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CAS No. : | 2132-80-1 | MDL No. : | MFCD00008402 |
Formula : | C14H14O2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | UIMPAOAAAYDUKQ-UHFFFAOYSA-N |
M.W : | 214.26 | Pubchem ID : | 16484 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 8% 2: 10% 3: 86% | With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 22h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 8% 2: 98% | With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 22h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 86% 2: 8% 3: 10% | With lithium chloride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 22h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 98% 2: 7% | With lithium chloride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 22h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 98% 2: 8% | With lithium chloride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 22h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | With triphenyl-arsane In 1-methyl-pyrrolidin-2-one at 20℃; for 89h; | |
68% | With tris(dibenzylideneacetone)dipalladium (0); triphenyl-arsane In 1-methyl-pyrrolidin-2-one at 20℃; for 89h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 66% 2: 21 % Chromat. | Stage #1: Allyl acetate With indium(III) chloride; N,N-dimethylbutylamine; lithium chloride In N,N-dimethyl-formamide at 35℃; Stage #2: para-iodoanisole In N,N-dimethyl-formamide at 100℃; | |
1: 66% 2: 21 % Chromat. | With indium(III) chloride; indium; N,N-dimethylbutylamine In N,N-dimethyl-formamide at 100℃; for 11h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
36% | With copper(l) iodide; cesium fluoride; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 140℃; for 281h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With sodium hydroxide at 60℃; for 6h; | |
80% | With tetrabutyl ammonium fluoride; tris-(o-tolyl)phosphine at 80℃; for 1h; | |
77% | With N-methyliminodiacetic acid; sodium fluoride; potassium hydroxide; palladium dichloride In water; isopropyl alcohol at 80℃; for 12h; |
68% | With 1,4-diaza-bicyclo[2.2.2]octane; tetrabutyl ammonium fluoride In 1,4-dioxane at 80℃; for 4h; | |
65% | With dichlorobis(dibenzyl diisopropylphosphoramidite)palladium(II); sodium hydroxide In water at 100℃; for 2h; | 3.3. General Procedure for the Synthesis General procedure: A mixture of aryl bromide (1.0 mmol), arylsilane (1.2 mmol), NaOH (3.0 mmol), 4.0 mL solvent,PEG:H2O = 1:1 (volume ratio) and catalyst (0.02 mmol) was stirred at 80-100 C for 2 h underair. The reaction was quenched with brine (15 mL) and extracted three times with ethyl acetate(3 10 mL). The organic phase was dried with MgSO4 for 4 h, filtered and concentrated under reducedpressure using a rotary evaporator. The crude products were re-crystallized by dichloromethane(2 mL) at 10 C for 24 h. Filtered and dried, the purified products were identified by 1H-NMR and13C-NMR spectroscopy. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 85% 2: 10 % Chromat. | With triphenylphosphine In tetrahydrofuran for 48h; Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | With caesium carbonate; triphenylphosphine In N,N-dimethyl acetamide at 90℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | With caesium carbonate; triphenylphosphine In N,N-dimethyl acetamide at 90℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
