[ CAS No. 19513-05-4 ] {[proInfo.proName]}

Name: 19513-05-4|Manganese(III) acetate dihydrate|98%
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Quality Control of [ 19513-05-4 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 19513-05-4 ]

Product Details of [ 19513-05-4 ]

CAS No. :	19513-05-4	MDL No. :	MFCD00150022
Formula :	C₆H₁₃MnO₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	268.10	Pubchem ID :	-
Synonyms :

Calculated chemistry of [ 19513-05-4 ]

Physicochemical Properties

Num. heavy atoms :	15
Num. arom. heavy atoms :	0
Fraction Csp3 :	0.5
Num. rotatable bonds :	6
Num. H-bond acceptors :	8.0
Num. H-bond donors :	2.0
Molar Refractivity :	41.96
TPSA :	97.36 Å²

Pharmacokinetics

GI absorption :	High
BBB permeant :	No
P-gp substrate :	No
CYP1A2 inhibitor :	No
CYP2C19 inhibitor :	No
CYP2C9 inhibitor :	No
CYP2D6 inhibitor :	No
CYP3A4 inhibitor :	No
Log Kp (skin permeation) :	-8.4 cm/s

Lipophilicity

Log Po/w (iLOGP) :	0.0
Log Po/w (XLOGP3) :	-0.65
Log Po/w (WLOGP) :	-0.09
Log Po/w (MLOGP) :	-2.27
Log Po/w (SILICOS-IT) :	-1.44
Consensus Log Po/w :	-0.89

Druglikeness

Lipinski :	0.0
Ghose :	None
Veber :	0.0
Egan :	0.0
Muegge :	0.0
Bioavailability Score :	0.55

Water Solubility

Log S (ESOL) :	-0.7
Solubility :	53.9 mg/ml ; 0.201 mol/l
Class :	Very soluble
Log S (Ali) :	-0.92
Solubility :	32.1 mg/ml ; 0.12 mol/l
Class :	Very soluble
Log S (SILICOS-IT) :	-0.31
Solubility :	131.0 mg/ml ; 0.49 mol/l
Class :	Soluble

Medicinal Chemistry

PAINS :	0.0 alert
Brenk :	0.0 alert
Leadlikeness :	0.0
Synthetic accessibility :	3.27

Safety of [ 19513-05-4 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 19513-05-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 19513-05-4 ]
Downstream synthetic route of [ 19513-05-4 ]

[ 19513-05-4 ] Synthesis Path-Upstream 1~6

1
[ 6156-78-1 ]
[ 108-24-7 ]
[ 19513-05-4 ]

Yield	Reaction Conditions	Operation in experiment
93%	Stage #1: at 90℃; Stage #2: for 1 h; Reflux	To a 2 L round-bottomed flask, Mn(OAc)2•4H2O (66 g, 0.27 mol) and glacial AcOH (660 mL) were added and the mixture was heated at 90°C to dissolve the components (normally for 10-30 min). The mixture must not be heated under reflux. After cooling, acetic anhydride (96 mL) was added to the mixture with stirring. Three portions of ground potassium permanganate, KMnO4, (11 g, 0.07 mol) were then slowly added with stirring. The mixture was heated under reflux for 1 h (Caution: the added KMnO4 must be dissolved in the reaction mixture. Otherwise the reaction mixture could be bumpy while cooling on the bench Very dangerous). After cooling, water (110 mL) was added and the mixture was kept at room temperature under dark conditions until the dark color of the supernatant solution turned transparent normally within for 2 weeks. The crystalline manganese(III) acetate formed was filtered, washed three times with glacial AcOH, washed twice with dried Et2O, and dried in a desiccator under reduced pressure using KOH as a drying agent, resulting in the bright-brown color of Mn(OAc)3•2H2O (67 g, 93percent yield).

