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Chemical Structure| 213272-97-0 Chemical Structure| 213272-97-0

Structure of 213272-97-0

Chemical Structure| 213272-97-0

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Product Details of [ 213272-97-0 ]

CAS No. :213272-97-0
Formula : C12H13NO
M.W : 187.24
SMILES Code : CC(NC1=CCCC2=C1C=CC=C2)=O
MDL No. :MFCD08272698

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Application In Synthesis of [ 213272-97-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 213272-97-0 ]

[ 213272-97-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14752-66-0 ]
  • [ 213272-97-0 ]
  • N-(2-((4-chlorophenyl)sulfonyl)-3,4-dihydronaphthalen-1-yl)acetamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With oxygen; nitrobenzene; In water; N,N-dimethyl-formamide; at 20℃; for 21h;Irradiation; General procedure: The 2a (0.6 mmol), UiO-67-Ru (2.0 mg), and nitrobenzene (0.4 mmol) were added to a clear-colored glass vial equipped with a stir bar. Then DMF : H2O (3:1, 2 mL) were added, followed by 1a (0.2 mmol). The reaction was stirred at room temperature under blue LEDs (3 W) for 21 h, until the raw materials completely disappeared by TLC. After the reaction was finished, water was added and the mixtures were extracted with ethyl acetate (20 mL * 4). The combined organic layer was washed with water (10 mL * 3), brine (10 mL * 3), dried over anhydrous Na2SO4. The filtrate was concentrated under reduced pressure. The obtained residue was chromatographed on a silica gel column eluted with PE : DCM : EA = 3:3:1 to afford the desired 3.
 

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