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Chemical Structure| 19013-30-0
Chemical Structure| 19013-30-0
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Product Details of [ 19013-30-0 ]

CAS No. :19013-30-0 MDL No. :MFCD01231360
Formula : C8H10O4S Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 202.23 Pubchem ID :-
Synonyms :

Safety of [ 19013-30-0 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 19013-30-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 19013-30-0 ]

[ 19013-30-0 ] Synthesis Path-Downstream   1~35

  • 1
  • [ 124-63-0 ]
  • [ 150-76-5 ]
  • [ 19013-30-0 ]
YieldReaction ConditionsOperation in experiment
99% With triethylamine In ethyl acetate at 0 - 20℃; for 0.166667h; Green chemistry; 3. General Procedure for the Synthesis of Aryl Mesylates (Table 4) General procedure: To a solution of hydroxyarene (25.0 mmol) in ethyl acetate (75 mL) at 0 °C was added triethylamine (5.06 g, 50.0 mmol) followed by MsCl (3.72 g, 32.5 mmol). After addition of MsCl, the ice-water bath was removed and the resulting thick slurry was vigorously stirred for 10 min. To the slurry was then added water (50 mL). The two-phase mixture was separated. The organic layer was washed with water (25 mL) and dried over anhydrous MgSO4. Removal of solvent under reduced pressure gave the corresponding pure aryl mesylate.
95% With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;
90% With triethylamine In dichloromethane at 0 - 20℃; General procedure for synthesis of aryl mesylates General procedure: To a solution of phenol substrate (1.0 eq, 10.0 mmol) and Et3N (1.5 eq, 15.0 mmol) in CH2Cl2 (0.5 g/mL) was added dropwise the solution of MsCl (1.2 eq, 12.0 mmol) in CH2Cl2 at 0 oC. The mixture was allowed to warm to RT and stirred for 4 h-12 h to detect for the reaction completion. The reaction solution was added to H2O (20 ml). The layers were separated and the aqueous layer was extracted with CH2Cl2 (10 mL× 2). The combined organic layers were washed with brine (20 mL), and dried over Na2SO4. After the solvent was evaporated, the product was purified by column chromatography over silica gel.
87.8% With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;
77% With pyridine
With triethylamine In benzene at 10℃; various concentrations;
With pyridine In benzene at 50℃;
With triethylamine further amines, effect of solvents; activation energy, preexponential terms; activation entropy;
With sodium hydroxide
With pyridine
With pyridine
With triethylamine In dichloromethane at 0℃; for 0.75h;
With sodium hydride In tetrahydrofuran at 20℃;
With pyridine In dichloromethane cooling;
With triethylamine In dichloromethane
With triethylamine In dichloromethane
With triethylamine In dichloromethane
With pyridine In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;
With pyridine In dichloromethane Inert atmosphere;
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;

Reference: [1]Lei, Xiangyang; Jalla, Anusha; Abou Shama, Mhd A.; Stafford, Jamie M.; Cao, Billy [Synthesis, 2015, vol. 47, # 17, p. 2578 - 2585]
[2]Chang, Joyce Wei Wei; Chia, Eugene Yurong; Chai, Christina Li Lin; Seayad, Jayasree [Organic and Biomolecular Chemistry, 2012, vol. 10, # 11, p. 2289 - 2299]
[3]Tu, Yahui; Zhang, Yi; Xu, Sheng; Zhang, Zhaoguo; Xie, Xiaomin [Synlett, 2014, vol. 25, # 20, p. 2938 - 2942]
[4]Wilson, Daniela A.; Wilson, Christopher J.; Moldoveanu, Costel; Resmerita, Ana-Maria; Corcoran, Patrick; Hoang, Lisa M.; Rosen, Brad M.; Percec, Virgil [Journal of the American Chemical Society, 2010, vol. 132, # 6, p. 1800 - 1801]
[5]Percec, Virgil; Bae, Jin-Young; Zhao, Mingyang; Hill, Dale H. [Journal of Organic Chemistry, 1995, vol. 60, # 1, p. 176 - 185]
