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Chemical Structure| 179031-23-3 Chemical Structure| 179031-23-3

Structure of 179031-23-3

Chemical Structure| 179031-23-3

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Product Details of [ 179031-23-3 ]

CAS No. :179031-23-3
Formula : C55H102O5
M.W : 843.40
SMILES Code : O=C(O)C1=CC(OCCCCCCCCCCCCCCCC)=C(OCCCCCCCCCCCCCCCC)C(OCCCCCCCCCCCCCCCC)=C1
MDL No. :N/A

Safety of [ 179031-23-3 ]

Application In Synthesis of [ 179031-23-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 179031-23-3 ]

[ 179031-23-3 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 81998-05-2 ]
  • [ 179031-23-3 ]
  • [ 1322090-76-5 ]
  • 2
  • [ 134272-64-3 ]
  • [ 179031-23-3 ]
  • C61H108N2O6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20℃; GA16OH was used for the synthesis of GA16-MA to increase the solubility in hydrocarbon. To asolution of GA16OH (0.5g, 0.60mmol) in dichloromethane (10 mL) was added N,Ndiisopropylethylamine(0.85ml, 6mmol). The mixture was treated with N-(3-dimethylaminopropyl)-N?-ethylcarbodiimide hydrochloride (0.19g, 1mmol), 1-hydroxybenzotriazole (0.13g, 1mmol) and N-(2-aminoethyl)maleimide hydrochloride (0.116g,0.66mmol) and stirred at room temperature overnight. The reaction was quenched with droplet ofHCl (1M) solution and washed with water for three times. The organic portion was dried overNa2SO4. The crude material was purified by silica gel column chromatography using hexane andEtOAc (4/1 to 3/1).1H NMR (400MHz, CDCl3): delta 6.96 (s, 2H), 6.73 (s, 2H), 6.58 (t, J=4.6 Hz, 1H), 4.04-3.96 (m,6H), 3.84-3.82 (m, 2H), 3.66-3.62 (m, 2H), 1.83-1.71 (m, 6H), 1.49-1.45 (m, 6H), 1.37-1.26 (m,72H), 0.90-0.86 (m, 9H)HRMS (ESI): Calculated for C61H108N2O6 ([M+H]+): 965.8286 , found 965.8264.
 

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