Structure of 15625-89-5
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The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
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Petko, Filip ; Jankowska, Magdalena ; Galek, Mariusz ; Noworyta, Małgorzata ; Popielarz, Roman ; Ortyl, Joanna
Abstract: New advanced iodonium salts based on stilbene chromophores with significantly improved photoinitiating properties are presented. The extended conjugated double bond system provides major improvement in quantum yield of superacid generation (up to 10 times higher compared to benzylidene-based iodonium salts) while maintaining absorption properties in UV-A and visible light. The newly developed iodonium salts exhibit photoinitiating activity toward cationically polymerizable monomers such as cyclic epoxy monomers (e.g., 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexane-carboxylate (CADE)), oxetanes(e.g., bis[1-ethyl(3-oxetanyl)]methyl ether (OXT-221)) and glycidyl ether monomers (e.g., diglycidyl ether of bisphenol A(DGEBA)) under the irradiation by light-emitting diodes (LEDs) emitting at 365, 405 and even 430 nm, with no additives. Commonly used diaryliodonium photoinitiators are inactive under those irradiation wavelengths. Moreover, some of the new iodonium salts are also able to photoinitiate free radical photopolymerization of the acrylate monomers, such as trimethylolpropanetriacrylate (TMPTA). Such high photoinitiating activity allows these salts to be used as one-component photoinitiators in cationic vat 3D printing of nanocomposites at ambient temperature. The resolution of the cationic prints was limited mainly by the DLP 3Dprinter and monomers, with slight signs of overpolymerization
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Katarzyna Starzak ; Wiktoria Tomal ; Anna Chachaj-Brekiesz ; Mariusz Galek ; Joanna Ortyl ;
Abstract: Herein, the application of previously unknown azulene derivatives as effective panchromatic photosensitizers in the visible light range in the initiation of light-induced cationic and free-radical polymerization processes was investigated. The presented azulene derivatives showed a high photoreodox potential allowing the use of these compounds in two-component and three-component photoinitiating systems for various photopolymerization processes. In addition, within the scope of this manuscript, the effectiveness of using photoinitiating systems containing the proposed azulene derivatives in 3D printing to obtain three-dimensional polymer structures has been confirmed and for the first time proven in the literature.
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Filip Petko ; Emilia Hol ; Magdalena Jankowska ; Alicja Gruchała-Hałat ; Joanna Ortyl ;
Abstract: In this article, the application of 10 new amino-m-terphenyls in 3D-VAT printing was described. New compounds have specially designed D-π-A structure, where the central phenyl ring with nitrile and amino groups is the acceptor and the modifiable amino group is donor. Such design eliminates problem with acid scavenging and guaranteed desire properties and photoactivity as well as it allows further development of such system for 3D-VAT printing. Efficient excitation with intramolecular charge transfer provides excellent absorption and electrochemical properties, which can be tuned by modification of the amino group. The design allows photoinitiation of free radical, hybrid and especially cationic polymerisation even at 455 nm with more than 70% of monomer conversion. Such properties allow to use the developed compounds as efficient visible light photoinitiators for 3D printing of nanocomposite materials. The terphenyls can efficiently cure resins containing CuO and Al2O3 nano additives leading to high-resolution 3D prints.
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CAS No. : | 15625-89-5 |
Formula : | C15H20O6 |
M.W : | 296.32 |
SMILES Code : | C=CC(OCC(CC)(COC(C=C)=O)COC(C=C)=O)=O |
MDL No. : | MFCD00008628 |
InChI Key : | DAKWPKUUDNSNPN-UHFFFAOYSA-N |
Pubchem ID : | 27423 |
GHS Pictogram: |
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Signal Word: | Warning |
Hazard Statements: | H315-H319-H317-H351 |
Precautionary Statements: | P501-P261-P202-P201-P264-P280-P272-P308+P313-P337+P313-P305+P351+P338-P302+P352-P333+P313-P362-P405 |
Tags: 15625-89-5 synthesis path| 15625-89-5 SDS| 15625-89-5 COA| 15625-89-5 purity| 15625-89-5 application| 15625-89-5 NMR| 15625-89-5 COA| 15625-89-5 structure
A479488 [94108-97-1]
Di(Trimethylolpropane)tetraacrylate
Similarity: 1.00
A642695 [29570-58-9]
Dipentaerythritol hexaacrylate
Similarity: 0.93
A827242 [67905-41-3]
Cyclohexane-1,4-diylbis(methylene) diacrylate
Similarity: 0.87
A479488 [94108-97-1]
Di(Trimethylolpropane)tetraacrylate
Similarity: 1.00
A642695 [29570-58-9]
Dipentaerythritol hexaacrylate
Similarity: 0.93
A827242 [67905-41-3]
Cyclohexane-1,4-diylbis(methylene) diacrylate
Similarity: 0.87
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P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
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P230 | Keep wetted |
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P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
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P263 | Avoid contact during pregnancy/while nursing. |
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P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
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P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
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P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
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P321 | |
P322 | |
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P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
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P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
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P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
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P378 | |
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P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
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P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
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P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
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H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
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