[6]Bezrodnyi, V. P.; Skrypnik, Yu. G.; Baranov, S. N. [Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, p. 1581 - 1586][Zhurnal Organicheskoi Khimii, 1980, vol. 16, # 9, p. 1863 - 1868]
[7]Skrypnik, Yu. G.; Bezrodnyi, V. P. [Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, p. 2056 - 2063][Zhurnal Organicheskoi Khimii, 1982, vol. 18, # 11, p. 2327 - 2334]
[8]Skrypnik, Yu. G.; Bezrodnyi, V. P. [Doklady Chemistry, 1982, vol. 266, p. 341 - 344][Dokl. Akad. Nauk SSSR Ser. Khim., 1982, vol. 266, # 3, p. 642 - 645]
[9]Kenner; Williams [Journal of the Chemical Society, 1955, p. 522,524]
[10]Burton; Hoggarth [Journal of the Chemical Society, 1945, p. 14,16]
[11]Carnahan,J.C. et al. [Journal of the American Chemical Society, 1976, vol. 98, p. 2526 - 2531]
[12]Culshaw, Peter N.; Walton, John C. [Journal of the Chemical Society. Perkin transactions II, 1991, # 8, p. 1201 - 1208]
[13]Kobayashi, Yuichi; William, Anthony D.; Mizojiri, Ryo [Journal of Organometallic Chemistry, 2002, vol. 653, # 1-2, p. 91 - 97]
[14]Percec, Virgil; Golding, Geoffrey M.; Smidrkal, Jan; Weichold, Oliver [Journal of Organic Chemistry, 2004, vol. 69, # 10, p. 3447 - 3452]
[15]So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee [Angewandte Chemie - International Edition, 2008, vol. 47, # 42, p. 8059 - 8063] So, Chau Ming; Lee, Hang Wai; Lau, Chak Po; Kwong, Fuk Yee [Organic Letters, 2009, vol. 11, # 2, p. 317 - 320] Chow, Wing Kin; So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee [Journal of Organic Chemistry, 2010, vol. 75, # 15, p. 5109 - 5112]
[16]Yeung, Pui Yee; So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee [Angewandte Chemie - International Edition, 2010, vol. 49, # 47, p. 8918 - 8922]
[17]Chow, Wing Kin; So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee [Chemistry - A European Journal, 2011, vol. 17, # 25, p. 6913 - 6917]
[18]Location in patent: experimental part Leowanawat, Pawaret; Zhang, Na; Percec, Virgil [Journal of Organic Chemistry, 2012, vol. 77, # 2, p. 1018 - 1025]
[19]Shen, Chaoren; Yang, Guoqiang; Zhang, Wanbin [Organic and Biomolecular Chemistry, 2012, vol. 10, # 17, p. 3500 - 3505]
[20]Zhang, Liangwei; Liu, Long; Huang, Tianzeng; Dong, Qizhi; Chen, Tieqiao; Chen, Tieqiao [Organometallics, 2020, vol. 39, # 11, p. 2189 - 2196]
  • 2
  • [ 25236-64-0 ]
  • [ 150-76-5 ]
  • [ 62158-88-7 ]
  • [ 19013-30-0 ]
YieldReaction ConditionsOperation in experiment
1: 20% 2: 12% With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 140℃; for 20h; Title compound not separated from byproducts;
1: 12% 2: 20% With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 140℃; for 20h;
  • 3
  • [ 19013-30-0 ]
  • [ 98-80-6 ]
  • [ 613-37-6 ]
YieldReaction ConditionsOperation in experiment
93% With trans-chloro(1-naphthyl)bis-(triphenylphosphine)nickel(II); tricyclohexylphosphine tetrafluoroborate; potassium carbonate In water; toluene at 20℃; for 24h; Inert atmosphere;
89% With potassium phosphate; bis(tricyclohexylphosphine)nickel(II) dichloride; tricyclohexylphosphine In 1,4-dioxane at 80℃; for 14h;
89% With potassium phosphate; C58H72N2O4P2Pd2 In <i>tert</i>-butyl alcohol at 110℃; for 8h; Inert atmosphere;
89% With potassium phosphate; 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate In <i>tert</i>-butyl alcohol at 110℃; for 8h; Inert atmosphere;
80% With potassium phosphate; 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate In <i>tert</i>-butyl alcohol at 20 - 120℃; for 24h;
75% With potassium phosphate; C17H36ClN6NiP2(1+)*Cl(1-) In toluene at 135℃; for 16h; Inert atmosphere;