63% | With tetrabutylammomium bromide; caesium carbonate; triphenylphosphine In N,N-dimethyl acetamide at 90℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | With tetrabutylammomium bromide; caesium carbonate; triphenylphosphine In N,N-dimethyl acetamide at 90℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | With caesium carbonate; triphenylphosphine In N,N-dimethyl acetamide at 90℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | With potassium phosphate;(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In 1,4-dioxane; at 110℃; for 18h;Product distribution / selectivity; | A Schlenk tube was charged with aryl halide (0.67 mmol, 1.0 equiv), aryl boronate ester (0.81 mmol, 1.2 equiv), potassium phosphate or CsF (3.0 equiv), Pd catalyst (0.1 equiv), 2-(dicyclohexylphosphino)biphenyl (0.2 equiv) (co-ligand was used in the presence of Pd(OAc)2 as catalyst and CsF as base (see Table 8, entries 13-15); reaction was performed at rt) and a Teflon coated stirbar. The reaction mixture was evacuated three times for ten minutes under high vacuum and backfilled with N2. Dry dioxane was added via the T-neck and the reaction mixture was heated to 110 0C for 18 h. The reaction mixture was cooled to room <n="24"/>temperature and diluted with DCM (10 rnL). The solution was filtered and the filtrated washed with DCM (100 mL). The filtrate was concentrated and purified by silica gel chromatography. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95% | With potassium phosphate;bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine; In tetrahydrofuran; at 20 - 25℃; for 8 - 12h;Product distribution / selectivity; | In a glove box with N2 atmosphere, a Schlenk tube was charged with aryl halide, tosylate or mesylate (1.0 equiv), aryl neopentylglycolboronate (1.5 equiv), potassium phosphate (0.9 mmol, 3.0 equiv), Ni(COD)2 (0.018 mmol, 0.06 equiv), tricyclohexylphosphine (0.11 mmol, 0.18 equiv), and a Teflon coated stirbar. Dry THF (2 ml) was added and reaction was left stirring for 8 h at rt. The reaction mixture was diluted with DCM (10 mL) and filtered. The filtrated solid was washed with DCM (100 mL) and the organic solvent concentrated. The coupling products were precipitated in MeOH and the white crystals were filtrated and washed with cold MeOH. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
94% | With potassium phosphate;bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine; In tetrahydrofuran; at 20 - 25℃; for 8 - 12h;Product distribution / selectivity; | In a glove box with N2 atmosphere, a Schlenk tube was charged with aryl halide, tosylate or mesylate (1.0 equiv), aryl neopentylglycolboronate (1.5 equiv), potassium phosphate (0.9 mmol, 3.0 equiv), Ni(COD)2 (0.018 mmol, 0.06 equiv), tricyclohexylphosphine (0.11 mmol, 0.18 equiv), and a Teflon coated stirbar. Dry THF (2 ml) was added and reaction was left stirring for 8 h at rt. The reaction mixture was diluted with DCM (10 mL) and filtered. The filtrated solid was washed with DCM (100 mL) and the organic solvent concentrated. The coupling products were precipitated in MeOH and the white crystals were filtrated and washed with cold MeOH. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 55% 2: 32 %Chromat. 3: 20 %Chromat. | With palladium diacetate; potassium carbonate In butanone at 120℃; for 12h; Inert atmosphere; | |
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 140℃; for 6h; Overall yield = 74 percent; | 2.2. Typical procedure for the Ullmann coupling reaction General procedure: To a 15 mL reaction tube, ArI (1 mmol), (i-Pr)2NEt (2 mmol),DMF (0.5 mL) and 5 mg of PdCl2/PANI were added. The reactionmixture was stirred at 140 °C under air for 2.5 h. After the reaction,the catalyst was isolated by centrifugalization, washed by deionized water and ethanol, vacuum dried at 60 °C and then reused in the next round of reaction. Organic phase was collected, add saturatedsalt water (2 mL), extracted with ethyl acetate (15 mL), thenthe organic phase was dried with anhydrous Na2SO4. The productwas separated and purified by silica gel column chromatography(eluent: petroleum ether). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 70% 2: 64% 3: 10% | Stage #1: 1-bromo-4-methoxy-benzene; p-trifluoromethylphenyl bromide With magnesium In tetrahydrofuran at 20℃; for 2h; Stage #2: With synthetic air; cobalt(II) chloride In tetrahydrofuran at 0℃; for 0.5h; | |
