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[ CAS No. 154065-33-5 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 154065-33-5
Chemical Structure| 154065-33-5
Structure of 154065-33-5 * Storage: {[proInfo.prStorage]}
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Product Details of [ 154065-33-5 ]

CAS No. :154065-33-5 MDL No. :MFCD18398076
Formula : C7H3BrF3IO Boiling Point : -
Linear Structure Formula :- InChI Key :LKNNUQZUTTXEKA-UHFFFAOYSA-N
M.W :366.90 Pubchem ID :58178544
Synonyms :

Safety of [ 154065-33-5 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 154065-33-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 154065-33-5 ]

[ 154065-33-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 886762-08-9 ]
  • [ 154065-33-5 ]
YieldReaction ConditionsOperation in experiment
52% With copper(l) iodide; tert.-butylnitrite; In acetonitrile; at 60℃; for 1h; 10.74 g (93.75 mmol) of tert-butyl nitrite and 28.5 g (150 mmol) of copper iodide are suspended in 270 ml of acetonitrile and heated to 60 C. A solution of 15 g (62.5 mmol) of <strong>[886762-08-9]5-bromo-2-trifluoromethoxyaniline</strong> in 130 ml of acetonitrile is slowly added dropwise to this suspension and the mixture is left to stir at 60 C. for another hour. The reaction solution is then poured on to a mixture of 250 ml of 2 N aqueous HCl and 250 ml of ethyl acetate. The organic phase is washed twice more with aqueous NaCl solution, filtered through a little silica gel and concentrated. The residue is separated by chromatography on silica gel (ethyl acetate/n-heptane=1/18). This affords 12.2 g (52% yield) of product 96 as a colorless oil.
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