54% With potassium phosphate; ferrocenylmethylphosphine In tetrahydrofuran at 20℃; for 48h;
21% With potassium phosphate; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride In toluene at 110℃; for 24h;
39 % Chromat. With potassium phosphate; zinc In tetrahydrofuran at 67℃; for 24h;

  • 4
  • [ 917-64-6 ]
  • [ 19013-30-0 ]
  • [ 104-93-8 ]
YieldReaction ConditionsOperation in experiment
54 % Chromat. With zinc In tetrahydrofuran for 10h; Ambient temperature;
  • 5
  • [ 19013-30-0 ]
  • [ 151-50-8 ]
  • [ CAS Unavailable ]
  • [ 874-90-8 ]
YieldReaction ConditionsOperation in experiment
1: 18 % Chromat. 2: 82 % Chromat. With triphenylphosphine; zinc In N,N-dimethyl-formamide at 80℃; for 12h;
  • 6
  • [ 19013-30-0 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
65% With methanol; potassium iodide; zinc In N,N-dimethyl-formamide at 50℃; for 16h;
  • 7
  • [ 19013-30-0 ]
  • [ 1493-27-2 ]
  • [ 58656-16-9 ]
YieldReaction ConditionsOperation in experiment
91% With CsCO3 In dimethyl sulfoxide at 80℃; for 30h;
  • 8
  • [ 109-72-8 ]
  • [ 19013-30-0 ]
  • [ 215877-30-8 ]
  • [ 18272-84-9 ]
  • [ 2132-80-1 ]
YieldReaction ConditionsOperation in experiment
58% Stage #1: n-butyllithium; 4,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborolane With bis(triphenylphosphine)nickel(II) chloride In tetrahydrofuran at 20℃; for 0.25h; Stage #2: p-methoxyphenyl mesylate In tetrahydrofuran at 60℃; for 41h;
  • 9
  • [ 87842-32-8 ]
  • [ 19013-30-0 ]
  • [ 2749-94-2 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
1: 75% 2: 14% With triethylamine; acetone In 2,2,2-trifluoroethanol for 60h; Irradiation;
  • 10
  • [ 19013-30-0 ]
  • [ 693-02-7 ]
  • [ 131558-77-5 ]
YieldReaction ConditionsOperation in experiment
73% With triethylamine; acetone In 2,2,2-trifluoroethanol for 60h; Irradiation;
68% With potassium phosphate; 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate In <i>tert</i>-butyl alcohol at 20 - 110℃; for 18h; Inert atmosphere;
  • 11
  • [ 19013-30-0 ]
  • [ 1066-54-2 ]
  • [ 3989-14-8 ]
YieldReaction ConditionsOperation in experiment
54% With triethylamine; acetone In 2,2,2-trifluoroethanol for 60h; Irradiation;
  • 12
  • [ 110-89-4 ]
  • [ 19013-30-0 ]
  • [ 13939-06-5 ]
  • [ 57700-94-4 ]
YieldReaction ConditionsOperation in experiment
78% With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); caesium carbonate; XPhos In 1,4-dioxane at 160℃; for 0.333333h; Microwave irradiation;
  • 13
  • [ 19013-30-0 ]
  • [ 62-53-3 ]
  • [ 1208-86-2 ]
YieldReaction ConditionsOperation in experiment
78% With 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate; potassium carbonate; phenylboronic acid In <i>tert</i>-butyl alcohol at 110℃; for 24h; Inert atmosphere;
  • 14
  • [ 905966-40-7 ]
  • [ 19013-30-0 ]
  • [ 729-17-9 ]
YieldReaction ConditionsOperation in experiment
98% With potassium phosphate;bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine; In tetrahydrofuran; at 20 - 25℃; for 8 - 12h;Product distribution / selectivity; In a glove box with N2 atmosphere, a Schlenk tube was charged with aryl halide, tosylate or mesylate (1.0 equiv), aryl neopentylglycolboronate (1.5 equiv), potassium phosphate (0.9 mmol, 3.0 equiv), Ni(COD)2 (0.018 mmol, 0.06 equiv), tricyclohexylphosphine (0.11 mmol, 0.18 equiv), and a Teflon coated stirbar. Dry THF (2 ml) was added and reaction was left stirring for 8 h at rt. The reaction mixture was diluted with DCM (10 mL) and filtered. The filtrated solid was washed with DCM (100 mL) and the organic solvent concentrated. The coupling products were precipitated in MeOH and the white crystals were filtrated and washed with cold MeOH.