1: 17% 2: 50% 3: 63% | Stage #1: 1-bromo-4-methoxy-benzene; p-trifluoromethylphenyl bromide With magnesium In tetrahydrofuran at 20℃; for 2h; Stage #2: With synthetic air; cobalt(II) chloride In tetrahydrofuran at 0℃; for 0.5h; | |
1: 27% 2: 39% 3: 35% | Stage #1: 1-bromo-4-methoxy-benzene; p-trifluoromethylphenyl bromide With magnesium In tetrahydrofuran at 20℃; for 2h; Stage #2: With synthetic air; cobalt(II) chloride In tetrahydrofuran at 0℃; for 0.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 90℃; for 2h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 34% 2: 26% | With copper(l) iodide; palladium diacetate In isopropyl alcohol at 25℃; for 48h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
6%; 46%; 12%; 59% | With palladium diacetate; caesium carbonate; In N,N-dimethyl-formamide; at 120℃; for 0.5h;Inert atmosphere; | General procedure: A stirred mixture of bromobenzene (471 mg, 3.0 mmol), <strong>[872-36-6]vinylene carbonate</strong> (86 mg, 1.0 mmol), Pd(OAc)2 (22 mg, 10 mol %), PPh3 (52 mg, 20 mol %), and Cs2CO3 (715 mg, 2.2 mmol) in DMF (1.5 mL) was heated to 120 C for 30 min under nitrogen atmosphere. After aqueous extractive workup and column chromatographic purification process (hexanes/EtOAc, 20:1) benzil was obtained as a pale yellow solid, 170 mg (81% based on <strong>[872-36-6]vinylene carbonate</strong>), along with biphenyl (65 mg, 28% based on bromobenzene) as a white solid. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | With palladium diacetate; caesium carbonate; triphenylphosphine; In 1-methyl-pyrrolidin-2-one; at 90℃; for 1h;Inert atmosphere; | General procedure: In a hot oven-dried Schlenk tube under N2 atmosphere were added Ph3Bi (0.25 mmol, 110 mg, 1.0 equiv), 2-bromobenzofuran (0.825 mmol, 163 mg, 3.3 equiv), Cs2CO3 (0.75 mmol, 244 mg, 3.0 equiv), Pd(OAc)2 (0.025 mmol, 5.6 mg, 0.1 equiv), PPh3 (0.1 mmol, 26 mg, 0.4 equiv), and NMP (3 mL) solvent. The resulting mixture was stirred in preheated oil bath at 90 C for 1 h. After the reaction is over, the mixture was cooled, quenched with dil HCl and extracted with ethyl acetate. The combined organic extract was washed with water, brine, and dried over MgSO4 and concentrated. The crude was subjected to silica gel column chromatography (230-400 mesh) using petroleum ether as the eluent to obtain the pure 2-phenylbenzofuran (2.1) as a white solid (140 mg, 96%). The product was characterized by spectroscopy and in comparison with the literature data. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
14% | With tetrakis(sodium) palladium(II) meso-tetrakis(4-sulfonatophenyl)porphyrin; In water; N,N-dimethyl-formamide; at 20℃; for 3h; | General procedure: To PdTSTpSPP (0.05 mol%) and PATFB (1) (1.10 mmol), 4 mL of deionized waterwas added and the mixture stirred at rt in open-air for the appropriate time (Table 2). Toensure the completion of the reaction by TLC, to the reaction mixture was added 5 mLwater and it was extracted using EtOAc (2 5 mL). The EtOAc combined solution wasdried in vacuo and subjected to silica-gel packed-CC to obtain the pure symmetrical biaryls(6). The products (6) structures were determined by their 1H and 13C NMR and massdata. The characterization data of 6 (Section 3.2) was found to be similar to that of thatreported [27,30,66,67] and the copies of 1H and 13C NMR spectra has been provided asSupplementary Materials with the manuscript. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | With silver fluoride In N,N-dimethyl-formamide at 80℃; for 12h; | |
