Alternatived Products of [ 18414-58-9 ]
Product Details of [ 18414-58-9 ]
CAS No. : | 18414-58-9 |
MDL No. : | MFCD29127436 |
Formula : |
C14H14O2Si
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
242.35
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 18414-58-9 ]
Signal Word: | |
Class: | N/A |
Precautionary Statements: | |
UN#: | N/A |
Hazard Statements: | |
Packing Group: | N/A |
Application In Synthesis of [ 18414-58-9 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 18414-58-9 ]
- Downstream synthetic route of [ 18414-58-9 ]
- 1
-
[ 51985-46-7 ]
-
[ 18414-58-9 ]
-
[ 59878-57-8 ]
-
[ 1346220-44-7 ]
- 2
-
[ 51934-41-9 ]
-
[ 18414-58-9 ]
-
[ 713-57-5 ]
- 3
-
[ 35371-03-0 ]
-
[ 18414-58-9 ]
-
[ 13205-48-6 ]
- 4
-
[ 18414-58-9 ]
-
[ 159217-89-7 ]
-
[ 66493-39-8 ]
- 5
-
[ 5572-94-1 ]
-
[ 18414-58-9 ]
-
[ 62729-39-9 ]
- 6
-
[ 5460-32-2 ]
-
[ 18414-58-9 ]
-
[ 93-07-2 ]
- 7
-
[ 18414-58-9 ]
-
[ 40757-09-3 ]
-
[ 28045-71-8 ]
Yield | Reaction Conditions | Operation in experiment |
99% |
With potassium trimethylsilonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In toluene at 40℃; for 0.333333h; |
|
- 8
-
[ 13697-89-7 ]
-
[ 18414-58-9 ]
-
[ 385-00-2 ]
- 9
-
[ 17347-32-9 ]
-
[ 18414-58-9 ]
-
[ 6179-26-6 ]
- 10
-
[ 3017-68-3 ]
-
[ 18414-58-9 ]
-
[ 565-63-9 ]
Yield | Reaction Conditions | Operation in experiment |
97% |
With lithium trimethylsilanolate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 80℃; for 16h; Glovebox; |
|
- 11
-
[ 216393-67-8 ]
-
[ 111-26-2 ]
-
[ 18414-58-9 ]
-
2-(2-amino-5-chloro-3-fluorophenyl)-N-hexyl-2-oxoacetamide
[ No CAS ]
- 12
-
[ 111-26-2 ]
-
[ 18414-58-9 ]
-
[ 105752-11-2 ]
-
2-(3-aminopyridin-4-yl)-N-hexyl-2-oxoacetamide
[ No CAS ]
- 13
-
[ 88511-27-7 ]
-
[ 111-26-2 ]
-
[ 18414-58-9 ]
-
2-(4-aminopyridin-3-yl)-N-hexyl-2-oxoacetamide
[ No CAS ]
- 14
-
Phe-Wang resin
[ No CAS ]
-
[ 5460-32-2 ]
-
[ 18414-58-9 ]
-
[ 169887-39-2 ]
- 15
-
Phe-Wang resin
[ No CAS ]
-
[ 591-50-4 ]
-
[ 18414-58-9 ]
-
[ 2566-22-5 ]
- 16
-
Phe-Wang resin
[ No CAS ]
-
[ 29682-41-5 ]
-
[ 18414-58-9 ]
-
(2,5-dichlorobenzoyl)-L-phenylalanine
[ No CAS ]
- 17
-
[ 41731-83-3 ]
-
Phe-Wang resin
[ No CAS ]
-
[ 18414-58-9 ]
-
(5-(ethoxycarbonyl)thiazole-2-carbonyl)-L-phenylalanine
[ No CAS ]
- 18
-
Phe-Wang resin
[ No CAS ]
-
[ 18414-58-9 ]
-
[ 192189-07-4 ]
-
(1H-indole-3-carbonyl)-L-phenylalanine
[ No CAS ]
- 19
-
Phe-Wang resin
[ No CAS ]
-
[ 18414-58-9 ]
-
[ 32111-21-0 ]
-
[ 114457-94-2 ]
- 20
-
[ 610-94-6 ]
-
[ 18414-58-9 ]
-
[ 4376-18-5 ]
Yield | Reaction Conditions | Operation in experiment |
57% |
With lithium trimethylsilanolate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 110℃; |
|
- 21
-
[ 3435-51-6 ]
-
[ 18414-58-9 ]
-
4-(2-(methyldiphenylsilyl)ethyl)benzonitrile
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
45% |
With dipotassium peroxodisulfate; silver nitrate In acetonitrile at 80℃; for 24h; |
3 4-(2-(methyldiphenylsilyl)ethyl)benzonitrile:
Accurately weigh silicic acid (24.2mg, 0.1mmol), silver nitrate (1.69mg, 0.01mmol), potassium persulfate (32.5mg, 0.12mmol), transfer to the reaction vessel, add p-cyanostyrene (18μL, 0.15mmol), finally add 2ml acetonitrile, screw the stopper tightly, react at 80°C for 24h, after the reaction, cool the reaction solution to room temperature, filter with short silica gel to remove insoluble impurities, extract 3 times with ethyl acetate and water, and extract with brine Once the solvent was removed from the organic phase to obtain a crude product, the crude product was separated by column chromatography (eluent: ethyl acetate/petroleum ether = 1:100) to obtain a pure and dry product with a yield of 45%. |
- 22
-
[ 698-70-4 ]
-
[ 18414-58-9 ]
-
[ 530-44-9 ]
Yield | Reaction Conditions | Operation in experiment |
72% |
With 1,10-Phenanthroline; copper(I) thiophene-2-carboxylate; cesium fluoride; palladium(II) iodide In 1-methyl-pyrrolidin-2-one at 110℃; for 1h; Glovebox; Inert atmosphere; |
|
Reference:
[1]Li, Xiong; Xu, Jie; Li, Yue; Kramer, Søren; Skrydstrup, Troels; Lian, Zhong
[Advanced Synthesis and Catalysis, 2020, vol. 362, # 19, p. 4078 - 4083]
- 23
-
[ 18414-58-9 ]
-
[ 288608-09-3 ]
-
(4-(2,5-dimethyl-1H-pyrrol-1-yl)phenyl)(phenyl)methanone
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
70% |
With 1,10-Phenanthroline; copper(I) thiophene-2-carboxylate; cesium fluoride; palladium(II) iodide In 1-methyl-pyrrolidin-2-one at 110℃; for 1h; Glovebox; Inert atmosphere; |
|
Reference:
[1]Li, Xiong; Xu, Jie; Li, Yue; Kramer, Søren; Skrydstrup, Troels; Lian, Zhong
[Advanced Synthesis and Catalysis, 2020, vol. 362, # 19, p. 4078 - 4083]
- 24
-
[ 18414-58-9 ]
-
[ 124-41-4 ]
-
[ 160030-70-6 ]
-
[ 112-63-0 ]
Yield | Reaction Conditions | Operation in experiment |
78% |
With potassium fluoride; propyl cyanide; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; (2-morpholino-N-(quinolin-8-yl)acetamido)nickel(II) chloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 20h; Inert atmosphere; Sealed tube; Irradiation; |
|
- 25
-
[ 4119-41-9 ]
-
[ 18414-58-9 ]
-
[ 124-41-4 ]
-
[ 2046-17-5 ]
Yield | Reaction Conditions | Operation in experiment |
65% |
With potassium fluoride; propyl cyanide; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; (2-morpholino-N-(quinolin-8-yl)acetamido)nickel(II) chloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 20h; Inert atmosphere; Sealed tube; Irradiation; |
|