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[ CAS No. 168169-11-7 ]

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2D
Chemical Structure| 168169-11-7
Chemical Structure| 168169-11-7
Structure of 168169-11-7 *Storage: {[proInfo.prStorage]}

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Product Details of [ 168169-11-7 ]

CAS No. :168169-11-7MDL No. :MFCD08704822
Formula : C15H16BrNO2 Boiling Point : 375.867°C at 760 mmHg
Linear Structure Formula :-InChI Key :-
M.W :322.20Pubchem ID :-
Synonyms :

Computed Properties of [ 168169-11-7 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 168169-11-7 ]

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Application In Synthesis of [ 168169-11-7 ]

  • Downstream synthetic route of [ 168169-11-7 ]

[ 168169-11-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 24424-99-5 ]
  • [ 2298-07-9 ]
  • [ 168169-11-7 ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide; In tetrahydrofuran; water; at 20℃; for 96h; 4-Bromo-l-naphthylamine (5.0g, 22.5 mmol) and ditertbutyldicarbonate (7.4 g, 33.9 mmol) in tetrahydrofuran (75 ml) and 1Msodium hydroxide (75 ml) are stirred at room temperature for 4 days. The mixture is thenpoured into ethyl acetate (250 ml) and washed with water (300 ml). The ethyl acetate layer isdried over anhydrous sodium sulfate and evaporated to dryness. The residue is purified bycolumn chromatography on silica gel eluted with 10% ethyl acetate in hexanes thenrecrystalized from ethyl acetate and hexanes to yield (4-bromo-naphthalen-l-yl)-carbamic acidtert-butyl ester (3.669 g).
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