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Chemical Structure| 1535192-99-4 Chemical Structure| 1535192-99-4

Structure of 1535192-99-4

Chemical Structure| 1535192-99-4

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Product Details of [ 1535192-99-4 ]

CAS No. :1535192-99-4
Formula : C11H18O3
M.W : 198.26
SMILES Code : O[C@H]1C[C@H](CC=C)[C@]2([H])[C@@]1([H])OC(C)(C)O2

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Application In Synthesis of [ 1535192-99-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1535192-99-4 ]

[ 1535192-99-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1535192-99-4 ]
  • [ 309947-86-2 ]
  • [ 1535193-01-1 ]
YieldReaction ConditionsOperation in experiment
75% With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20℃; for 12h;Inert atmosphere; Mitsunobu coupling of 28 (2.1 g, 11 mmol) with 15 (5.0 g, 15 mmol) by the same procedure for the synthesis of 17 afforded 29 (4.1 g, 75%) as a white foam; 1H NMR (400 MHz, CDCl3) delta 8.82 (s, 1H), 8.08 (s, 1H), 5.81 (ddt, J=17.2, 10.4, 6.8 Hz, 1H), 5.08 (td, J=17.2, 1.2 Hz, 2H), 5.08 (d, J=13.2 Hz, 1H). 4.75 (dd, J=11.2, 6.0 Hz, 1H), 4.50 (dd, J=7.2, 4.8 Hz, 1H), 2.48-2.38 (m, 2H), 2.33-2.20 (m, 3H), 1.54 (s, 3H), 1.44 (s, 18H), 1.28 (s, 3H); 13C NMR (100.6 MHz, CDCl3) delta 153.3, 151.9, 150.7, 150.5, 144.3, 129.7, 117.0, 114.0, 83.8, 83.4, 65.9, 62.3, 43.4, 37.5, 36.6, 27.9, 27.6, 25.2; HRMS (ESI-TOF) m/z: [M+H]+ calcd for C26H38N5O6 516.2822; Found 516.2798.
 

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