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Chemical Structure| 22515-30-6 Chemical Structure| 22515-30-6

Structure of 22515-30-6

Chemical Structure| 22515-30-6

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Product Details of [ 22515-30-6 ]

CAS No. :22515-30-6
Formula : C11H16O2Si
M.W : 208.33
SMILES Code : O=C(OC)C1=CC=C([Si](C)(C)C)C=C1
MDL No. :MFCD22682799

Safety of [ 22515-30-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 22515-30-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 22515-30-6 ]

[ 22515-30-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 22515-30-6 ]
  • [ 792-74-5 ]
YieldReaction ConditionsOperation in experiment
58.8 mg With tetrakis(acetonitrile)palladium(II) bis(tetrafluoroborate); o-tetrachloroquinone; In chloroform; 1,2-dichloro-ethane; at 60℃; for 10h;Inert atmosphere; General procedure: To a screw-capped glass tube containing a magnetic stirrer bar were addedaryltrimethylsilane 1 (0.30 mmol, 1.0 equiv), Pd(CH3CN)4(BF4)2 (3.3 mg, 0.075 mmol, 2.5molpercent), CHCl3 (1.5 mL) or CHCl3/1,2-dichloroethane (1:4, 1.5 mL) and o-chloranil (55.9 mg, 0.225 mmol, 0.75 equiv) under a stream of nitrogen. After stirring at 60 °C for 10 hours, thereaction mixture was cooled to room temperature, and then passed through a short pad of silicagel (eluent: CHCl3). After the organic solvent was removed under reduced pressure, the residuewas purified by flash column chromatography on silica gel to yield biaryl 2. The reactions wereconducted in 0.50 mmol scale for 1a in 2.5 mL of CHCl3, 0.30 mmol scale for 1b?1t in 1.5 mLof the indicated solvent, and 0.20 mmol scale for 1w in the indicated solvent, respectively.
 

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