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Chemical Structure| 16807-48-0 Chemical Structure| 16807-48-0

Structure of 16807-48-0

Chemical Structure| 16807-48-0

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Product Details of [ 16807-48-0 ]

CAS No. :16807-48-0
Formula : C8H8O4
M.W : 168.15
SMILES Code : CC(C1=C(OC(C)=CC1=O)O)=O

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Application In Synthesis of [ 16807-48-0 ]

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  • Downstream synthetic route of [ 16807-48-0 ]

[ 16807-48-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 16807-48-0 ]
  • [ 36997-31-6 ]
  • C33H30N6O12 [ No CAS ]
YieldReaction ConditionsOperation in experiment
79% In methanol; for 24.0h;Reflux; These ligands were synthesized by a general procedure. Synthesis of H6L1 (I) is presented here. A methanolic (20 mL) suspension of the <strong>[36997-31-6]benzene-1,3,5-tricarbohydrazide</strong> (H3bthz) (0.252 g, 1 mmol) was added to 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one (2.12 g, 3 mmol) dissolved in MeOH (70 mL) and the reaction mixture was heated at reflux inan oil bath along with slow magnetic stirring. The trihydrazide slowly went into solution in ca. 3 h. After ca. 24 h of reflux, a clear solution was cooled to room temperature where a pale yellow solid slowly precipitated. The solid was filtered, washed with methanol and dried under vacuum over silica gel. Data for H6L1 (I). Yield 1.68 g (79%). C33H30N6O12 (702.6): calcd C, 56.41; H, 4.30; N, 11.96. Found C, 56.0; H, 4.5; N 11.59%. HR-MS: 703.204. IR (cm-1): 3343 (O-H), 3200 (N-H), 1647 (C- -O), 1508(C- -N) cm 1. 1H NMR (400 MHz, DMSO-d6): δ = 16.18 (s, 3H N-H)), 8.67 (br, 3H, O-H), 6.30 (s, 3H, aryl), 5.91 (s, 3H, aryl), 2.29 (s, 9H, CH3 on aryl), 2.13 (s, 9H, CH3).
 

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