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Type HazMat fee for 500 gram (Estimated)
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Chemical Structure| 2436-90-0 Chemical Structure| 2436-90-0

Structure of 2436-90-0

Chemical Structure| 2436-90-0

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Product Details of [ 2436-90-0 ]

CAS No. :2436-90-0
Formula : C10H18
M.W : 138.25
SMILES Code : C=CC(C)CC/C=C(C)/C
MDL No. :MFCD00137459

Safety of [ 2436-90-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H317-H304-H226-H400-H410-H315
Precautionary Statements:P264-P280-P302+P352-P321-P332+P313-P362-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P391-P501-P273-P391-P501
Class:3
UN#:1993
Packing Group:

Application In Synthesis of [ 2436-90-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 2436-90-0 ]

[ 2436-90-0 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 67403-76-3 ]
  • [ 121-46-0 ]
  • [ 2436-90-0 ]
  • [ 95-11-4 ]
YieldReaction ConditionsOperation in experiment
71% With bis(1,5-cyclooctadiene)nickel (0); dimethylaluminum chloride; bis[2-(diphenylphosphino)phenyl] ether In hexane; benzene at 28℃; for 16 h; Inert atmosphere; Glovebox 69 (82.6 mg, 0.50 mmol), norbornadiene 8 (51 μΙ_, 0.5 mmol) and 1 .0M solution of AIMe2CI in hexane (50 μΙ_, 10.0 molpercent, 0.05 mmol) were added sequentially to a solution of Ni(COD)2 (3.45 mg, 2.5 molpercent, 12.5 μηηοΙ) and DPEphos (6.75 mg, 2.5 ηηο /ο , 12.5 μιτιοΙ) in benzene (1 .0 ml_) prepared in a 4 ml_ Screw-cap vial under an argon atmosphere in a glove box. The vial was taken out of the glove box, the temperature of which was fixed at 28 °C. The reaction mixture was stirred for 16 hours at 28 °C. After that time, the reaction mixture was concentrated under reduced pressure and the residue purified by flash column chromatography on silica gel (100percent pentane) to 70 (49.0 mg, yield: 71 percent). 1H NMR (500 MHz, CDCI3) δ 5.74 - 5.64 (m, 1 H), 5.13 - 5.06 (m, 1 H), 4.99 - 4.88 (m, 2H), 2.12 (p, J = 7.0 Hz, 1 H), 2.01 - 1 .89 (m, 2H), 1 .68 (s, 3H), 1 .60 (s, 3H), 1 .35 - 1 .26 (m, 2H), 0.99 (d, J = 6.9 Hz, 3H); 13C NMR (125 MHz, CDCI3) δ 144.91 , 131 .44, 124.80, 1 12.61 , 37.51 , 36.89, 25.88, 20.30, 17.83
References: [1] Patent: WO2017/93149, 2017, A1, . Location in patent: Page/Page column 28.
 

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