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[ CAS No. 188774-55-2 ]

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Chemical Structure| 188774-55-2
Chemical Structure| 188774-55-2
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Product Details of [ 188774-55-2 ]

CAS No. :188774-55-2 MDL No. :MFCD00482914
Formula : C7H5BrClNO Boiling Point : 283.4°C at 760 mmHg
Linear Structure Formula :- InChI Key :-
M.W :234.48 g/mol Pubchem ID :-
Synonyms :

Safety of [ 188774-55-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 188774-55-2 ]

  • Upstream synthesis route of [ 188774-55-2 ]
  • Downstream synthetic route of [ 188774-55-2 ]

[ 188774-55-2 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 188774-55-2 ]
  • [ 1096296-85-3 ]
YieldReaction ConditionsOperation in experiment
76% With borane In tetrahydrofuran at 0 - 85℃; for 10 h; To a solution of 5-bromo-2-chloro-benzamide (7.5 g, 32 mmol) in 200 mL of THF was added BH3 (10M, 16 mL) dropwise at 0 °C and the reaction mixture was stirred at 85 °C for 10 hours. Then the reaction was quenched with 2N HCI (30 mL) and heated to reflux for 1 hour. After adjusting to pH = 8 with NaHC03 aq., extraction with EtOAc (200 mL), drying over Na2S04 , the mixture was concentrated to give (5-bromo-2-chloro-phenyl)methanamine (6.5 g, 76percent).
Reference: [1] Patent: WO2014/202703, 2014, A1, . Location in patent: Page/Page column 101; 102
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