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[ CAS No. 1973-22-4 ]

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2D
Chemical Structure| 1973-22-4
Chemical Structure| 1973-22-4
Structure of 1973-22-4 *Storage: {[proInfo.prStorage]}

Quality Control of [ 1973-22-4 ]

Related Doc. of [ 1973-22-4 ]

SDS
Alternatived Products of [ 1973-22-4 ]
Alternatived Products of [ 1973-22-4 ]

Product Details of [ 1973-22-4 ]

CAS No. :1973-22-4MDL No. :MFCD00000077
Formula : C8H9Br Boiling Point : 199°C at 760 mmHg
Linear Structure Formula :-InChI Key :N/A
M.W :185.06Pubchem ID :16089
Synonyms :

Computed Properties of [ 1973-22-4 ]

TPSA : 0 H-Bond Acceptor Count : 0
XLogP3 : - H-Bond Donor Count : 0
SP3 : 0.25 Rotatable Bond Count : 1

Safety of [ 1973-22-4 ]

Signal Word:WarningClass:N/A
Precautionary Statements:P261-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 1973-22-4 ]

  • Upstream synthesis route of [ 1973-22-4 ]
  • Downstream synthetic route of [ 1973-22-4 ]

[ 1973-22-4 ] Synthesis Path-Upstream   1~25

  • 1
  • [ 201230-82-2 ]
  • [ 2039-88-5 ]
  • [ 1973-22-4 ]
  • [ 107408-16-2 ]
YieldReaction ConditionsOperation in experiment
24 % ee With {(R)-binap}PtCl2; hydrogen; tin(ll) chloride In toluene at 40℃; for 128 h; Autoclave; Schlenk technique General procedure: In a typical experiment, a solution of PtCl2[(R)-BINAP] (4.5 mg;0.005 mmol) and tin(II) chloride (1.9 mg; 0.01 mmol) in toluene(5 mL) containing styrene derivatives (1a-g, 5a-g) (1.0 mmol) wastransferred under argon into a 100 mL stainless steel autoclave. Thereaction vessel was pressurized to 80 bar total pressure (CO/H2 1:1) and placed in an oil bath of constant temperature. Themixture was stirred with a magnetic stirrer for the given reactiontime. The pressure was monitored throughout the reaction. Aftercooling and venting of the autoclave, the pale yellow solution wasremoved and immediately analyzed by GC-MS and chiral GC.
30 % ee With {(R)-binap}PtCl2; hydrogen; tin(ll) chloride In toluene at 100℃; for 24 h; Autoclave; Schlenk technique General procedure: In a typical experiment, a solution of PtCl2[(R)-BINAP] (4.5 mg;0.005 mmol) and tin(II) chloride (1.9 mg; 0.01 mmol) in toluene(5 mL) containing styrene derivatives (1a-g, 5a-g) (1.0 mmol) wastransferred under argon into a 100 mL stainless steel autoclave. Thereaction vessel was pressurized to 80 bar total pressure (CO/H2 1:1) and placed in an oil bath of constant temperature. Themixture was stirred with a magnetic stirrer for the given reactiontime. The pressure was monitored throughout the reaction. Aftercooling and venting of the autoclave, the pale yellow solution wasremoved and immediately analyzed by GC-MS and chiral GC.
Reference: [1] Journal of Organometallic Chemistry, 2016, vol. 824, p. 118 - 123
[2] Journal of Organometallic Chemistry, 2016, vol. 824, p. 118 - 123
  • 2
  • [ 2039-88-5 ]
  • [ 1973-22-4 ]
Reference: [1] Green Chemistry, 2013, vol. 15, # 8, p. 2141 - 2148
[2] Journal of the American Chemical Society, 1941, vol. 63, p. 1892,1894
[3] Journal of the American Chemical Society, 2013, vol. 135, # 22, p. 8157 - 8160
  • 3
  • [ 100-41-4 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
Reference: [1] ChemSusChem, 2013, vol. 6, # 8, p. 1337 - 1340
[2] RSC Advances, 2014, vol. 4, # 92, p. 51016 - 51021
[3] Chemistry Letters, 2003, vol. 32, # 10, p. 932 - 933
[4] Tetrahedron, 1989, vol. 45, # 24, p. 7869 - 7878
[5] Chemische Berichte, 1885, vol. 18, p. 1273
[6] Chemische Berichte, 1885, vol. 18, p. 1273
[7] Zeitschrift fuer Chemie, 1871, p. 131 Anm.
[8] Justus Liebigs Annalen der Chemie, 1867, vol. 144, p. 280
[9] Proc. Royal Soc. London, vol. 18, p. 126[10] Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1869, p. 412
[11] Synthetic Communications, 1992, vol. 22, # 8, p. 1095 - 1099
[12] Chemical Communications, 1997, # 13, p. 1203 - 1204
[13] Chemische Berichte, 1885, vol. 18, p. 1273
[14] Chemische Berichte, 1885, vol. 18, p. 1273
[15] Journal of the Chemical Society, Perkin Transactions 1, 2000, # 16, p. 2745 - 2752
[16] Russian Journal of Applied Chemistry, 2006, vol. 79, # 6, p. 949 - 956
[17] Russian Journal of Applied Chemistry, 2006, vol. 79, # 6, p. 949 - 956
[18] Russian Journal of General Chemistry, 2010, vol. 80, # 2, p. 263 - 267
[19] Green Chemistry, 2012, vol. 14, # 6, p. 1673 - 1679