Reference： [1] Heterocycles, 2015, vol. 90, # 1, p. 540 - 562

2
[ 6156-78-1 ]
[ 19513-05-4 ]

Reference： [1] Journal of the Chemical Society - Dalton Transactions, 1998, # 21, p. 3673 - 3677
[2] Journal of Thermal Analysis and Calorimetry, 2012, vol. 107, p. 97 - 104
[3] Russian Journal of General Chemistry, 2011, vol. 81, # 11, p. 2304 - 2309
[4] Tetrahedron, 2017, vol. 73, # 51, p. 7223 - 7232

3
[ 638-38-0 ]
[ 19513-05-4 ]

Reference： [1] Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1993, vol. 23, p. 907 - 920

4
[ 6156-78-1 ]
[ 301-04-2 ]
[ 19513-05-4 ]

Reference： [1] Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1994, vol. 24, p. 519 - 524

5
[ 7722-64-7 ]
[ 6156-78-1 ]
[ 108-24-7 ]
[ 64-19-7 ]
[ 19513-05-4 ]

Reference： [1] Synlett, 2017, vol. 28, # 6, p. 724 - 728

6
[ 6156-78-1 ]
[ 64-19-7 ]
[ 19513-05-4 ]

Reference： [1] Chemical Communications, 2015, vol. 51, # 9, p. 1605 - 1607
[2] Journal of Organic Chemistry, 2015, vol. 80, # 5, p. 2621 - 2626

[ 19513-05-4 ] Synthesis Path-Downstream 1~34

1
[ 1170-02-1 ]
[ 19513-05-4 ]
meso-Na{manganese(EHPG)}*3H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry,1989,vol. 28,p. 3403 - 3410

2
[ 1170-02-1 ]
[ 19513-05-4 ]
manganese(SALEN)(2-(3-oxobutenyl)phenolate) [ No CAS ]

Reference： [1]Inorganic Chemistry,1989,vol. 28,p. 3403 - 3410

3
[ 1170-02-1 ]
[ 19513-05-4 ]
[ 19478-47-8 ]

Reference： [1]Inorganic Chemistry,1989,vol. 28,p. 3403 - 3410

4
[ 19513-05-4 ]
[ 2050-14-8 ]
[ 136276-15-8 ]

Reference： [1]Inorganic Chemistry,1991,vol. 30,p. 4031 - 4037

5
[ 1761-56-4 ]
[ 19513-05-4 ]
[ 81567-19-3 ]

Reference： [1]Inorganic Chemistry,1991,vol. 30,p. 4031 - 4037

6
[ 120-70-7 ]
[ 19513-05-4 ]
{Mn₂(1,3-bis(salicylideneiminato)propane dianion)3} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
95%	With NaOH In methanol soln. of ligand and NaOH in methanol stirred for 1 h at 15°C, addn. of Mn(acetate)3, stirred for 15 min; vac. filtered in air, recrystn. (pyridine); elem. anal.;

Reference： [1]Larson, Erlund J.; Pecoraro, Vincent L. [Journal of the American Chemical Society, 1991, vol. 113, # 10, p. 3810 - 3818]

7
[ 94-91-7 ]
[ 19513-05-4 ]
[ 80778-81-0 ]

Reference： [1]Bulletin of the Chemical Society of Japan,1981,vol. 54,p. 3743 - 3748

8
[ 5962-42-5 ]
[ 19513-05-4 ]
manganese(II) carboxyethylphosphonate monohydrate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
9%	In water High Pressure; a soln. of carboxyethylphosphonic acid added to an aq. suspn. of Mn salt, heated in an autoclave at 150°C for 4 d; filtered off, washed (H2O), dried at 60°C; elem. anal.;

Reference： [1]Gomez-Alcantara, M. Mar; Aranda, Miguel A. G.; Olivera-Pastor, Pascual; Beran, Premysl; Garcia-Munoz, Jose L.; Cabeza, Aurelio [Dalton Transactions, 2006, # 4, p. 577 - 585]

