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Chemical Structure| 18052-27-2 Chemical Structure| 18052-27-2

Structure of 18052-27-2

Chemical Structure| 18052-27-2

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Product Details of [ 18052-27-2 ]

CAS No. :18052-27-2
Formula : C12H20OSi
M.W : 208.37
SMILES Code : C[Si](C)(C(C)(C)C)OC1=CC=CC=C1

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Application In Synthesis of [ 18052-27-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 18052-27-2 ]

[ 18052-27-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 54925-64-3 ]
  • [ 108-95-2 ]
  • [ 18052-27-2 ]
  • 2
  • [ 18052-27-2 ]
  • [ 108-24-7 ]
  • [ 13031-43-1 ]
YieldReaction ConditionsOperation in experiment
82% With perchloric acid immobilized on silica gel; In dichloromethane; General procedure: HClO4-SiO2 (0.5 mmol/g; 50 mg) was added to a stirred solution of substrate (1.0 mmol) and Ac2O (0.45 mL, 5.0 mmol) in CH2Cl2 (5 mL) at rt or heated under reflux. After complete conversion and filtration to remove the catalyst, saturated aqueous solution of NaHCO3 (10 mL) was added and separated. The aqueous solution was extracted with CH2Cl2 (2×10 mL). The organic layer was combined, washed with brine (10 mL), dried (MgSO4), and concentrated under reduced pressure. The residual was isolated through short column chromatography on silica gel, which was eluted with ethyl acetate-petroleum (bp 60-90 C) to give the target products.All new products were characterized by 1H NMR, 13C NMR and HRMS (ESI) spectra and the NMR data for known compounds matched that reported in literature.
 

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