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Chemistry
Heterocyclic Building Blocks
Benzothiazoles
other-benzothiazole
2-Mercaptobenzothiazolezincsalt
Chemistry
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Heterocyclic Building Blocks
Transition metal
Benzothiazoles
Zinc
other-benzothiazole

[ CAS No. 155-04-4 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
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3d Animation Molecule Structure of 155-04-4
Chemical Structure| 155-04-4
Chemical Structure| 155-04-4
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Quality Control of [ 155-04-4 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification
Alternatived Products of [ 155-04-4 ]

Product Details of [ 155-04-4 ]

CAS No. :155-04-4 MDL No. :MFCD00072234
Formula : C14H8N2S4Zn Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 397.90 Pubchem ID :-
Synonyms :

Safety of [ 155-04-4 ]

Signal Word:Danger Class:9
Precautionary Statements:P501-P273-P260-P270-P264-P280-P391-P314-P337+P313-P305+P351+P338-P301+P312+P330 UN#:3077
Hazard Statements:H302-H319-H372-H410 Packing Group:Ⅲ
GHS Pictogram:

Application In Synthesis of [ 155-04-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 155-04-4 ]

[ 155-04-4 ] Synthesis Path-Downstream   1~16

  • 1
  • [ 615-20-3 ]
  • [ 155-04-4 ]
  • [ 4074-77-5 ]
YieldReaction ConditionsOperation in experiment
In chlorobenzene Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
  • 2
  • [ 2407-11-6 ]
  • [ 155-04-4 ]
  • [ 91960-67-7 ]
YieldReaction ConditionsOperation in experiment
In benzene Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
  • 3
  • [ 105-39-5 ]
  • [ 155-04-4 ]
  • [ 24044-88-0 ]
YieldReaction ConditionsOperation in experiment
In chlorobenzene for 8h; Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
  • 4
  • [ 88-11-9 ]
  • [ 155-04-4 ]
  • [ 95-30-7 ]
YieldReaction ConditionsOperation in experiment
In benzene Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
  • 5
  • [ 155-04-4 ]
  • [ 97-00-7 ]
  • [ 4230-91-5 ]
YieldReaction ConditionsOperation in experiment
In chlorobenzene for 7h; Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
  • 6
  • [ 155-04-4 ]
  • [ 16420-13-6 ]
  • [ 3432-25-5 ]
YieldReaction ConditionsOperation in experiment
In benzene Heating;
Reference： [1]Cherntsov,O.M.; Chalykh,E.A. [Journal of general chemistry of the USSR, 1963, vol. 33, p. 1905 - 1910][Zhurnal Obshchei Khimii, 1963, vol. 33, p. 1958 - 1964]
YieldReaction ConditionsOperation in experiment
beim Stehen d. Lsg. in Chloroform scheidet sich die Form(2) ab: (MBT)5Zn3OH;
YieldReaction ConditionsOperation in experiment
beim Behandeln von 2-Mercapto-benzothiazol mit d. wss. Lsg. eines Zinksalzes;
  • 9
  • [ 155-04-4 ]
  • zinc sulfide [ No CAS ]
YieldReaction ConditionsOperation in experiment
In further solvent(s) addn. of oleylamine to Zn(Mer)2, vac. evapn. at 100 °C for 30 min, cooling to room temp. Zn(Mer)2 addn., Ar bubbling for 20 min, flash heating to 270 °C for 3.5 h - 12 h in inert atmosphere; centrifugation, washing (EtOH), vac. drying;
Reference： [1]Geng; Liu; Ma; Du; Zhang [Applied Physics Letters, 2007, vol. 90, # 18]
  • 10
  • [ 557-34-6 ]
  • [ 149-30-4 ]
  • [ 155-04-4 ]
YieldReaction ConditionsOperation in experiment
In ethanol mixing the soln. of Zn(CH3CO2)2 and 2-mercaptobenzothiazole with stirring, 30 min cooling in ice water bath, filtration; collection of the precipitate, washing (de-ionized water), vac. drying at 60 °C overnight;
Reference： [1]Geng; Liu; Ma; Du; Zhang [Applied Physics Letters, 2007, vol. 90, # 18]
  • 11
  • [ 149-30-4 ]
  • [ 5970-45-6 ]
  • [ 155-04-4 ]
YieldReaction ConditionsOperation in experiment
85% In ethanol addn. of Zn-compound to hot soln. of ligand with stirring;; filtration of ppt.; washed (EtOH); dried (vacuum, 80°C);
Reference： [1]Baggio, Ricardo; Garland, Maria Teresa; Perec, Mireille [Journal of the Chemical Society, Dalton Transactions, 1993, # 22, p. 3367 - 3372]
  • 12
  • [ 66-71-7 ]
  • [ 155-04-4 ]