97% With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine; In tetrahydrofuran; at 23℃; for 1h;Inert atmosphere; Glovebox; Sealed tube;Catalytic behavior; General procedure: 3.1 General Procedure 1 for the Cross-Coupling of 4-Methoxyphenyl Halides and Mesylates with Aryl Neopentylglycolboronates Catalyzed by Ni-Precatalysts and Mixed-Ligand Systems in Dry THF at 23 C In an oven dried test tube charged with a Teflon coated stirring bar, aryl halide or aryl mesylate (0.3 mmol), <strong>[905966-40-7]methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate</strong> (78.13 mg, 0.315 mmol), K3PO4(H2O)3.2 ((191.00 ± 1.00 mg, 0.9 mmol) and Ni-catalyst were added (in the case of NiIICl(1-naphthyl)(PCy3)2 (11.18 ± 0.0510 mg, 0.015 mmol, 5% catalyst loading) and NiIICl(1-naphthyl)(PPh3)2) (11.73 ± 0.0510 mg, 0.015 mmol, 5% catalyst loading). The test tube was brought into a nitrogen filled glove box (moisture level < 2 ppm) through three degassing cycles and PCy3 (8.4 mg, 0.03mmol, 10% loading) ligand was added. In the case of Ni(COD)2 (4.12 ± 0.0510 mg, 0.015 mmol, 5% catalyst loading), it was also added inside the glove box. Dry THF (1 mL) was added inside the glove box and the test tube was sealed by a rubber septum and left stirring at 23C.. A sample was taken by syringe and transferred outside the glove box. The sample was diluted by distilled THF (0.2 mL) and filtered through a short column of aluminum oxide. The filtrate was concentrated and the GC analysis was carried out. The reaction mixture was diluted with dichloromethane (2 mL), filtered through a layer of aluminum oxide and washed with dichloromethane (1 mL) three times. The filtrate was collected and concentrated under vacuum. The crude product was purified by column chromatography on silica gel with EtOAc/hexane mixture as eluent. The reductive elimination side-product was also isolated and characterized.
  • 15
  • [ 19013-30-0 ]
  • [ 668987-38-0 ]
  • [ 213596-33-9 ]
YieldReaction ConditionsOperation in experiment
8% With triethylamine;bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine; In toluene; at 100℃; for 18h;Inert atmosphere;Product distribution / selectivity; A round-bottom flask charged with the aryl halide (5.0 mmol, 1.0 equiv), Ni (For exact amount of catalyst and co-ligand see Table 8; 10% loading was used for Ni catalysts not specified in Table 8). (NiCl2(L)x , Ni(COD)2) or Pd (No co-ligand was used for Pd catalyst) catalysts (PdCl2(dppf)) (0.5 mmol, 0.1 to 0.02 equiv), ligand (L: dppp, dppe, dppf, PPh3, Et3N, bpy, PCy3) (0.5 mmol, 0.1 equiv), and a Teflon coated stir bar was evacuated three times for 10 min under high vacuum and backfilled with N2. Toluene (5 mL) and base (Et3N or (i-Pr)2EtN (15.0 mmol, 3.0 equiv) were added to the reaction mixture at rt. Freshly prepared neopentylglycolborane (10.0 mmol, 2.0 equiv in 5 ml toluene) was added to the red colored suspension via syringe at 23 0C. The reaction mixture was heated to 100 0C and the conversion was followed by GC. After 2 h-12 h (reaction time depends on the type of the aryl halide; iodo derivatives were found to react faster, in 2-4 h , while bromo derivatives in 8-12h), the reaction mixture was quenched via slow addition of saturated aqueous ammonium chloride (10 mL). The quenched reaction mixture was three times washed with saturated aqueous ammonium chloride and extracted with ethyl acetate (50 mL). The combined organic layers were dried over anhydrous MgSO4, filtered, and concentrated. The crude product was purified by silica gel chromatography or recrystallization.
  • 16
  • [ 19013-30-0 ]
  • [ 213596-33-9 ]
  • [ 2132-80-1 ]
YieldReaction ConditionsOperation in experiment
94% With potassium phosphate;bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine; In tetrahydrofuran; at 20 - 25℃; for 8 - 12h;Product distribution / selectivity; In a glove box with N2 atmosphere, a Schlenk tube was charged with aryl halide, tosylate or mesylate (1.0 equiv), aryl neopentylglycolboronate (1.5 equiv), potassium phosphate (0.9 mmol, 3.0 equiv), Ni(COD)2 (0.018 mmol, 0.06 equiv), tricyclohexylphosphine (0.11 mmol, 0.18 equiv), and a Teflon coated stirbar. Dry THF (2 ml) was added and reaction was left stirring for 8 h at rt. The reaction mixture was diluted with DCM (10 mL) and filtered. The filtrated solid was washed with DCM (100 mL) and the organic solvent concentrated. The coupling products were precipitated in MeOH and the white crystals were filtrated and washed with cold MeOH.
