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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
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Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 16068-37-4 Chemical Structure| 16068-37-4

Structure of 16068-37-4

Chemical Structure| 16068-37-4

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Product Details of [ 16068-37-4 ]

CAS No. :16068-37-4
Formula : C14H34O6Si2
M.W : 354.59
SMILES Code : CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC
MDL No. :MFCD00239362
InChI Key :IZRJPHXTEXTLHY-UHFFFAOYSA-N
Pubchem ID :85266

Safety of [ 16068-37-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H312-H372-H412
Precautionary Statements:P264-P270-P280-P301+P310-P302+P352-P312-P330-P362+P364-P405-P501
Class:6.1
UN#:2810
Packing Group:

Application In Synthesis of [ 16068-37-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 16068-37-4 ]

[ 16068-37-4 ] Synthesis Path-Upstream   1~23

  • 1
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YieldReaction ConditionsOperation in experiment
87% at 60 - 120℃; for 3 h; Inert atmosphere Weigh 468g of ethanol into the constant pressure dropping funnel, while 500gbis (trichloro) silylethane into a three-neck flask, heated in an oil bath, while the temperature rose to at 60 , open magnetic stirrer was slowly added dropwise 1 / 3 parts of ethanol, while nitrogen gas bubbling hydrogen chloride off reaction, the dropwise addition 40min; temperature was raised to 90 deg.] C, was added dropwise 1/3 parts ethanol, 50min dropwise addition, reaction was continued for 30min; temperature was raised to 120 deg.] C, continue the remaining solution of ethanol, 60min dropping end. After the addition, continue nitrogen until the solution Cl- content of less than 1percent, the reaction was stopped. Was added dropwise a solution of sodium ethoxide was neutralized, until the solution was neutral, the solution was filtered to remove salt wherein the resulting liquid was filtered at a vacuum degree of 0.08Mpa ~ 0.098Mpa, a temperature of 120 ~ 160 distillation under reduced pressure to give the product as a colorless bis (triethoxysilyl) ethane silicon, the final quantity was 522 g, 87percent yield of the final product.
References: [1] Patent: CN105367597, 2016, A, . Location in patent: Paragraph 0021.
[2] Russian Journal of General Chemistry, 2001, vol. 71, # 8, p. 1252 - 1254.
[3] , 1952, vol. 3, p. 65,69,73.
[4] Doklady Akademii Nauk SSSR, 1952, vol. 87, p. 601[5] Chem.Abstr., 1954, p. 114.
  • 2
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  • [ 692-52-4 ]
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References: [1] Patent: US2012/123143, 2012, A1, . Location in patent: Page/Page column 3.
  • 3
  • [ 87061-56-1 ]
  • [ 16068-37-4 ]
References: [1] Patent: US2012/123143, 2012, A1, . Location in patent: Page/Page column 4.
  • 4
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  • [ 78-08-0 ]
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References: [1] Journal of Organometallic Chemistry, 1986, vol. 301, p. 209 - 226.
[2] Journal of Organometallic Chemistry, 1986, vol. 301, p. 209 - 226.
[3] Patent: JP5652360, 2015, B2, . Location in patent: Paragraph 0048; 0049.
  • 5
  • [ 64-17-5 ]
  • [ 4364-07-2 ]
  • [ 16068-37-4 ]
References: [1] ACS Catalysis, 2018, vol. 8, # 3, p. 2558 - 2566.
  • 6
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References: [1] J. Gen. Chem. USSR (Engl. Transl.), 1984, vol. 54, # 2, p. 316 - 318[2] Zhurnal Obshchei Khimii, 1984, vol. 54, # 2, p. 354 - 356.
[3] Journal of the American Chemical Society, 1999, vol. 121, # 23, p. 5413 - 5425.
[4] Journal of Organometallic Chemistry, 1986, vol. 299, p. 143 - 148.
[5] J. Gen. Chem. USSR (Engl. Transl.), 1987, p. 1548 - 1553[6] Zhurnal Obshchei Khimii, 1987, vol. 57, # 8, p. 1735 - 1741.
[7] Applied Organometallic Chemistry, 2019, vol. 33, # 6, .
  • 7
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  • [ 74-86-2 ]
  • [ 78-08-0 ]
  • [ 16068-37-4 ]
References: [1] Journal of Organometallic Chemistry, 1980, vol. 195, # 3, p. 363 - 374.
[2] Journal of Organometallic Chemistry, 1980, vol. 195, # 3, p. 363 - 374.