9
[ 1170-02-1 ]
[ 19513-05-4 ]
[ 1310-73-2 ]
[ 442877-71-6 ]

Reference： [1]Inorganica Chimica Acta,2002,vol. 331,p. 310 - 317

10
[ 1170-02-1 ]
[ 19513-05-4 ]
[ 1310-73-2 ]
rac-Na[Mn(OC₆H₄CH(COO)NHCH₂)2]*3H₂O [ No CAS ]

Reference： [1]Inorganica Chimica Acta,2002,vol. 331,p. 310 - 317

11
[ 94-91-7 ]
sodium perchlorate [ No CAS ]
[ 19513-05-4 ]
rac-[Mn(N,N'-(1-methylethylene)bis(salicylideneiminato))(H₂O)2]ClO₄ [ No CAS ]

Reference： [1]Inorganic Chemistry,1998,vol. 37,p. 255 - 263

12
[ 16690-08-7 ]
[ 29841-69-8 ]
[ 19513-05-4 ]
lithium chloride [ No CAS ]
[N,N'-bis(2-acetyl-3-oxobutylidene)-(1S,2S)-1,2-diphenylethylenediaminato]chloromanganese(III) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol; 1,2-dichloro-ethane addn. of the formyldiketone and the diamine in ClCH2CH2Cl to the Mn saltin EtOH/ClCH2CH2Cl, reflux (3 h), addn. of LiCl, reacting 1 h; solvent removal (reduced pressure), extn. (CH2Cl2), drying (Na2SO4), concn. (vac.), chromy. (SiO2; CH2Cl2/acetone), repptn. (Ch2Cl2/Et2O);

Reference： [1]Nagata, Takushi; Imagawa, Kiyomi; Yamada, Tohru; Mukaiyama, Teruaki [Bulletin of the Chemical Society of Japan, 1995, vol. 68, # 5, p. 1455 - 1466]

13
[ 111-51-3 ]
[ 7664-39-3 ]
[ 19513-05-4 ]
(HN(CH₃)2CH₂CH₂)2⁽²⁺⁾*2[MnF₄(H₂O)2]^(1-)=(HN(CH₃)2CH₂CH₂)2[MnF₄(H₂O)2]2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In water heating (1 h); cooling (5°C), diffusion of EtOH;

Reference： [1]Jacobs, Ute; Schroeder, Ludger; Massa, Werner; Elias, Carlos; Fuentes, Jesus; Nunez, Pedro; Bentrup, Ursula [Zeitschrift fur Anorganische und Allgemeine Chemie, 1998, vol. 624, # 9, p. 1471 - 1476]

14
[ 30652-11-0 ]
[ 19513-05-4 ]
Mn(1,2-dimethyl-3-hydroxy-4-pyridinone^(1-))3*2.5H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry,2005,vol. 44,p. 2031 - 2038

15
[ 5962-42-5 ]
[ 19513-05-4 ]
Mn⁽³⁺⁾*OH^(1-)*O₃PC₂H₄CO₂H^(2-)*H₂O=Mn(OH)(O₃PC₂H₄CO₂H)*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
25%	In water refluxed for 5 d; filtered off, washed (H2O), dried at 60°C; elem. anal.;

Reference： [1]Gomez-Alcantara, M. Mar; Aranda, Miguel A. G.; Olivera-Pastor, Pascual; Beran, Premysl; Garcia-Munoz, Jose L.; Cabeza, Aurelio [Dalton Transactions, 2006, # 4, p. 577 - 585]

16
[ 67-56-1 ]
[ 131071-84-6 ]
[ 19513-05-4 ]
[ 3109-63-5 ]
[ 606944-00-7 ]

Reference： [1]Inorganic Chemistry,2008,vol. 47,p. 439 - 447

17
sodium azide [ No CAS ]
[ 19513-05-4 ]
[ 151433-25-9 ]
[((1R,2R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino)] manganese(III) azide monohydrate [ No CAS ]