  • 17
  • [ 19013-30-0 ]
  • [ 2996-92-1 ]
  • [ 613-37-6 ]
YieldReaction ConditionsOperation in experiment
79% With 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; tetrabutyl ammonium fluoride; palladium diacetate; acetic acid In <i>tert</i>-butyl alcohol at 90℃; for 16h; Inert atmosphere;
  • 18
  • [ 19013-30-0 ]
  • [ 668984-08-5 ]
  • [ 59115-45-6 ]
YieldReaction ConditionsOperation in experiment
70% With 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; potassium phosphate; palladium diacetate; triethylamine In <i>tert</i>-butyl alcohol at 20 - 110℃; Inert atmosphere;
  • 19
  • [ 929626-27-7 ]
  • [ 19013-30-0 ]
  • [ 19234-04-9 ]
YieldReaction ConditionsOperation in experiment
70% With bis(1,5-cyclooctadiene)nickel(0); potassium phosphate; tricyclohexylphosphine tetrafluoroborate In water; <i>tert</i>-butyl alcohol at 110℃; for 4h; Inert atmosphere;
  • 20
  • potassiumhexacyanoferrate(II) trihydrate [ No CAS ]
  • [ 19013-30-0 ]
  • [ 874-90-8 ]
YieldReaction ConditionsOperation in experiment
91% With 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate; potassium carbonate In water; <i>tert</i>-butyl alcohol at 80℃; for 18h; Inert atmosphere;
85% With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; palladium diacetate; potassium carbonate; phenylboronic acid In water; <i>tert</i>-butyl alcohol at 120℃; for 24h; Inert atmosphere; Schlenk technique; general procedures for the cyanation of aryl chlorides and mesylates General procedure: An oven-dried Schlenk tube was evacuated and backfilled with nitrogen. The Schlenk tube was charged with Pd(OAc)2 (4.5 mg, 0.02 mmol ), L1 (36.5 mg, 0.08 mmol), PhB(OH)2 (6.1 mg, 0.05 mmol), and t-BuOH (2 mL), and the mixture was stirred for half hour at 50 °C. After cooling to r.t., aryl chloride or mesylates (1.00 mmol), K4[Fe(CN)6]·3H2O (211.2 mg, 0.50 mmol), K2CO3 (138.2 mg, 1.00 mmol), and H2O (2 mL) were added. The septum was replaced with an inside reflux condenser, and then the Schlenk tube was placed in an oil bath preheated to 100 °C (120 °C for aryl mesylates) with stirring for 6 h (24 h for aryl mesylates). Then the reaction mixture was allowed to cool to r.t., extracted with CH2Cl2, and concentrated under reduced pressure. The crude material was purified by column chromatography on silica gel.
