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[ CAS No. 17075-14-8 ] {[proInfo.proName]}

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Chemical Structure| 17075-14-8
Chemical Structure| 17075-14-8
Structure of 17075-14-8 * Storage: {[proInfo.prStorage]}
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Product Details of [ 17075-14-8 ]

CAS No. :17075-14-8 MDL No. :MFCD11212372
Formula : C6H7NO2S Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 157.19 Pubchem ID :-
Synonyms :

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Application In Synthesis of [ 17075-14-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 17075-14-8 ]
  • Downstream synthetic route of [ 17075-14-8 ]

[ 17075-14-8 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 18438-38-5 ]
  • [ 21948-75-4 ]
  • [ 17075-14-8 ]
YieldReaction ConditionsOperation in experiment
85% With dihydrogen peroxide In water at 50℃; for 3 h; General procedure: A test tube equipped with a magnetic stirring bar was charged with thioanisole (130.3 mg, 1.0 mmol), aqueous 35percent H2O2 (247.7 mg, 2.5 mmol), and Ti-IEZ-MWW (9.9 mg). The mixture was stirred at 50°C for 3 h. The conversion and yield were determined by GC analysis of the toluene solution with biphenyl as an internal standard. The yield of methyl phenyl sulfone was>99percent, conversion of thioanisole was >99percent, and selectivity (yield/conversion) was >99percent.
84% With sodium hypochlorite pentahydrate In water; acetonitrile at 20℃; for 0.383333 h; Green chemistry General procedure: To a solution of thioanisole (1a; 248 mg, 2.0 mmol) in MeCN (10 mL) and H2O (2 mL), NaOCl·5H2O (362 mg, 2.2 mmol) was added and the mixture was stirred at r.t. for 18 min. H2O (20 mL) and CHCl3 (15mL) were added, the organic layer was separated, and the aqueous phase was extracted with CHCl3 (3 × 15 mL). The extracts were dried over anhydrous magnesium sulfate, and evaporated. The residue was purified by silica gel column chromatography (n-hexane–EtOAc, 1:2 v/v) to provide methyl phenyl sulfoxide (2a; 275 mg, 98percent) as colorless crystals. Methyl phenyl sulfone (3a; 6 mg, 2percent) was also obtained as colorless crystals.
Reference: [1] Tetrahedron, 2014, vol. 70, # 41, p. 7584 - 7592
[2] Synlett, 2015, vol. 26, # 18, p. 2547 - 2552
[3] Tetrahedron, 2014, vol. 70, # 41, p. 7584 - 7592
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