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[ CAS No. 1613389-28-8 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 1613389-28-8
Chemical Structure| 1613389-28-8
Structure of 1613389-28-8 * Storage: {[proInfo.prStorage]}
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Product Details of [ 1613389-28-8 ]

CAS No. :1613389-28-8 MDL No. :N/A
Formula : C34H42S6 Boiling Point : -
Linear Structure Formula :- InChI Key :WPOFHNVMLKEBQF-UHFFFAOYSA-N
M.W : 643.09 Pubchem ID :132565036
Synonyms :

Safety of [ 1613389-28-8 ]

Signal Word:Warning Class:
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 UN#:
Hazard Statements:H315-H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1613389-28-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1613389-28-8 ]

[ 1613389-28-8 ] Synthesis Path-Downstream   1~5

  • 1
  • [ 1613389-28-8 ]
  • [ 2460300-90-5 ]
YieldReaction ConditionsOperation in experiment
62% Stage #1: 4,8-bis(5-((2-ethylhexyl)thio)thiophen-2-yl)benzo[1,2-b:4,5-b']-dithiophene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere; Stage #2: With carbon tetrabromide In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
  • 2
  • [ 1613389-28-8 ]
  • [ 1066-45-1 ]
  • [ 1613389-30-2 ]
YieldReaction ConditionsOperation in experiment
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine at -78℃;
Stage #1: 4,8-bis(5-((2-ethylhexyl)thio)thiophen-2-yl)benzo[1,2-b:4,5-b']-dithiophene With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Stage #2: trimethyltin(IV)chloride In tetrahydrofuran at 20℃; for 3h;
With n-butyllithium
  • 3
  • [ 18908-66-2 ]
  • [ 1613389-28-8 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 1 h / 0 °C 1.2: 2 h 1.3: 20 °C 2.1: n-butyllithium / tetrahydrofuran / 1 h / 0 °C 2.2: 2 h / 50 °C 2.3: 2 h
Multi-step reaction with 2 steps 1: sulfur; lithium diisopropyl amide / -78 °C
  • 4
  • [ 32281-36-0 ]
  • [ 1330786-48-5 ]
  • [ 1613389-28-8 ]
YieldReaction ConditionsOperation in experiment
Stage #1: 2-(2-ethylhexylthio)thiophene With n-butyllithium In tetrahydrofuran at 0℃; for 1h; Stage #2: 4,8-dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-dione In tetrahydrofuran at 50℃; for 2h; Stage #3: With hydrogenchloride; tin(ll) chloride In tetrahydrofuran; water for 2h;
  • 5
  • 4,8-bis(5-((2-ethylhexyl)thio)thiophen-2-yl)benzo[1,2-b:4,5-b']-dithiophene [ No CAS ]
  • [ 18013-97-3 ]
  • C80H94O4S12 [ No CAS ]
YieldReaction ConditionsOperation in experiment
74% Compound a under nitrogen stream in 500 ml flask add (4,8-bis (5-((2-ethylhexyl)thio)thiophen-2-yl) benzo [1,2-b: 4,5-b '] dithiophene, 18 g, 0.0279 mol) and add THF 120 dissolved in ml and then at 0 C11.42 ml of n-BuLi (2.5M in hexane) was slowly added thereto and stirred at 50C for 1 hour 30 minutes. After stirring, cooled to -78C and dried a solution of ZnCl 2 (3.81 g, 0.0279 mol) dissolved in THF was added to the reaction mixture, followed by stirring at 0 C. for 1 hour and 30 minutes.Pd (PPh3) 4 (0.65 g, 0.00056 mol) and diethyl 2,5-dibromoterephthalate (diethyl 2,5-dibromoterephthalate, 4.25 g, 0.011196 mol) were added thereto, and the mixture was refluxed and stirred for 12 hours. After completion of the reaction, the mixture was extracted with water and dichloromethane (MC), dried over MgSO 4 and column chromatography (hexane: MC = 2: 1) to proceed was obtained compound b (12.6 g, 74%).
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