Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 167298-52-4 Chemical Structure| 167298-52-4

Structure of 167298-52-4

Chemical Structure| 167298-52-4

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 167298-52-4 ]

CAS No. :167298-52-4
Formula : C8H18N2
M.W : 142.24
SMILES Code : N[C@H]1CC[C@H](N(C)C)CC1
MDL No. :MFCD20617654

Safety of [ 167298-52-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H227
Precautionary Statements:P210-P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378-P403+P235-P405-P501
Class:8
UN#:2735
Packing Group:

Application In Synthesis of [ 167298-52-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 167298-52-4 ]

[ 167298-52-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 64-18-6 ]
  • [ 62226-17-9 ]
  • [ 167298-52-4 ]
  • 1-N,1-N-dimethyl-4-N-(thieno[2,3-b]pyridin-4-yl)cyclohexane-1,4-diamine formate [ No CAS ]
YieldReaction ConditionsOperation in experiment
14% Example 129. l-N,l-N-dimethyl-4-N-[thieno[2,3-b]pyridin-4-yl]cyclohexane-l,4-diamine.Into a 100-mL round-bottom flask purged and maintained with an inert atmosphere of nitrogen, was placed a solution of <strong>[62226-17-9]4-chlorothieno[2,3-b]pyridine</strong> (commercially available, 100 mg, 0.59 mmol, 1.00 equiv) in toluene ( 15 mL), l -N, l-N-dimethylcyclohexane-l ,4-diamine (126 mg, 0.89 mmol, 1.50 equiv), Pd2(dba)3 chloroform (30 mg, 0.03 mmol, 0.05 equiv), XantPhos (34 mg, 0.06 mmol, 0.10 equiv), t-BuONa(l 13mg, 1.18 mmol, 2.00 equiv). The resulting solution was stirred overnight at 100C in an oil bath. The resulting mixture was concentrated under vacuum. The residue was applied onto a silica gel column with dichloromethane/methanol (6: 1). The crude product (50 mg) was purified by Prep-HPLC with the following conditions: Column, SunFire Prep C18, 19* 150mm 5um; mobile phase, CH3CN and water with 0.05%HCOOH (10.0% water with 0.05%HCOOH up to 50.0% in 10 min, up to 100.0% in 2 min down to 10.0% in 2 min); Detector, uv 254/220nm.This resulted in 23.4 mg (14%) of l -N, l-N-dimethyl-4-N- [thieno[2,3-b]pyridin-4-yl]cyclohexane- l ,4-diamine as yellow semi-solid. MS: (ES, m/z): 276.10 [M- 1.56HCOOH+H]+ .'H NMR- (300 MHz, CDC13, ppm): 51.20- 1.47 (m, 2H), 1.60- 1.72 (m, 2H), 2.21 -2.38 (m, 4H), 2.69(s, 6H), 3.00-3.13 (m, 1 H)3.71 (s, 1 H),4.72 (m, 1 H), 6.38(d, J= 5.7 Hz, 1H), 7.19 (d, J=6.0 Hz, 1 H), 7.30 (d, J = 6.0 Hz, 1 H), 8.25 (d, J = 5.4 Etazeta, Iota Eta), 8.48 (s, 1.56H,), 9.01 -9.15(br, 1 H).
 

Historical Records

Technical Information

Categories