  • 21
  • [ 695-37-4 ]
  • [ 19013-30-0 ]
  • [ 1174000-49-7 ]
YieldReaction ConditionsOperation in experiment
62% With palladium diacetate; cesium fluoride; XPhos In toluene; <i>tert</i>-butyl alcohol at 110℃; for 20h; Inert atmosphere;
  • 22
  • [ 273-53-0 ]
  • [ 19013-30-0 ]
  • [ 838-34-6 ]
YieldReaction ConditionsOperation in experiment
97% With palladium diacetate; caesium carbonate; cesium pivalate; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 120℃;
46% Stage #1: benz<b>oxazole; p-methoxyphenyl mesylate With 2-[2-(dicyclohexylphosphino)-phenyl]-1-methyl-1H-indole; palladium diacetate; potassium carbonate; triethylamine Inert atmosphere; Stage #2: In N,N-dimethyl-formamide; <i>tert</i>-butyl alcohol at 110℃; for 24h; Inert atmosphere;
  • 23
  • [ 1268340-93-7 ]
  • [ 19013-30-0 ]
  • [ 46441-11-6 ]
YieldReaction ConditionsOperation in experiment
80% With potassium phosphate; palladium diacetate; XPhos In water; <i>tert</i>-butyl alcohol at 110℃; for 18h; Inert atmosphere; Sealed tube;
  • 24
  • [ 19013-30-0 ]
  • [ 73183-34-3 ]
  • [ 171364-79-7 ]
YieldReaction ConditionsOperation in experiment
83% With potassium acetate In <i>tert</i>-butyl alcohol at 90℃; for 24h; Inert atmosphere;
  • 25
  • [ CAS Unavailable ]
  • [ 19013-30-0 ]
  • [ 3613-53-4 ]
YieldReaction ConditionsOperation in experiment
60% With potassium phosphate; 1,1'-bis(diisopropylphosphino)ferrocene; (2'-amino-[1,1'-biphenyl]-2-yl)palladium(II)chloride dimer In water; <i>tert</i>-butyl alcohol at 110℃; for 20h; Inert atmosphere;
  • 26
  • [ 1065010-87-8 ]
  • [ 19013-30-0 ]
  • [ 4030-17-5 ]
YieldReaction ConditionsOperation in experiment
96% With potassium phosphate; palladium diacetate; ruphos In water; <i>tert</i>-butyl alcohol at 110℃; Inert atmosphere;
  • 27
  • [ 19013-30-0 ]
  • [ 5720-07-0 ]
  • [ 213596-33-9 ]
  • [ 2132-80-1 ]
YieldReaction ConditionsOperation in experiment
88% With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tricyclohexylphosphine In tetrahydrofuran at 25℃; for 8h; Inert atmosphere;
  • 28
  • [ 19013-30-0 ]
  • [ 335343-05-0 ]
  • [ 49602-47-3 ]
YieldReaction ConditionsOperation in experiment
93% With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tricyclohexylphosphine In tetrahydrofuran at 25℃; for 12h; Inert atmosphere;
81% With potassium phosphate; trans-chloro(1-naphthyl)bis-(triphenylphosphine)nickel(II); tricyclohexylphosphine In tetrahydrofuran at 25℃; for 13h; Inert atmosphere;
  • 29
  • [ 19013-30-0 ]
  • [ 849412-52-8 ]
  • [ 17103-25-2 ]
YieldReaction ConditionsOperation in experiment
98% With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tricyclohexylphosphine In tetrahydrofuran at 25℃; for 12h; Inert atmosphere;
96% With potassium phosphate; trans-chloro(1-naphthyl)bis-(triphenylphosphine)nickel(II); tricyclohexylphosphine In tetrahydrofuran at 25℃; for 12h; Inert atmosphere;
  • 30
  • [ 363-72-4 ]
  • [ 19013-30-0 ]
  • [ 51207-29-5 ]
YieldReaction ConditionsOperation in experiment
20% With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium carbonate In toluene; <i>tert</i>-butyl alcohol at 120℃; for 17h; Inert atmosphere; Microwave irradiation;
  • 31
  • [ 19013-30-0 ]
  • [ 762-04-9 ]
  • [ 3762-33-2 ]
YieldReaction ConditionsOperation in experiment
36% With 1,1'-bis-(diphenylphosphino)ferrocene; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; N-ethyl-N,N-diisopropylamine; zinc In N,N-dimethyl-formamide at 100℃; for 36h; Inert atmosphere;
  • 32
  • [ 19013-30-0 ]
  • [ 4559-70-0 ]
  • [ 795-44-8 ]
YieldReaction ConditionsOperation in experiment
39% With 1,1'-bis-(diphenylphosphino)ferrocene; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; N-ethyl-N,N-diisopropylamine; zinc In N,N-dimethyl-formamide at 140℃; for 36h; Inert atmosphere;
  • 33
  • [ 1314538-55-0 ]
  • [ 19013-30-0 ]
  • [ 120157-94-0 ]
  • 34
  • [ 2629-72-3 ]
  • [ 19013-30-0 ]
  • [ 1390631-66-9 ]
YieldReaction ConditionsOperation in experiment
77% With sodium t-butanolate In acetonitrile at 80℃; for 16h; Inert atmosphere;
  • 35
  • [ 19013-30-0 ]
  • [ 171364-79-7 ]
  • [ 2132-80-1 ]
YieldReaction ConditionsOperation in experiment
50% With potassium phosphate; chloro(1-naphthyl)bis(triphenylphosphine)nickel(II); tricyclohexylphosphine In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;
Same Skeleton Products
Historical Records