Alternatived Products of [ 24133-46-8 ]
Product Details of [ 24133-46-8 ]
CAS No. : | 24133-46-8 |
MDL No. : | MFCD03425725 |
Formula : |
C6H12O3
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
132.16
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 24133-46-8 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 24133-46-8 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 24133-46-8 ]
- 1
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[ 64-17-5 ]
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[ 24133-46-8 ]
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[ 70159-96-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
With sulfuric acid |
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- 2
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[ 135291-86-0 ]
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[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
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With hydrogenchloride |
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- 3
-
[ 13361-35-8 ]
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[ 13259-29-5 ]
-
[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With 2-methyl-propan-1-ol bei nachfolgendem Verseifen des entstandenen Esters mit konz.Kalilauge; |
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- 4
-
[ 24133-46-8 ]
-
[ 140472-28-2 ]
Yield | Reaction Conditions | Operation in experiment |
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With thionyl chloride |
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- 5
-
[ 24133-46-8 ]
-
[ 103860-78-2 ]
Yield | Reaction Conditions | Operation in experiment |
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With thionyl chloride Erhitzen des Reaktionsprodukts mit <i>sec</i>-Butylalkohol; |
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- 6
-
[ 13259-29-5 ]
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[ 79-11-8 ]
-
[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With 2-methyl-propan-1-ol |
|
- 7
-
[ 24133-46-8 ]
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[ 100-63-0 ]
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isobutoxy-acetic acid-(<i>N</i>'-phenyl-hydrazide)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
at 120℃; |
|
- 8
-
[ 24133-46-8 ]
-
[ 56680-72-9 ]
Yield | Reaction Conditions | Operation in experiment |
|
With thionyl chloride |
|
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With thionyl chloride In chloroform at 50℃; |
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Reference:
[1]Basavaiah, D.; Rao, P. Dharma; Gowriswari, V. V. L.
[Synthetic Communications, 1988, vol. 18, # 12, p. 1411 - 1414]
[2]Mounetou, Emmanuelle; Poisson, Claude; Monteil, Andre; Madelmont, Jean-Claude
[Journal of labelled compounds and radiopharmaceuticals, 1998, vol. 41, # 3, p. 181 - 189]
- 9
-
[ 78-83-1 ]
-
[ 105-36-2 ]
-
[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With sodium hydride In tetrahydrofuran |
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- 10
-
[ 78-83-1 ]
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[ 79-11-8 ]
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[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With sodium 2.) reflux; Multistep reaction; |
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- 12
-
[ 7719-09-7 ]
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[ 24133-46-8 ]
-
[ 34180-11-5 ]
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[ 56680-72-9 ]
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[ 140472-28-2 ]
- 13
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[ 24133-46-8 ]
-
[ 56680-72-9 ]
Yield | Reaction Conditions | Operation in experiment |
|
With thionyl chloride at 40 - 55℃; |
|
- 14
-
[ 24133-46-8 ]
-
[ 15268-49-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: SOCl2 / 40 - 55 °C
2: benzene |
|
- 15
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[ 24133-46-8 ]
-
[ 189128-87-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: SOCl2 / 40 - 55 °C |
|
- 16
-
[ 78-83-1 ]
-
[ 3926-62-3 ]
-
[ 24133-46-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With NaH In tetrahydrofuran; hexane; water; dimethyl sulfoxide |
3 2-Methylpropoxyacetic acid STR12
EXAMPLE 3 2-Methylpropoxyacetic acid STR12 Sodium hydride (1.72 g of 60% NaH in oil=1.03 g, 43 mmol) in oil dispersion was washed twice with 10 ml of hexane. THF was added (10 ml) and the mixture was cooled to -15° C. A solution of 2-methyl propanol (2.5 g, 35 mmol) in THF was then added, and the mixture was warmed to 25° C. for 1 hour. The THF was removed by distillation under vacuum and a solution of sodium chloroacetate (5.2 g, 45 mmol) in DMSO (100 ml) was added. The mixture was stirred at room temperature for 20 hours, then diluted with 300 ml. of water. The mixture was extracted twice with 50 ml. of hexane. The agueous phase was acidified with 4 N hydrochloric acid and the product was extracted twice with 100 ml. of ethyl acetate. The combined ethyl acetate layers were washed twice with 100 ml. water, dried over MgSO4, filtered, and the solvent was removed by distillation under reduced pressure to give 4.6g of product as a colorless oil. Yield of product=99.6%. |