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Chemical Structure| 15396-00-6 Chemical Structure| 15396-00-6

Structure of 15396-00-6

Chemical Structure| 15396-00-6

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Product Details of [ 15396-00-6 ]

CAS No. :15396-00-6
Formula : C7H15NO4Si
M.W : 205.28
SMILES Code : CO[Si](OC)(CCCN=C=O)OC
MDL No. :MFCD00044990
InChI Key :FMGBDYLOANULLW-UHFFFAOYSA-N
Pubchem ID :84892

Safety of [ 15396-00-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H312-H314-H317-H330-H334
Precautionary Statements:P260-P264-P270-P271-P272-P280-P284-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P403+P233-P405-P501
Class:6.1(8)
UN#:2927
Packing Group:

Application In Synthesis of [ 15396-00-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 15396-00-6 ]

[ 15396-00-6 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 619-60-3 ]
  • [ 15396-00-6 ]
  • 4-(dimethylamino)phenyl N-[3-(trimethoxysilyl)propyl]carbamate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With dibutyltin dilaurate; In toluene; at 70 - 80℃; for 12h; Flanged four-necked flask (100 mL volume) equipped with stirring blade, thermometer, dropping funnel and cooling tube, Dehydrated toluene: 30 mL, 4- (dimethylamino) phenol: 6.86 g (0.05 mol), dibutyltin (IV) dilaurate: 17.13 mg (corresponding to 1000 ppm) were added and dissolved.Next, 10.27 g (0.05 mol) of (3-isocyanatopropyl) trimethoxysilane was weighed into the dropping funnel.While heating and maintaining the four-necked flask at 70 ° C.,(3-isocyanatopropyl) trimethoxysilane was added dropwise while stirring so that the internal temperature does not exceed 80 ° C.After completion of the dropwise addition, stirring was continued for 12 hours to ripen.After completion of ripening, the solvent was removed with an evaporator.The resulting compound was a very pale yellow oil,HPLC and FT-IR measurements of the compound were carried out.Analytical conditions for HPLC measurement are column ZORBAX-ODS,Acetonitrile / distilled water = 7/3, flow rate 0.5 mL / min,Multi-scan UV detector,RI detector, MS detector.The FT-IR measurement was carried out by the ATR method.As a result of HPLC measurement, the raw materials 4- (dimethylamino) phenol and (3-isocyanatopropyl) trimethoxysilane disappeared and a new peak: 4- (dimethylamino) phenyl (3- (trimethoxysilyl) propyl ) Carbamate (molecular weight 342.5) was confirmed. As a result of FT-IR measurement,Absorption of isocyanate group and absorption and disappearance of phenol group were confirmed.The structural formula of the synthesized 4- (dimethylamino) phenyl (3- (trimethoxysilyl) propyl) carbamate is shown below.
  • 2
  • [ 1585-90-6 ]
  • [ 15396-00-6 ]
  • C12H20N2O7Si [ No CAS ]
YieldReaction ConditionsOperation in experiment
80% With dibutyltin dilaurate; In toluene; at 50 - 58℃;Inert atmosphere; [0031] In a 250mL 3 necked flask equipped with a magnetic stir bar and nitrogen inlet was taken isocyantopropyltrimethoxysilane (20.94g, 102mmol) in toluene (150mL). Under nitrogen atmosphere, this mixture was heated to 50°C and two drops of dibutyltin dilaurate was added. 2-hydroxyethylmaleimide (14.4g, 102mmol) was added in portions. The temperature varied in the range 50-58°C during the addition. Initially there was drop in temperature during the addition but the temperature then increased due to urethane formation. After the addition was complete, an IR was run on the sample and it showed near complete disappearance of the isocyanate band. There were peaks at 3300cm-1 for the urethane NH, and two carbonyl bands around 1700cm"1 for the maleimide and the urethane carbonyls. The mixture was transferred to a 500mL flask and the solvent evaporated. During evaporation, the material solidified. The solvent was stripped off for about 2h at 53°C and cooled to r.t. under nitrogen atmosphere. 100ml_ of heptane was added and the contents stirred and the heptane was decanted. The operation was repeated again. Last traces of heptane was stripped of in rotovap under vacuum. This gave the maleimide functional silane 4 as a white solid (28.2g, 80percent).
  • 3
  • [ 1709-71-3 ]
  • [ 15396-00-6 ]
  • C17H29NO9Si [ No CAS ]
YieldReaction ConditionsOperation in experiment
With octyl sulfoxide; at 80℃; for 2h; In a 1 L separable flask equipped with a stirrer, a reflux condenser, a dropping funnel and a thermometer, 205 g (1 mol) of 3-isocyanatopropyltrimethoxysilane and 0.04 g of dioctyl tin oxide were placed and heated to 80 C. Into this, 214 g (1 mol) of <strong>[1709-71-3]2-hydroxy-3-acryloyloxypropyl methacrylate</strong> (manufactured by Shin-Nakamura Chemical Co., Ltd., 701A) was added dropwise, and the mixture was stirred at 80 C. for 2 hours. After that, it was confirmed by IR measurement that the absorption peak derived from the isocyanate group of the raw material completely disappeared, and it was considered that the reaction was completed. Silica gel 60N (Kanto Chemical Co., Ltd. product) 8g was added, and it stirred at 25 degreeC for 3 hours. The product obtained by filtration was a pale yellow transparent liquid, which was confirmed by 1H-NMR to be a compound represented by the following formula (11). The tin content in the product was 15 ppm by weight.
 

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