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Chemical Structure| 17598-82-2 Chemical Structure| 17598-82-2

Structure of L-Tagatose
CAS No.: 17598-82-2

Chemical Structure| 17598-82-2

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Product Details of [ 17598-82-2 ]

CAS No. :17598-82-2
Formula : C6H12O6
M.W : 180.16
SMILES Code : OCC([C@@H]([C@@H]([C@H](CO)O)O)O)=O
MDL No. :MFCD00083478

Safety of [ 17598-82-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 17598-82-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 17598-82-2 ]

[ 17598-82-2 ] Synthesis Path-Downstream   1~1

  • 1
  • magnesium glycerol phosphate [ No CAS ]
  • [ 497-09-6 ]
  • [ 17598-82-2 ]
  • [ 57-48-7 ]
YieldReaction ConditionsOperation in experiment
With FAD; Thermus thermophilus HB8 L-fuculose-1-phosphate aldolase; Streptococcus pneumonia glycerol phosphate oxidase; In water-d2; at 30℃; for 22h;pH 7;Enzymatic reaction; General procedure: To a solution of DL-glycerol 3-phosphate magnesium salt (548.78 mg, 2.4 mmol) in 6.86 mL ddH2O was added <strong>[497-09-6]D-glyceraldehyde</strong> (or L-glyceraldehyde) (2 mL, 0.5 M, 1.0 mmol) at pH 7.0, glycerol phosphate oxidase saturated with FAD (final concentration 0.2 mg/mL), catalase (1000 U, 1.18 muL) and aldolase (final concentration 0.5 mg/mL). ddH2O was added to bring the total volume to 10 mL if necessary. The reaction mixture was shaken at 30 °C for 22 h and the reaction was monitored by TLC (developed by nBuOH/AcOH/H2O 2/1/1 (v/v/v) and stained with anisaldehyde sugar stain). The pH was then adjusted to pH ~5 with 6 N HCl and 11 muL acid phosphatase (18 U) was added and the mixture was shaken at 37 °C for 24 h. After cooling to rt., the pH was adjusted to 7.0 with 1 N NaOH and the mixture was diluted with methanol. The solution was filtered through Celite and washed with methanol. The filtrate was concentrated under reduced pressure and the residue was purified by silica gel column chromatography (EtOAc/iPrOH/H2O 9/3/1 (v/v/v)) to afford a pale yellow syrup which was further purified by Bio gel P-2 column. The mixture of monosaccharides could be isolated by Ca2+ exchange resin column. The purification process using P-2 column or Ca2+ exchange resin column was performed with the same procedure we previously used.
 

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• Appel Reaction • Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Bucherer-Bergs Reaction • Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions • Chugaev Reaction • Clemmensen Reduction • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Corey-Kim Oxidation • Dess-Martin Oxidation • Fischer Indole Synthesis • Grignard Reaction • Heat of Combustion • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Jones Oxidation • Lawesson's Reagent • Leuckart-Wallach Reaction • Martin's Sulfurane Dehydrating Reagent • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Mitsunobu Reaction • Moffatt Oxidation • Oxidation of Alcohols by DMSO • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Alcohols • Preparation of Aldehydes and Ketones • Preparation of Amines • Prins Reaction • Reactions of Alcohols • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions with Organometallic Reagents • Reformatsky Reaction • Ritter Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Sharpless Olefin Synthesis • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Swern Oxidation • Tebbe Olefination • Ugi Reaction • Wittig Reaction • Wolff-Kishner Reduction

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