[3] Journal of Organometallic Chemistry, 1980, vol. 195, # 3, p. 363 - 374.
[4] Journal of Organometallic Chemistry, 1983, vol. 251, # 1, p. 39 - 44.
[5] J. Gen. Chem. USSR (Engl. Transl.), 1986, vol. 56, p. 1844 - 1847[6] Zhurnal Obshchei Khimii, 1986, vol. 56, # 9, p. 2092 - 2095.
[7] Gmelin Handbuch, Gmelin Handbook: Si: MVol.C, 70, page 194 - 196, .
[8] Organometallics, 2011, vol. 30, # 2, p. 352 - 355.
[9] Patent: US2637738, 1949, , .
[10] Gmelin Handbuch, Gmelin Handbook: Si: MVol.C, 132, page 365 - 367, .
[11] Patent: US2637738, 1949, , .
[12] Patent: US2637738, 1949, , .
  • 8
  • [ 998-30-1 ]
  • [ 74-86-2 ]
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References: [1] Doklady Chemistry, 1980, vol. 254, p. 449 - 451[2] Dokl. Akad. Nauk SSSR Ser. Khim., 1980, vol. 254, # 4, p. 887 - 890.
[3] Patent: US2637738, 1949, , .
[4] Gmelin Handbuch, Gmelin Handbook: Si: MVol.C, 82, page 228 - 229, .
[5] Patent: US2637738, 1949, , .
  • 9
  • [ 998-30-1 ]
  • [ 78-08-0 ]
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  • [ 87061-56-1 ]
References: [1] Polish Journal of Chemistry, 1982, vol. 56, # 2, p. 287 - 296.
[2] Polish Journal of Chemistry, 1982, vol. 56, # 2, p. 287 - 296.
  • 10
  • [ 15267-95-5 ]
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References: [1] Russian Journal of General Chemistry, 2006, vol. 76, # 10, p. 1564 - 1570.
  • 11
  • [ 78-08-0 ]
  • [ 540-63-6 ]
  • [ 16068-37-4 ]
References: [1] Catalysis Letters, 2014, vol. 144, # 5, p. 935 - 942.
  • 12
  • [ 2504-64-5 ]
  • [ 16068-37-4 ]
References: [1] , 1952, vol. 3, p. 65 - 76[2] C. A., 1954, p. 9907.
[3] Doklady Akademii Nauk SSSR, 1952, vol. 87, p. 601 - 603[4] C. A., 1954, p. 113.
[5] Gmelin Handbuch, Gmelin Handbook: Si: MVol.C, 82, page 228 - 229, .
  • 13
  • [ 998-30-1 ]
  • [ 78-08-0 ]
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  • [ 52885-14-0 ]
References: [1] Journal of Organometallic Chemistry, 1994, vol. 484, # 1-2, p. 147 - 152.
  • 14
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  • [ 78-07-9 ]
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References: [1] Journal of Organometallic Chemistry, 2000, vol. 597, # 1-2, p. 175 - 181.
  • 15
  • [ 998-30-1 ]
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  • [ 78-07-9 ]
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References: [1] Organometallics, 2011, vol. 30, # 2, p. 352 - 355.
  • 16
  • [ 998-30-1 ]
  • [ 74-86-2 ]
  • [ 78-07-9 ]
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  • [ 87061-56-1 ]
References: [1] Organometallics, 2011, vol. 30, # 2, p. 352 - 355.
  • 17
  • [ 998-30-1 ]
  • [ 78-08-0 ]
  • [ 78-07-9 ]
  • [ 16068-37-4 ]
  • [ 52885-14-0 ]
References: [1] Journal of Organometallic Chemistry, 1994, vol. 484, # 1-2, p. 147 - 152.
  • 18
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  • [ 78-10-4 ]
  • [ 16068-37-4 ]
  • [ 87061-56-1 ]
  • [ 52885-14-0 ]
  • [ 137963-74-7 ]
References: [1] Journal of Organometallic Chemistry, 1996, vol. 521, # 1-2, p. 245 - 251.
  • 19
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  • [ 78-08-0 ]
  • [ 78-07-9 ]
  • [ 16068-37-4 ]
  • [ 87061-56-1 ]
References: [1] Polish Journal of Chemistry, 1982, vol. 56, # 2, p. 287 - 296.
[2] Polish Journal of Chemistry, 1982, vol. 56, # 2, p. 287 - 296.
  • 20
  • [ 998-30-1 ]
  • [ 78-08-0 ]
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References: [1] Polish Journal of Chemistry, 1996, vol. 70, # 2, p. 253 - 258.
  • 21
  • [ 998-30-1 ]
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  • [ 16068-37-4 ]
  • [ 87061-56-1 ]
  • [ 52885-14-0 ]
  • [ 137963-74-7 ]
References: [1] Journal of Organometallic Chemistry, 1993, vol. 454, # 1-2, p. 45 - 50.
  • 22
  • [ 998-30-1 ]
  • [ 78-08-0 ]
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  • [ 78-10-4 ]
  • [ 16068-37-4 ]
  • [ 52885-14-0 ]
  • [ 137963-74-7 ]
  • [ 91458-95-6 ]
References: [1] Journal of Organometallic Chemistry, 1991, vol. 418, # 1, p. 61 - 67.
  • 23
  • [ 998-30-1 ]
  • [ 78-08-0 ]
  • [ 78-07-9 ]
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  • [ 52885-14-0 ]
References: [1] Journal of Organometallic Chemistry, 1994, vol. 484, # 1-2, p. 147 - 152.
 

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