[20] Organic Letters, 2013, vol. 15, # 9, p. 2108 - 2111
[21] Organic Process Research and Development, 1998, vol. 2, # 4, p. 245 - 249
[22] Organic Process Research and Development, 2000, vol. 4, # 4, p. 270 - 274
  • 4
  • [ 578-54-1 ]
  • [ 1973-22-4 ]
Reference: [1] Journal of Organic Chemistry, 1959, vol. 24, p. 1025
[2] Journal of Organic Chemistry, 1957, vol. 22, p. 390,392, 393
[3] Gazzetta Chimica Italiana, 1957, vol. 87, p. 329,339
[4] Journal of Organic Chemistry, 1959, vol. 24, p. 1025
[5] Journal of Organic Chemistry, 1957, vol. 22, p. 390,392, 393
[6] Gazzetta Chimica Italiana, 1957, vol. 87, p. 329,339
[7] Journal of Organic Chemistry, 1962, vol. 27, p. 921 - 924
[8] Bulletin de la Societe Chimique de France, 1966, p. 1012 - 1020
[9] Recueil des Travaux Chimiques des Pays-Bas, 1960, vol. 79, p. 1211 - 1222
  • 5
  • [ 2039-88-5 ]
  • [ 1333-74-0 ]
  • [ 1973-22-4 ]
Reference: [1] Dalton Transactions, 2013, vol. 42, # 20, p. 7318 - 7329
  • 6
  • [ 128254-32-0 ]
  • [ 1973-22-4 ]
Reference: [1] Tetrahedron Letters, 1990, vol. 31, # 43, p. 6179 - 6182
  • 7
  • [ 113163-19-2 ]
  • [ 1074-15-3 ]
  • [ 100-41-4 ]
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  • [ 103-63-9 ]
Reference: [1] Journal of the American Chemical Society, 1990, vol. 112, # 4, p. 1629 - 1630
  • 8
  • [ 7364-19-4 ]
  • [ 1973-22-4 ]
Reference: [1] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1979, p. 176 - 179
  • 9
  • [ 6630-33-7 ]
  • [ 1973-22-4 ]
Reference: [1] Journal of the American Chemical Society, 2013, vol. 135, # 22, p. 8157 - 8160
  • 10
  • [ 92-52-4 ]
  • [ 57190-08-6 ]
  • [ 1973-22-4 ]
Reference: [1] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1979, p. 176 - 179
  • 11
  • [ 74-96-4 ]
  • [ 108-86-1 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
Reference: [1] Zhurnal Obshchei Khimii, 1959, vol. 29, p. 1072,1075; engl. Ausg. S. 1043, 1044
  • 12
  • [ 100-41-4 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, p. 149 - 154[2] Zhurnal Organicheskoi Khimii, 1988, vol. 24, # 1, p. 168 - 174
  • 13
  • [ 100-41-4 ]
  • [ 108-86-1 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
Reference: [1] J. Appl. Chem. USSR (Engl. Transl.), 1980, vol. 53, # 5, p. 885 - 888[2] Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1980, vol. 53, # 5, p. 1122 - 1126
[3] Russian Journal of Organic Chemistry, 2005, vol. 41, # 11, p. 1631 - 1636
  • 14
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  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985, vol. 39, # 6, p. 437 - 444
  • 15
  • [ 108-86-1 ]
  • [ 74-85-1 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985, vol. 39, # 6, p. 437 - 444
  • 16
  • [ 100-41-4 ]
  • [ 7726-95-6 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
Reference: [1] Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1957, p. 840,841, 846; engl. Ausg. S. 861, 862, 865
  • 17
  • [ 100-41-4 ]
  • [ 7726-95-6 ]
  • [ 7553-56-2 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
Reference: [1] Chemische Berichte, 1885, vol. 18, p. 1273
  • 18
  • [ 100-41-4 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, p. 149 - 154[2] Zhurnal Organicheskoi Khimii, 1988, vol. 24, # 1, p. 168 - 174
  • 19
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985, vol. 39, # 6, p. 437 - 444
  • 20
  • [ 1973-22-4 ]
  • [ 1585-07-5 ]
  • [ 2725-82-8 ]
Reference: [1] Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985, vol. 39, # 6, p. 437 - 444
  • 21
  • [ 108-86-1 ]
  • [ 74-85-1 ]
  • [ 1585-07-5 ]
  • [ 1973-22-4 ]
  • [ 2725-82-8 ]
Reference: [1] Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985, vol. 39, # 6, p. 437 - 444
  • 22
  • [ 1973-22-4 ]
  • [ 4001-73-4 ]
Reference: [1] Organic Letters, 2016, vol. 18, # 4, p. 784 - 787
  • 23
  • [ 1973-22-4 ]
  • [ 767-90-8 ]
Reference: [1] Journal of the American Chemical Society, 1991, vol. 113, # 25, p. 9630 - 9639
  • 24
  • [ 1973-22-4 ]
  • [ 90002-36-1 ]
Reference: [1] Chemistry - A European Journal, 2008, vol. 14, # 36, p. 11429 - 11441
[2] Organic Letters, 2005, vol. 7, # 7, p. 1291 - 1294
  • 25
  • [ 109-72-8 ]
  • [ 150-46-9 ]
  • [ 1973-22-4 ]
  • [ 90002-36-1 ]
Reference: [1] Patent: US2003/195157, 2003, A1,
[2] Patent: US2004/127423, 2004, A1,
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