Multi-step reaction with 2 steps 1: toluene / 3 h / 100 °C 2: palladium diacetate; tetrabutyl ammonium fluoride; XPhos / toluene; tetrahydrofuran / 3 h / 100 °C / Schlenk technique |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91% | With copper diacetate; palladium diacetate; In tetrahydrofuran; N,N-dimethyl acetamide; at 80℃; for 3h; | General procedure: A mixture of the arylsulfonyl hydrazides (0.5 mmol), Pd(OAc)2(3 mol%) and Cu(OAc)2 (0.5 mmol) was stirred in DMA/THF = 1:1(1 mL) at 80 C for 3 h. Afterwards, 1 mL water was added to thereaction solution which was then filtered through a filter paper. Thesolution was extracted by Et2O (1 mL) three times. The organic phasewas combined and evaporated under reduced pressure. The residue waspurified on a SiO2 column, and eluted with mixtures of petrol and ethylacetate to afford the desired product. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine; In tetrahydrofuran; at 23℃; for 2h;Inert atmosphere; Glovebox; Sealed tube; | General procedure: Cross-Coupling of ortho-, meta-, and para-Substituted, Electron-Rich and Electron-Deficient Aryl Halides and Aryl Mesylates with Aryl Neopentylglycolboronates Catalyzed by NiIICl(1-naph-thyl)(PCy3)2/PCy3 in Anhydrous THF at 23 C; General Procedure 2In an oven-dried test tube charged with a Teflon coated stirring barwere added aryl halide or aryl mesylate (0.3 mmol), aryl neopentyl-glycolboronates (0.315 mmol), K3PO4(H2O)3.2 (191.00 ± 1.00 mg, 0.9mmol), and NiIICl(1-naphthyl)(PCy3)2 (11.73 ± 0.0510 mg, 0.015mmol, 5% catalyst loading). The test tube was brought into a N2 filledglove box (moisture level <2 ppm) through three degassing cycles andPCy3 (8.4 mg, 0.03 mmol, 10% loading) ligand was added. Distilled sol-vent (1 mL) was added inside the glove box and the test tube wassealed by a rubber septum and left stirring at 23 C. A sample was tak-en by syringe and transferred outside the glove box. The sample wasdiluted by distilled THF (0.2 mL) and filtered through a short columnof Al2O3. The filtrate was concentrated and the GC analysis was car-ried out. The reaction mixture was diluted with CH2Cl2 (2 mL), filteredthrough a layer of Al2O3, and washed with CH2Cl2 (3 1 mL). The fil-trate was collected and concentrated under vacuum. The crude prod-uct was purified by column chromatography on silica gel with EtO-Ac/hexane mixture as eluent. The reductive elimination side-productwas also isolated and characterized. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 48% 2: 2% 3: 3% | With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In N,N-dimethyl-formamide at 100 - 105℃; for 2.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 51% 2: 28% 3: 18% | With palladium(II) trifluoroacetate; copper diacetate In water at 20℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 76 %Chromat. 2: 21 %Chromat. | With palladium(II) trifluoroacetate; copper diacetate In water at 20℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium phosphate; palladium diacetate; hydrazine hydrate In dimethyl sulfoxide; N,N-dimethyl-formamide at 20℃; for 8h; Green chemistry; Overall yield = 83 %; | ||
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 140℃; for 6h; Overall yield = 74 percent; | 2.2. Typical procedure for the Ullmann coupling reaction General procedure: To a 15 mL reaction tube, ArI (1 mmol), (i-Pr)2NEt (2 mmol),DMF (0.5 mL) and 5 mg of PdCl2/PANI were added. The reactionmixture was stirred at 140 °C under air for 2.5 h. After the reaction,the catalyst was isolated by centrifugalization, washed by deionized water and ethanol, vacuum dried at 60 °C and then reused in the next round of reaction. Organic phase was collected, add saturatedsalt water (2 mL), extracted with ethyl acetate (15 mL), thenthe organic phase was dried with anhydrous Na2SO4. The productwas separated and purified by silica gel column chromatography(eluent: petroleum ether). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90% | With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); caesium carbonate; ruphos; In N,N-dimethyl acetamide; at 90℃; for 6h; | General procedure: Add arylsulfonyl hydrazide (1.0 mmol) to the reaction flask,P-methoxybromobenzene (1.1 mmol),Palladium catalyst Pd (dppp) Cl2 (5mol%),Ligand RuPhos (10mol%),Base Cs2CO3 (1.2mol) andSolvent DMA (2mL), then heated to 90 C for reaction, TLC monitored the progress of the reaction,After 6 hours, 10 mL of water was added, and then extracted three times with dichloromethane, washed with saturated brine, dried over anhydrous sodium sulfate, concentrated to remove the solvent, and then separated by column chromatography.The product biaryl hydrocarbon is obtained, and the reaction formula is as follows: |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 47% 2: 31% | With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In 1,4-dioxane; water at 90℃; for 2h; Sealed tube; Inert atmosphere; | Biphenyl-4,4′-dicarbaldehyde (14a); Typical HC Procedure General procedure: A crimp-cap vial equipped with magnetic stirrer bar wascharged with (dppf)PdCl2·CH2Cl2 (8.2 mg, 0.010 mmol), (4-formylphenyl)boronic acid (2a; 97.9 mg, 0.653 mmol), Na2CO3(69.2 mg, 0.653 mmol), and 2-bromo-1,3-bis(trifluoromethyl)benzene (6; 95.7 mg, 0.327 mmol). The vial was sealedwith a crimp-cap septum and filled with Ar by using threevacuum-purge cycles. Degassed (Ar sparge) 1,4-dioxane (0.70mL) and H2O (0.25 mL) were added, and the vial was immersedin an oil bath at 90 °C for 2 h, then cooled to r.t. H2O was addedand the mixture was extracted with CH2Cl2 (2 × 4 mL). The combinedorganics were mixed with PhCF3 (60.0 L, 0.488 mmol) asan added standard, and an aliquot was diluted in CDCl3 forquantitative 19F NMR spectroscopy. The organics were thendried (Na2SO4) and concentrated in vacuo. Purification by flashchromatography [silica gel, hexanes-EtOAc (0-25%)] gave awhite solid; yield: 53.2 mg (77%); mp 141-143 °C; Rf = 0.26 (25%EtOAc-hexanes). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: 4-chloromethoxybenzene With joYPhos; (x)C17H14O*2Pd In toluene for 0.5h; Schlenk technique; Inert atmosphere; Stage #2: tert.-butyl lithium In toluene at 22℃; for 1h; Schlenk technique; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56%; 10% | With potassium carbonate; In ethanol; at 75℃; for 6h; | General procedure: Aryl halide (2 mmol), K2CO3 (2 mmol, 0.276 g), Cr(CO)6 (1 mmol, 0.22 g) and 3 (2 mol%, 0.08 g) were taken in a round-bottomed flask. To the reaction mixture, EtOH (3 mL) was added and stirred at 75 C in an oil bath for the desired time. After completion of the reaction which was monitored by TLC, the reaction mixture was cooled to room temperature and the catalyst was separated by simple filtration. Afterwards, the filtrate was extracted with water and ethyl acetate. The combined organic fractions were dried over Na2SO4 and concentrated by reduced pressure. The residue was purified by column chromatography on silica gel using n-hexane/ethyl acetate gradient (20/1) to obtain the desired symmetrical diaryl ketones. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
27% | With copper(l) iodide; E-pyridine-2-carbaldehyde 2-pyridylhydrazone; cobalt(II) chloride hexahydrate; potassium carbonate In acetonitrile at 20℃; Irradiation; Overall yield = 73 percent; |
Tags: 2132-80-1 synthesis path| 2132-80-1 SDS| 2132-80-1 COA| 2132-80-1 purity| 2132-80-1 application| 2132-80-1 NMR| 2132-80-1 COA| 2132-80-1 structure
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P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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