Reference： [1]Dalton Transactions,2008,p. 5031 - 5036

18
sodium azide [ No CAS ]
[ 94-91-7 ]
[ 19513-05-4 ]
[ 1161745-95-4 ]

Reference： [1]Inorganica Chimica Acta,2009,vol. 362,p. 3563 - 3568

19
[ 94-91-7 ]
sodium perchlorate [ No CAS ]
[ 7732-18-5 ]
[ 19513-05-4 ]
[Mn(N,N'-1,2-propylene)-bis-(salicylideneiminate)(H₂O)]2(ClO₄)2 [ No CAS ]

Reference： [1]Inorganica Chimica Acta,2009,vol. 362,p. 3563 - 3568

20
[ 94-91-7 ]
[ 540-72-7 ]
[ 19513-05-4 ]
[ 1179327-87-7 ]

Reference： [1]Inorganica Chimica Acta,2009,vol. 362,p. 3563 - 3568

21
[ 67-56-1 ]
[ 94-91-7 ]
[ 143-66-8 ]
[ 19513-05-4 ]
[ 1179327-85-5 ]

Reference： [1]Inorganica Chimica Acta,2009,vol. 362,p. 3563 - 3568

22
(Bu₄N)Mn[N(CN)₂]₃ [ No CAS ]
[ 120-70-7 ]
[ 19513-05-4 ]
[ 1442449-67-3 ]

Yield	Reaction Conditions	Operation in experiment
72%	Stage #1: N,N'-propane-1,3-diylbis(salicylideneimine); manganese(III) triacetate dihydrate In methanol at 50℃; Stage #2: (Bu₄N)Mn[N(CN)₂]₃ In methanol at 50℃;

Reference： [1]Kopotkov; Simonov; Sadakov; Yagubskii [Russian Journal of Coordination Chemistry, 2013, vol. 39, # 2, p. 201 - 208][Koord. Khim., 2013, vol. 39, # 2, p. 112 - 119,8]

23
manganese(II) dicyanoamide [ No CAS ]
[ 120-70-7 ]
[ 19513-05-4 ]
[ 1442449-67-3 ]

Yield	Reaction Conditions	Operation in experiment
65%	Stage #1: N,N'-propane-1,3-diylbis(salicylideneimine); manganese(III) triacetate dihydrate In methanol at 50℃; Stage #2: manganese(II) dicyanoamide In methanol at 50℃;

Reference： [1]Kopotkov; Simonov; Sadakov; Yagubskii [Russian Journal of Coordination Chemistry, 2013, vol. 39, # 2, p. 201 - 208][Koord. Khim., 2013, vol. 39, # 2, p. 112 - 119,8]

24
[ 1336-21-6 ]
[ 7631-95-0 ]
rubidium chloride [ No CAS ]
[ 19513-05-4 ]
[ 118072-93-8 ]
Mo<SUB>4</SUB>(zoledronate)<SUB>2</SUB>Mn [ No CAS ]