  • zinc(II)(benzothiazole-2-thiolate)2(1,10-phenanthroline) [ No CAS ]
YieldReaction ConditionsOperation in experiment
70% In chloroform; N,N-dimethyl-formamide addn. of ligand in CHCl3/DMF to suspn. fo Zn-compound in CHCl3 at room temp.; stirred for 12 h at 60°C;; filtration; filtrate allowed to stand at room temp. for 2 weeks; pptn.; vacuum filtration; elem. anal.;
Reference： [1]Baggio, Ricardo; Garland, Maria Teresa; Perec, Mireille [Journal of the Chemical Society, Dalton Transactions, 1993, # 22, p. 3367 - 3372]
  • 13
  • [ 155-04-4 ]
  • [ 152272-24-7 ]
YieldReaction ConditionsOperation in experiment
85% With (C5H4N)2 In chloroform; N,N-dimethyl-formamide addn. of ligand in CHCl3/DMF to suspn. fo Zn-compound in CHCl3 at room temp.; stirred for 2 h;; filtration; filtrate allowed to stand at room temp. for 5 d; pptn.; vacuum filtration; washing (acetone); elem. anal.;
Reference： [1]Baggio, Ricardo; Garland, Maria Teresa; Perec, Mireille [Journal of the Chemical Society, Dalton Transactions, 1993, # 22, p. 3367 - 3372]
  • 14
  • [ 155-04-4 ]
  • [ 14740-86-4 ]
YieldReaction ConditionsOperation in experiment
80% With pyridine In pyridine slow addn. of Zn-compound to dry pyridine at room temp. with stirring;; filtration; filtrate allowed to stand for 1 week at room temp.; pptn.; filtration; crystals dried (N2-stream); elem. anal.;
Reference： [1]Baggio, Ricardo; Garland, Maria Teresa; Perec, Mireille [Journal of the Chemical Society, Dalton Transactions, 1993, # 22, p. 3367 - 3372]
  • 15
  • [ 149-30-4 ]
  • [ 155-04-4 ]
YieldReaction ConditionsOperation in experiment
With carbon dioxide; ammonia; potassium hydroxide; zinc(II) oxide In water at 50 - 100℃; 2 Prepare 600 grams of solution A as in Example 1 with 9.56% zinc. Add 243 grams of 2-mercaptobenzothiazole with acid value of 327 mg of KOH per gram and melting point of about 180° C. to the solution. Stir and warm the solution to 50° C. for one hour. The pH of this solution is measured at 10.67. Heat the solution to boil off the ammonia and carbon dioxide. The solution boils at about 60° C. to 90° C. When all the ammonia is boiled out the temperature rises to 100° C. and the pH drops to 8.57. Cool the mixture to 25° C. Filter the mixture and dry the white precipitate at 150° C. for 6 hours, and then and mill it to obtain zinc 2-mercaptobenzothiazole (ZMBT), sample No. ZMBT-A, with the following properties: Commercial ZMBT A ZMBT Zinc (wt. %) 18.56 17.42 Acid Value (mg KOH/g) 52.07 50 Melting point (° C.) 330 (dec) 330 (dec) pH 7.57 7.88 Bulk density (g/cm3) 0.58 0.6 Residue on 150 Mesh Sieve 0.1 2.4 (wt. %) This material has comparable characteristics to commercial zinc 2-mercaptobenzothiazole obtained from Master Glove (commercial ZMBT).
Reference： [1]Current Patent Assignee: NIE ER - US2010/168230, 2010, A1 Location in patent: Page/Page column 5
  • 16
  • [ 149-30-4 ]
  • [ 7733-02-0 ]
  • [ 155-04-4 ]
YieldReaction ConditionsOperation in experiment
99.5% In water Milling; Green chemistry; 2 Example 2 In a 45 mL ball mill reactor 8 diameter 2mm chrome steel ball were placed, 2-mercaptobenzothiazole (2.67 g, 16 mmol) was added sequentially, zinc sulfate (1.61 g, 10 mmol), water (lmL), feeding finished, the reactor was sealed and placed in a ball mill at a rotational speed of 300 revolutions per minute for 5 minutes and a pause of 30 seconds for one cycle. After four cycles, TLC tracking indicated the consumption of 2-mercaptobenzothiazole was complete and the reaction mixture was washed with water (5 mL X3)Filtration and drying the filter cake yielded 3.17 g of the solid product in 99.5% yield. X-ray powder diffraction of the sample is shown in Fig. 2. The interplanar spacing d = 13.2999, 9.6207, 8.9702, 7.3719, 6.5067, 5.6519, 5.2328 Am belongs to the characteristic peak of zinc-2-mercaptobenzothiazole.
Reference： [1]Current Patent Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY - CN103772316, 2016, B Location in patent: Paragraph 0022-0023

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