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Chemical Structure| 209901-86-0
Chemical Structure| 209901-86-0
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Product Details of [ 209901-86-0 ]

CAS No. :209901-86-0 MDL No. :MFCD06796986
Formula : C21H14FN3 Boiling Point : -
Linear Structure Formula :- InChI Key :MYQQZCVIAQFISL-UHFFFAOYSA-N
M.W : 327.35 Pubchem ID :57357727
Synonyms :

Safety of [ 209901-86-0 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P302+P352-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 209901-86-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 209901-86-0 ]

[ 209901-86-0 ] Synthesis Path-Downstream   1~20

  • 1
  • [ 1122-62-9 ]
  • [ 459-57-4 ]
  • [ 209901-86-0 ]
YieldReaction ConditionsOperation in experiment
40% With ammonium hydroxide; potassium hydroxide; In ethanol; at 20.0℃;Inert atmosphere; The terpyridyl ligand has been synthesized by following the reported procedure [43]. 4-F-benzaldehyde (0.620 g, 5 mmol) and 2-acetylpyridine (1.21 g, 10 mmol) were dissolved in ethanol. KOH (0.77 g, 10 mmol) was added and the mixture was vigorously stirred. After the potassium hydroxide pellets completely dissolved, ammonia (excess, ca. 20 ml) was added and the mixture was stirred at room temperature for 16 h under a N2 atmosphere. The resulting solution was filtered under vacuum and washed with ethanol to give a very light blue colored fluffy solid, yield 0.656 g (40%). The crude product was recrystallised from methanol. Mass: 328 (M+1). 1H NMR (CDCl3, δ, ppm): 8.61 (2H, d, Ph3,5-H), 8.59 (2H, d, Ph2,6-H), 8.55 (2H, d, 6,6"-H), 7.75 (2H, ddd, 5,5"-H), 7.8 (2H, ddd, 4,4"-H), 7.15 (2H, s, 3',5'H), 7.05-7.1 (2H, m, 3,3"-H). 13C NMR (CDCl3, δ, ppm): 155.76 (CL), 154.80 (CF), 149.34 (CE), 148.19 (CH), 137.47 (CA), 136.29 (CC), 134.35 (CI), 129.36 (CJ), 128.78 (CB), 124.38 (CD), 120.94 (CG), 117.82 (CK).
With ammonia; potassium hydroxide; In ethanol; water; at 20.0℃; for 8h; General procedure: All tridentate ligands were synthesized similarly by following literature procedure [24]. 2-Acetyl pyridine (20.0 mmol) was added to an ethanolic solution of various aldehydes (10.0 mmol in 70 mL EtOH). KOH pellets (26 mmol) and aqueous NH3 (25%, 0.425 mol) were added to the solution and was stirred at room temperature for 8 h. An off-white solid formed which was collected by filtration, followed by washings with H2O (3 x 10 mL) and EtOH (2 x 5 mL). Crystallization from CHCl3-MeOH system gives a white crystalline solid. The proposed reaction is shown in Scheme 1.
With ammonia; potassium hydroxide; In ethanol; water; at 20.0℃; for 8h;Inert atmosphere; General procedure: All tridentate ligands were synthesized similarly by followingliterature procedure [31]. 2-Acetyl pyridine (20.0 mmol) wasadded to an ethanolic solution of various aldehydes (10.0 mmolin 70 mL EtOH). KOH pellets (26 mmol) and aqueous NH3 (25%,0.425 mol) were added to the solution and was stirred at roomtemperature for 8 h. An off-white solid formed which was collectedby filtration, followed by washings with H2O (3 10 mL) and EtOH(2 5 mL). Crystallization from CHCl3-MeOH system gives a whitecrystalline solid. The proposed reaction is shown in Scheme 1.
  • 2
  • [ 209901-86-0 ]
  • ammonium hexafluorophosphate [ No CAS ]
  • ruthenium(III) chloride trihydrate [ No CAS ]
  • [Ru(4'-(4-fluorophenyl)-2,2':6',2''-terpyridine)2][PF6]2 [ No CAS ]
  • 3
  • [ 209901-86-0 ]
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 42120-27-4 ]
  • [Fe(4'-(4-fluorophenyl)-2,2':6',2''-terpyridine)2][PF6]2 [ No CAS ]
  • 4
  • [ 209901-86-0 ]
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 6147-53-1 ]
  • [Co(4'-(4-fluorophenyl)-2,2':6',2''-terpyridine)2][PF6]2 [ No CAS ]
  • 5
  • [ 209901-86-0 ]
  • copper(II) choride dihydrate [ No CAS ]
  • [ 85721-33-1 ]
