Home Cart 0 Sign in  

[ CAS No. 175676-42-3 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 175676-42-3
Chemical Structure| 175676-42-3
Structure of 175676-42-3 * Storage: {[proInfo.prStorage]}

Please Login or Create an Account to: See VIP prices and availability

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

* Shipping: {[proInfo.prShipping]}

Quality Control of [ 175676-42-3 ]

Related Doc. of [ 175676-42-3 ]

Alternatived Products of [ 175676-42-3 ]
Product Citations

Product Details of [ 175676-42-3 ]

CAS No. :175676-42-3 MDL No. :MFCD31695793
Formula : C8H7F3O3S Boiling Point : -
Linear Structure Formula :- InChI Key :NHBKFPDJMAEDOS-UHFFFAOYSA-N
M.W : 240.20 Pubchem ID :13494930
Synonyms :

Safety of [ 175676-42-3 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 175676-42-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 175676-42-3 ]

[ 175676-42-3 ] Synthesis Path-Downstream   1~6

  • 1
  • [ 175676-42-3 ]
  • [ 1454-85-9 ]
  • 1-(trifluoromethoxy)heptadecane [ No CAS ]
  • 2
  • [ 175676-42-3 ]
  • [ 262373-15-9 ]
  • 2-iodo-5-methyl-1-(trifluoromethoxy)benzene [ No CAS ]
  • 2-iodo-4-methyl-1-(trifluoromethoxy)benzene [ No CAS ]
YieldReaction ConditionsOperation in experiment
With potassium fluoride; 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane; cis-dicyclohexano-18-C-6; carbonic acid dimethyl ester; at 60℃; for 12h; General procedure: To a 15 mL of pressure-proof pipe equipped with a stir bar was added 1 (0.50 mmol, 1.00 equiv), cis-DCy-18-C-6 (372.49 mg, 1.00 mmol, 2.0 equiv), C4F9I (1037.79 mg, 3.00 mmol, 6.00 equiv) and DMC (3.0 mL) in the glove box. 2a (240.20 mg, 1.00 mmol, 2.0 equiv) and KF (116.20 mg, 2.00 mmol, 4.00 equiv) were added with stirring at room temperature. The reaction was stirred at 60 C for 12 h and cooled to room temperature. The solvent was evaporated under vacuum and the crude product was purified by flash column chromatography to give products 3. Yields were listed in Table 5. The ratio of regioisomer ab/ba was determined by 19F NMR spectroscopy.
  • 3
  • [ 175676-42-3 ]
  • [ 88284-48-4 ]
  • [ 175278-00-9 ]
YieldReaction ConditionsOperation in experiment
64% With potassium fluoride; 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane; cis-dicyclohexano-18-C-6; carbonic acid dimethyl ester; at 60℃; for 12h; General procedure: To a 15 mL of pressure-proof pipe equipped with a stir bar was added 1 (0.50 mmol, 1.00 equiv), cis-DCy-18-C-6 (372.49 mg, 1.00 mmol, 2.0 equiv), C4F9I (1037.79 mg, 3.00 mmol, 6.00 equiv) and DMC (3.0 mL) in the glove box. 2a (240.20 mg, 1.00 mmol, 2.0 equiv) and KF (116.20 mg, 2.00 mmol, 4.00 equiv) were added with stirring at room temperature. The reaction was stirred at 60 C for 12 h and cooled to room temperature. The solvent was evaporated under vacuum and the crude product was purified by flash column chromatography to give products 3. Yields were listed in Table 5. The ratio of regioisomer ab/ba was determined by 19F NMR spectroscopy.
  • 4
  • [ 175676-42-3 ]
  • [ 88284-48-4 ]
  • [ 456-55-3 ]
  • [ 175278-00-9 ]
  • 5
  • [ 175676-42-3 ]
  • [ 57280-22-5 ]
  • C8H13F3O4 [ No CAS ]
  • 6
  • [ 175676-42-3 ]
  • [ 31865-25-5 ]
  • C13H14F3NO4 [ No CAS ]
Recommend Products
Same Skeleton Products

Technical Information

Historical Records
; ;