Reference： [1]Chemistry - A European Journal,2015,vol. 21,p. 10537 - 10547

25
[ 934-60-1 ]
[ 124-38-9 ]
[ 19513-05-4 ]
[ 2751-90-8 ]
[ 75-05-8 ]
[Fe(6-methylpicolinate)₂(μ-OH)₂]·3H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%		An acetonitrile solution (4 mL) of 6-methylpicolinic acid (6Me-picH, 0.274 g, 2.0 mmol) was added to an acetonitrile solution(4 mL) containing Mn(OAc)3·2H2O (0.232 g, 1.0 mmol) to give a brown suspension. To the suspension was added (n-Bu4N)(OAc) (120 mg, 0.40 mmol) in acetonitrile (2 mL) at 60 C to give a clear solution. The resulting solution was cooled to ambient temperature, to which was added NEt3 (28 muL, 0.20 mmol) in acetonitrile (0.4 mL). A stream of CO2 gas was passed over the resulting solution at ambient temperature for 1 minute to afford a yellowish brown solution, to which was added Ph4PBr (251 mg, 0.60 mmol) in acetonitrile (2 mL) and diethyl ether (~12 mL). The resulting solution was allowed to stand for several days at -40 C to afford brown crystals suitable for X-ray crystallography together with brown powder. It was found that this complex gradually decomposed at ambient temperature under air. This complex was stored at -40 C. Yield: 0.509 g (65 %). Anal. Calcd for C40H38.5MnN2.5O9.5P: C,60.65; H, 4.90; N, 4.42 %. Found: C, 60.43; H, 5.19; N, 4.64 %. IR (KBr, cm-1): 1637 (COO),1571 (CO3), 1591 (C=C), 1571 (CO3), 1460 (CO3), 1259 (CO3) 1107 (PPh4). ESI-TOF/MS(acetonitrile): m/z = 387.0 [M]-. UV-vis [lambdamax/nm (epsilon/M-1 cm-1)] in acetonitrile at -40 C: 225nm (epsilon = 10000 M-1 cm-1), 269 nm (epsilon = 3400 M-1 cm-1), and 310 nm (epsilon = 620 M-1 cm-1).

Reference： [1]Chemistry Letters,2015,vol. 44,p. 330 - 332

26
[ 304906-01-2 ]
[ 19513-05-4 ]
Mn⁽³⁺⁾*C₂H₃O₂^(1-)*H₂O*2C₁₃H₁₂N₂O₃S^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium acetate In ethanol for 4h; Reflux;	2.3. Synthesis of Mn(III) based neat complexes General procedure: The procedures for preparation of Mn(III) complexes are 0.02 M vanillin thiophene-2-carboxylic acid hydrazone (VTCH), VFCH, ethylvanillin thiophene-2-carboxylic acid hydrazone (EVTCH), and/or ethylvanillin furoic-2-carboxylic acid hydrazone (EVFCH) ligands were dissolved in 25 mL ethanol and then heated to boiling. This was followed by dropwise addition of a solution of 0.01 M Mn(CH3COO)3·2H2O in 10 mL ethanol. The pH of the resulting solution was adjusted to 5-6 by dropwise addition of CH3COONa solution. The resultant solution was stirred and refluxed for 4 h. After cooling, the solid product was separated by filtration and dried in vacuum.

Reference： [1]Modi, Chetan K.; Trivedi, Parthiv M. [Journal of Coordination Chemistry, 2014, vol. 67, # 22, p. 3678 - 3688]

27
[ 20845-48-1 ]
tetrakis(tetrabutylammonium) octamolybdate [ No CAS ]
[ 19513-05-4 ]
[ 75-05-8 ]
(tetrabutylammonium)₃MnMo₆O₁₈(2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol(-3H))₂*2CH₃CN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	for 6h; Reflux;

Reference： [1]Li, Xin-Xiong; Wang, Yang-Xin; Wang, Rui-Hu; Cui, Cai-Yan; Tian, Chong-Bin; Yang, Guo-Yu [Angewandte Chemie - International Edition, 2016, vol. 55, # 22, p. 6462 - 6466][Angew. Chem., 2016, vol. 128, # 22, p. 6572 - 6576,5]