  • [ 1259925-93-3 ]
  • 6
  • [ 209901-86-0 ]
  • [ 871132-66-0 ]
  • (μ-H)(μ,η3-4'-(p-C6H4)(2,2':6',2''-terpyridine))Os3(CO)9 [ No CAS ]
  • (μ-H)(μ,η2-4'-(p-C6H4)(2,2':6',2''-terpyridine))Os3(CO)10 [ No CAS ]
  • 7
  • [ 209901-86-0 ]
  • copper(II) choride dihydrate [ No CAS ]
  • [ 70458-96-7 ]
  • [ 1356397-58-4 ]
  • 8
  • [ 209901-86-0 ]
  • copper(II) choride dihydrate [ No CAS ]
  • [ 110871-86-8 ]
  • C40H35ClCuF3N7O3 [ No CAS ]
  • 9
  • [ 209901-86-0 ]
  • [ 130-26-7 ]
  • copper(II) choride dihydrate [ No CAS ]
  • C30H18Cl2CuFIN4O*H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium methylate; In methanol; ethanol; for 2h;pH Ca. 6.8;Reflux; Inert atmosphere; Ethanolic solution of CuCl2*2H2O (1.5 mmol) was added to a ethanolic solution of 40-substituted-2,20:60,20 0-terpyridine (L1-3)(1.5 mmol), followed by the addition of a previously prepared methanolic solution of clioquinol (1.5 mmol) in presence of CH3-ONa (1.5 mmol). The pH of the reaction mixture was adjusted to 6.8. The resulting solution was refluxed for 2 h on a water bath, followed by concentrating to half of its volume. A fine, dark brown amorphous product obtained was washed with ether/hexane and dried in vacuum desiccators in Scheme 2. Physical properties and analytical data of copper(II) complexes with clioquinol and terpyridines in Table 1.
  • 10
  • [ 209901-86-0 ]
  • ruthenium trichloride [ No CAS ]
  • C21H14Cl3FN3Ru [ No CAS ]
YieldReaction ConditionsOperation in experiment
35.24% In methanol; for 3h;Reflux; Inert atmosphere; p-F-tpy (1.2 g, 3.67 mmol) and RuCl3 (0.95 g, 3.67 mmol) were dissolved in 20 ml dry methanol and heated to reflux under N2 for 3 h. The resulting deep brown solution was allowed to cool at room temperature, after which the solution was cooled in an ice bath for 0.5 h. The brown solid that formed was collected by vacuum filtration and washed with cold methanol until the filtrate was colorless, and then it was washed with Et2O and air dried. The product (yield: 0.691 g, 35.24%) was used without further purification.
  • 11
  • [ 209901-86-0 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • C42H28F2N6Zn(2+)*2NO3(1-) [ No CAS ]
  • 12
  • [ 209901-86-0 ]
  • [ 41756-81-4 ]
  • C39H29Cl2FN3PRu [ No CAS ]
  • 13
  • [ 209901-86-0 ]
  • sodium hexaflorophosphate [ No CAS ]
  • [ 41756-81-4 ]
  • C57H44ClFN3P2Ru(1+)*F6P(1-) [ No CAS ]
  • 14
  • [ 209901-86-0 ]
  • europium(III) nitrate hexahydrate [ No CAS ]
  • nitrate [ No CAS ]
  • 15
  • [ 209901-86-0 ]
  • terbium(III) nitrate hexahydrate [ No CAS ]
  • [Tb(III)(4′-p-fluorophenyl-2,2′:6′,2′′-terpyridine)(NO3)3] [ No CAS ]
  • 16
  • [ 209901-86-0 ]
  • iridium(III) chloride trihydrate [ No CAS ]
  • C21H14Cl3FIrN3 [ No CAS ]
  • 17
  • [ 209901-86-0 ]
  • sodium hexaflorophosphate [ No CAS ]
  • [ 41756-81-4 ]
  • C57H44ClFN3P2Ru(1+)*F6P(1-) [ No CAS ]
  • 18
  • [ 209901-86-0 ]
  • ruthenium(III) chloride hexahydrate [ No CAS ]
  • C21H14Cl3FN3Ru [ No CAS ]
  • 19
  • [ 209901-86-0 ]
  • [ 10108-64-2 ]
  • C21H14CdCl2FN3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% In water; at 120.0℃; for 48h;Autoclave; General procedure: For complexes 1b, 1c, 1e, and 2a-2c, the dichloromethane solutions of the corresponding ligands were added dropwise to methanol solutions of CdCl2 and the system was stirred for 24h. The powders of the compounds were separated from the mother solution by filtration and dried in a desiccator. For 1d and 1f, a mixture of CdCl2, corresponding ligands and distilled water was sealed in a stainless reactor with a Teflon liner and heated at 120C for two days to obtain the crystals of 1d and 1f.
  • 20
  • [ 209901-86-0 ]
  • copper dichloride [ No CAS ]
  • [CuCl2(4'-(4-fluorophenyl)-2,2':6',2''-terpyridine)] [ No CAS ]
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