃; for 0.5h;Darkness; |
Compound 14 (0.21 g, 3.29 × 10 -4 mol) was dissolved in THF (5 mL),Tetrabutylammonium fluoride (TBAF) (0.79 mL, 7.89 × 10 -4 mol) was added to the solution,The mixture was stirred at room temperature under light shielding for 30 minutes. After the reaction,The solvent was distilled off under reduced pressure,Purification was performed twice by silica gel column chromatography (CH2Cl2: hexane = 1: 3).To give Compound 15 as a pale yellow solid (yield 0.12 g, 75.0%).). |
Reference:
[1]Journal of the American Chemical Society,2011,vol. 133,p. 15412 - 15424
[2]Chemical Communications,2015,vol. 51,p. 2957 - 2959
[3]Organic and Biomolecular Chemistry,2009,vol. 7,p. 58 - 60
[4]Organometallics,2014,vol. 33,p. 665 - 676
[5]Patent: JP2020/2024,2020,A .Location in patent: Paragraph 0102; 0103
[6]Polymer,2010,vol. 51,p. 437 - 446
[7]Dyes and Pigments,2016,vol. 133,p. 406 - 414
- 38
-
RuH(CO)Cl(P(CH3)3)3
[ No CAS ]
-
[ 152270-00-3 ]
-
[ 594-09-2 ]
-
[ 1215069-01-4 ]
- 39
-
[ 619-44-3 ]
-
[ 152270-00-3 ]
-
[ 1197887-62-9 ]
- 40
-
[ 609770-35-6 ]
-
[ 152270-00-3 ]
-
[ 1267583-42-5 ]
- 41
-
[ 1066-54-2 ]
-
1,4-dihalo-2,5-bis(dodecyloxy)benzene
[ No CAS ]
-
[ 152270-00-3 ]
- 42
-
[ 1275593-66-2 ]
-
[ 152270-00-3 ]
-
[ 1275593-58-2 ]
- 43
-
2-bromo-5-(4-hexylthiophen-2-yl)thieno[3,2-b]thiophene
[ No CAS ]
-
[ 152270-00-3 ]
-
[ 1330118-85-8 ]
- 44
-
[ 145483-66-5 ]
-
[ 152270-00-3 ]
Reference:
[1]Journal of Nanoscience and Nanotechnology,2010,vol. 10,p. 6800 - 6804
[2]Journal of the American Chemical Society,2011,vol. 133,p. 15412 - 15424
[3]Chemistry - A European Journal,2011,vol. 17,p. 13247 - 13257
[4]Dyes and Pigments,2016,vol. 133,p. 406 - 414
- 45
-
[ 1091632-52-8 ]
-
[ 152270-00-3 ]
-
[ 1290140-53-2 ]
- 46
-
[ 143-15-7 ]
-
[ 152270-00-3 ]
- 47
-
[ 123-31-9 ]
-
[ 152270-00-3 ]
- 48
-
[ 1353054-63-3 ]
-
[ 152270-00-3 ]
-
[ 1353054-64-4 ]
- 49
-
[ 1353054-13-3 ]
-
[ 152270-00-3 ]
-
[ 1353054-15-5 ]
- 50
-
[ 1353054-14-4 ]
-
[ 152270-00-3 ]
-
[ 1353054-16-6 ]
- 51
-
[ 7321-27-9 ]
-
[ 152270-00-3 ]
-
[ 1351101-41-1 ]
- 52
-
[ 1373930-60-9 ]
-
[ 152270-00-3 ]
-
C96H158O8
[ No CAS ]
- 53
-
[ 152270-00-3 ]
-
[ 523978-90-7 ]
-
[ 865649-64-5 ]
- 54
-
[ 152270-00-3 ]
-
C78H114O3Si2
[ No CAS ]
- 55
-
[ 18156-15-5 ]
-
[ 152270-00-3 ]
-
[ 1312589-42-6 ]
- 56
-
[ 18156-15-5 ]
-
[ 152270-00-3 ]
-
C84H125NO3Si3
[ No CAS ]
- 57
-
[ 152270-00-3 ]
-
[ 327622-22-0 ]
-
[ 1548646-05-4 ]
- 58
-
C58H75IO2
[ No CAS ]
-
[ 152270-00-3 ]
-
C150H202O6
[ No CAS ]
- 59
-
C58H75IO2
[ No CAS ]
-
[ 152270-00-3 ]
-
C150H202O6
[ No CAS ]
- 60
-
[ 14753-51-6 ]
-
[ 152270-00-3 ]
- 61
-
(5-bromo-15-((triisopropylsilyl)ethynyl)-10,20-bis(5-(2-ethylhexyl)thienyl)porphinato)zinc (II)
[ No CAS ]
-
[ 152270-00-3 ]
-
C144H186N8O2S4Si2Zn2
[ No CAS ]
- 62
-
[ 150-78-7 ]
-
[ 152270-00-3 ]
- 63
-
[ 51560-21-5 ]
-
[ 152270-00-3 ]
- 64
-
[ 13064-64-7 ]
-
[ 152270-00-3 ]
- 65
-
[ 152270-00-3 ]
-
[ 145483-66-5 ]
-
C94H156I2O6
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
35% |
|
Compound 15 (0.12 g, 2.43 × 10 -4 mol) and Compound 10 (0.41 g, 5.82 × 10 -4 mol) were dissolved in toluene (7 mL),Add copper iodide (1. 4 mg, 7.29 × 10 -6 mol), and the mixture was stirred under a nitrogen stream for 30 minutes.Thereafter, Pd (PPh3) 4 (8.4 mg, 7.29 × 10 -6 mol) and 7 mL of TEA were added to the reaction solution,The mixture was stirred and refluxed at 90 C. overnight. After the reaction, the solvent was distilled off under reduced pressure, and silica was removed.Purification was performed twice by gel column chromatography (CH2Cl2: hexane = 1: 2).Thus, Compound 16 was obtained as a yellow solid (yield 0.14 g, 35.0%). |