28
[ 7631-95-0 ]
[ 19513-05-4 ]
[ 118072-93-8 ]
5H₃N*7H⁽¹⁺⁾*2Mo₂O₆*2C₅H₅N₂O₇P₂^(5-)*Mn⁽³⁺⁾*10H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
21%		To a solution of Na2MoO42H2O (0.242 g, 1 mmol) in 10 mL of 1M CH3COONH4/CH3COOH buffer was added Mn(OAc)3.2H20 (0.070 g, 0.26 mmol) and zoledronic acid (0.137 g, 0.5 mmol). The solution was stirred for 5 mm then NH3 (33% in water) was added dropwise to pH = 7.5. The solution was left to evaporate and was filtered after 24 h in order to remove a pink precipitate. EDX measurements and IR spectroscopyindicated that the precipitate was a manganese BP complex that did not contain molybdenum. Greyish crystals of the title compound appeared after three days. Yield: 0.080 g (21% based on Mo). Anal. Calc. (found) for C10H52MnMo4N9O36P4 (M.W. = 1437 g mol-1): C 8.36 (8.88), H 3.65 (3.90), N 8.77 (8.78). IR (FTR): v (cm-i) = i575(m), i546 (w), i42i(s), i288 (w), ii36(s), iii2(sh), 1045(s), 1018(sh), 973(m), 915(s), 888(s), 790(s), 699(m), 656(m), 6i9(w), 560(w),529(m).

Reference： [1]Patent: WO2016/189109,2016,A1 .Location in patent: Page/Page column 18; 19

29
tetrakis(tetrabutylammonium) octamolybdate [ No CAS ]
[ 13880-05-2 ]
[ 19513-05-4 ]
C₁₄H₂₀MnMo₆N₂O₂₆^(3-)*3C₁₆H₃₆N⁽¹⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In acetonitrile; for 16.0h;Reflux;	The 800 mg (0.37 mmol) [n-(C 4 H 9) 4 N] 4 [alpha-Mo 8 O 26], 149 mg (0.56 mmol) Mn (CH 3 COO) 3 · 2H 2 O and 224 mg (1.28 mmol) N-[ 1,3-dihydroxy) - 2 - (hydroxymethyl) - 2-propyl]-acrylamide (ACC-tris) underwaterly to 25 ml in acetonitrile, reflux 16h. Concentrated reaction solution, the diffusion crystallization in ether. 2h to filter the white precipitate, then the ether is in an atmosphere of a few days to obtain the product 752 mg, yield 81%.

Reference： [1]Patent: CN103992357,2016,B .Location in patent: Paragraph 0090-0092

30
[ 7631-95-0 ]
[ 19513-05-4 ]
[ 118072-93-8 ]
2C₅H₅N₂O₇P₂^(5-)*5H₃N*7H⁽¹⁺⁾*10H₂O*Mn(Mo₂O₆)2⁽³⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 7558 - 7565

31
[ 4671-77-6 ]
Na₉[A-α-PW₉O₃₄]*7H₂O [ No CAS ]
[ 506-59-2 ]
[ 19513-05-4 ]
14C₂H₇N*14H⁽¹⁺⁾*8Na⁽¹⁺⁾*26H₂O*((PW₉O₃₄)2(PW₁₀O₃₇)2Mn₁₂O₆(OH)2(O₂CCH₃)2(C₄H₈O₆P₂)2)^(22-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
31%	Stage #1: Na₉[A-α-PW₉O₃₄]*7H₂O; manganese(III) triacetate dihydrate In aq. acetate buffer at 20℃; for 1h; Stage #2: 1,4-butylenediphosphonic acid In aq. acetate buffer for 2h; Stage #3: N,N-dimethylammonium chloride In aq. acetate buffer

Reference： [1]Liu, Zhiwei; Wang, Wei; Tang, Jinkui; Li, Weiqi; Yin, Weiye; Fang, Xikui [Chemical Communications, 2019, vol. 55, # 46, p. 6547 - 6550]

