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Chemical Structure| 2417-75-6 Chemical Structure| 2417-75-6

Structure of 2417-75-6

Chemical Structure| 2417-75-6

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Product Details of [ 2417-75-6 ]

CAS No. :2417-75-6
Formula : C13H11BrO2
M.W : 279.13
SMILES Code : O=C(OC)C1=C2C=CC=CC2=C(CBr)C=C1
MDL No. :MFCD18414905
InChI Key :NZZLGVIQLWHWCI-UHFFFAOYSA-N
Pubchem ID :10333813

Safety of [ 2417-75-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 2417-75-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2417-75-6 ]

[ 2417-75-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 67-56-1 ]
  • [ 4488-40-8 ]
  • [ 2417-75-6 ]
YieldReaction ConditionsOperation in experiment
Commercially available 4-methyl-1-naphthalene carboxylic acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) (251 mg) was dissolved in methanol (7.5 ml) and then aerated under ice-cooling with hydrogen chloride gas for 5 minutes. After that, the solution was stirred at room temperature for 19 hours and the solvent was then distilled off. The residue was dissolved in chloroform and then washed with a 1 mol/l sodium hydroxide aqueous solution. After the solution had been dried with anhydrous sodium sulfate, the solvent was then distilled off. The residue was dissolved in carbon tetrachloride (8.0 ml) and then added with N-bromo succinimide (253 mg) and azobisisobutyronitrile (22.1 mg), followed by stirring at 70C for 6 hours. After completion of the reaction, the solid was removed through glass filter, followed by concentration. The residue was dissolved in chloroform and then washed with a 1 mol/l sodium hydroxide aqueous solution and saturated saline solution. The solution was dried with anhydrous sodium sulfate and the solvent was then distilled off. The residue was dried under reduced pressure, thereby obtaining the subject compound (364 mg) as a pale-yellow oily substance. MS(FAB,Pos.):m/z=279,281[M+H]+ 1H-NMR(60MHz,CDCl3):delta=3.94(3H,s),4.86(3H,s),7.35-7.68(3H,m),7.88-8.21(2H,m),8.66-8.89(1H,m).
  • 2
  • [ 4488-40-8 ]
  • [ 2417-75-6 ]
 

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