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Chemical Structure| 204-02-4 Chemical Structure| 204-02-4

Structure of 204-02-4

Chemical Structure| 204-02-4

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Product Details of [ 204-02-4 ]

CAS No. :204-02-4
Formula : C11H8N2
M.W : 168.19
SMILES Code : C12=C3C(NC=N2)=CC=CC3=CC=C1
MDL No. :MFCD00024145

Safety of [ 204-02-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 204-02-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 204-02-4 ]

[ 204-02-4 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 204-02-4 ]
  • [ 532-02-5 ]
  • 9-β-naphthalenesulfonylperimidine [ No CAS ]
  • 6-β-naphthalenesulfonylperimidine [ No CAS ]
  • 2
  • [ 204-02-4 ]
  • [ 4761-00-6 ]
  • [ 1615212-42-4 ]
YieldReaction ConditionsOperation in experiment
67% General procedure: A suspension of NaH (0.86 g; 35.7 mmol) in THF (15 mL) was transferred drop wise into the solution of 1H-perimidine (5.0 g; 29.7 mmol) in 60 mL of THF and the resulting mixture was refluxed for 24 h. Then 2,4,6-trimethylbenzyl bromide or 2,4,6-triisopropylbenzyl bromide (35.7 mmol) was added and the mixture was refluxed for additional 24 h. The solvent was removed under reduced pressure. The oily residue was treated with CH2Cl2 and filtered off, then was purified by column chromatography over silica gel using CH2Cl2/MeOH (98:2) as the eluent to give pure compounds as yellow solid.
 

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