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Chemical Structure| 162010-78-8 Chemical Structure| 162010-78-8

Structure of 162010-78-8

Chemical Structure| 162010-78-8

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Product Details of [ 162010-78-8 ]

CAS No. :162010-78-8
Formula : C8H6ClNO6S
M.W : 279.65
SMILES Code : O=C(OC)C1=CC=C(S(=O)(Cl)=O)C([N+]([O-])=O)=C1
MDL No. :MFCD09863389

Safety of [ 162010-78-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H290
Precautionary Statements:P501-P260-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 162010-78-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 162010-78-8 ]

[ 162010-78-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 34402-78-3 ]
  • [ 162010-78-8 ]
  • C15H14N2O8S [ No CAS ]
YieldReaction ConditionsOperation in experiment
Potassium tert-butoxide (1 M, 39.17 mL) and THF (50 mL) were added into a pre-dried 500 mL three-necked flask, and then vacuumized and purged with nitrogen gas for three times. After the mixture was cooled to 0C, a solution of WX186-1 (5 g, 32.64 mmol) in THF (50 mL) was added dropwise at a temperature of 0-5C. After completion of the addition, the solution was heated to 25C and stirred for 20 minutes, and the mixture became a white suspension. After cooling down to 0C, a solution of BB-6-1 (10.95 g, 39.17 mmol) in THF (100 mL) was slowly added dropwise below 5C. The color of the solution turned deep red. After completion of the addition, the solution was heated to 25C and stirred for 12 hours, and the color of the solution turned yellow. The reaction mixture was poured into 300 mL of water to quench the reaction, extracted with ethyl acetate (300 mL). The combined organic phase was washed with 250 mL saturated brine and dried over anhydrous sodium sulfate, followed by filtration. The filtrate was collected, and evaporated under reduced pressure to remove the solvent to give BB-6-2.
 

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