Home Cart Sign in  
Chemical Structure| 18446-90-7 Chemical Structure| 18446-90-7

Structure of 18446-90-7

Chemical Structure| 18446-90-7

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 18446-90-7 ]

CAS No. :18446-90-7
Formula : C9H16O
M.W : 140.22
SMILES Code : CC([C@H]1CC[C@H](C)CC1)=O
MDL No. :MFCD24690321

Safety of [ 18446-90-7 ]

Application In Synthesis of [ 18446-90-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 18446-90-7 ]

[ 18446-90-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 6972-82-3 ]
  • [ 18446-90-7 ]
  • [ 1621225-75-9 ]
YieldReaction ConditionsOperation in experiment
With sodium cyanoborohydride; acetic acid; In methanol; at 50℃; To a mixture of l-((?ras)-4-methylcyclohexyl)ethanone (Preparative Example 3.13; 1.20 g, 7.69 mmol) and 5,6-diamino-l-methylpyrimidine-2,4(lH,3H)-dione (1.18 g, 8.46 mmol) in MeOH (30 mL) was added acetic acid (73 mu, 1.28 mmol), followed by NaCNBH3 (1.35 g, 21.5 mmol). The reaction was heated at 50 °C overnight. The reaction was then concentrated in vacuo and water was added. The crude solid was collected by filtration, washed with saturated aqueous aHC03 solution and water, and dried in vacuo to afford crude 6-amino-l-methyl-5- ((l-((?ras)-4-methylcyclohexyl)ethyl)amino)pyrimidine-2,4(lH,3H)-dione, which was used in next step without purification. MS (APCI) = 281 (M+l)+
 

Historical Records