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[ CAS No. 1544673-40-6 ] {[proInfo.proName]}

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Chemical Structure| 1544673-40-6
Chemical Structure| 1544673-40-6
Structure of 1544673-40-6 * Storage: {[proInfo.prStorage]}
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Product Details of [ 1544673-40-6 ]

CAS No. :1544673-40-6 MDL No. :MFCD18729959
Formula : C13H18BClO3 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 268.54 Pubchem ID :-
Synonyms :

Safety of [ 1544673-40-6 ]

Signal Word:Warning Class:
Precautionary Statements:P210-P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378-P403+P233-P403+P235-P405-P501 UN#:
Hazard Statements:H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1544673-40-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1544673-40-6 ]

[ 1544673-40-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1150114-78-5 ]
  • [ 1544673-40-6 ]
  • 2
  • [ 1112209-14-9 ]
  • [ 1544673-40-6 ]
YieldReaction ConditionsOperation in experiment
314 mg With sodium tetrahydroborate; at 20.0℃; for 5.0h; General procedure: To a mixture of a4-formylbenzenboronic acid (1a, 375 mg, 2.50 mmol), pinacol (355 mg, 3.00 mmol) and anhydrous magnesium sulfate (625 mg, 5.00 mmol), methanol was added (12.50 mL). The mixture was stirred at room temperature for 6 h. After the reaction was completed, the crude solution was filtered, and then sodium borohydride (47 mg, 1.25 mmol) was added to the filtrate. Afterwards, the reaction mixture was stirred for an additional 5 h. Once the reaction was completed, the reaction mixture was filtered and the filtrate was concentrated in vacuo to give the desired product 2a as a white solid (m.p. 75-77 C) in88% yield (513 mg). 1H-NMR (CD3OD-d4) delta ppm 7.71 (d, J = 8.0 Hz, 2H), 7.35 (d, J = 7.8 Hz, 2H),4.62 (s, 2H), 1.34 (s, 12H); 13C-NMR (CD3OD-d4) delta ppm 146.23, 135.93, 127.26, 85.19, 65.24, 25.34;11B-NMR (CDCl3) delta ppm 34.82.
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