32
[ 3946-91-6 ]
[ 19513-05-4 ]
C₂₂H₁₉MnN₂O₅ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; at 20℃;	General procedure: All complexes were prepared with the previously reported literature method [6,9,11,14]. They were synthesized by stirring the ligands (1x10-3 mol, La or Lb or Lc) and Mn(III)(OAc)32H2O (1x10-3 mol) in MeOH (5 mL) at 20 C (Scheme 1) [6,9,11,14]. Brown powder was formed, filtered and washed with MeOH. For 1a, ESI-MS: m/z calcd for [1a + H+]+: 515.00, found 515.09 (Fig. S4(a)). Elements analysis calcd (%) for C22H19MnN2O5: C, 59.20; H, 4.29; N, 6.28. Found: C, 59.24; H,3.90; N, 6.11. For 1b, ESI-MS: m/z calcd for [1b + H+ + 2MeCN]+: 529.13, found 528.93 (Fig. S4(b)). Elements analysis calcd (%) for C22H19MnN2O5: C, 51.29; H, 3.33; N, 5.44. Found: C, 51.83; H, 2.87; N, 5.46. For 1c, ESI-MS: m/z calcd for [1c + H+]+: 475.11, found 474.98 (Fig. S4(c)). Elements analysis calcd (%) for C22H17Cl2MnN2O5: C,60.76; H, 4.89; N, 5.91. Found: C, 60.74; H, 4.45; N, 5.69.

Reference： [1]Inorganica Chimica Acta,2021,vol. 520

33
[ 10213-10-2 ]
[ 19513-05-4 ]
None [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Stage #1: sodium tungstate (VI) dihydrate; manganese(III) triacetate dihydrate With hydrogenchloride In water for 2h; Stage #2: at 450℃; for 3h;	Preparation of pure and Mn doped WO3 nanoparticles General procedure: The synthesis of WO3 nanoparticles was carried out by hydraulic acid-assisted precipitation method. The required molar concentration of precursor was prepared by dissolving Na2WO4•2H2O in water. The resulting solution is stirred vigorously for half an hour. To the obtained homogeneous solution concentrated HCl was added dropwise till the pH~2. The resulting solution was vigorously stirred for 2 hr. It was kept undisturbed for settlement overnight. The supernatant was discarded, and the remaining precipitate was filtered, washed, and dried for 3 hr at 120 °C. The resulting sample was annealed at 450 °C for 3 hr and crushed using agate mortar and pestle. For the synthesis of the doped samples, the similar procedure was carried out by adding the required molar concentration of manganese acetate solution to perform 1 wt%, and 5 wt% doping into the lattice.

Reference： [1]Avani, A. V.; Joshua, J. Richards; Kathirvel, P.; Marnadu, R.; Mohan, Lakshmi; Nallamuthu, N.; Packiaraj, R.; Saravanakumar, S.; Shkir, Mohd [Journal of Alloys and Compounds, 2021, vol. 882]

34
[ 10213-10-2 ]
[ 19513-05-4 ]
None [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Stage #1: sodium tungstate (VI) dihydrate; manganese(III) triacetate dihydrate With hydrogenchloride In water for 2h; Stage #2: at 450℃; for 3h;	Preparation of pure and Mn doped WO3 nanoparticles General procedure: The synthesis of WO3 nanoparticles was carried out by hydraulic acid-assisted precipitation method. The required molar concentration of precursor was prepared by dissolving Na2WO4•2H2O in water. The resulting solution is stirred vigorously for half an hour. To the obtained homogeneous solution concentrated HCl was added dropwise till the pH~2. The resulting solution was vigorously stirred for 2 hr. It was kept undisturbed for settlement overnight. The supernatant was discarded, and the remaining precipitate was filtered, washed, and dried for 3 hr at 120 °C. The resulting sample was annealed at 450 °C for 3 hr and crushed using agate mortar and pestle. For the synthesis of the doped samples, the similar procedure was carried out by adding the required molar concentration of manganese acetate solution to perform 1 wt%, and 5 wt% doping into the lattice.

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[ CAS No. 19513-05-4 ] {[proInfo.proName]}

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[ 19513-05-4 ] Synthesis Path-Upstream 1~6

[ 19513-05-4 ] Synthesis Path-Downstream 1~34

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