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Chemical Structure| 2499-59-4 Chemical Structure| 2499-59-4

Structure of 2499-59-4

Chemical Structure| 2499-59-4

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Product Details of [ 2499-59-4 ]

CAS No. :2499-59-4
Formula : C11H20O2
M.W : 184.28
SMILES Code : O=C(OCCCCCCCC)C=C
MDL No. :MFCD00048935

Safety of [ 2499-59-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H227
Precautionary Statements:P501-P210-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313-P403+P235

Application In Synthesis of [ 2499-59-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2499-59-4 ]

[ 2499-59-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 381-98-6 ]
  • [ 2499-59-4 ]
  • octyl (2E,4E)-6,6,6-trifluorohexa-2,4-dienoate [ No CAS ]
YieldReaction ConditionsOperation in experiment
39% With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) acetate; In 1-methyl-pyrrolidin-2-one; at 120℃; for 6h;Inert atmosphere; General procedure: Amixture of styrene (6a) (2 mmol, 208 mg), alpha-trifluoromethylacrylic acid (2) (0.5mmol, 70 mg), [Cp*RhCl2]2 (0.005 mmol, 3 mg), AgOAc (1 mmol, 167 mg) and1-methylnaphthalene (ca. 40 mg) as internal standard was stirred in NMP (2.5ml) under argon at 120 C for 6h. Then the reaction mixture was diluted byethyl acetate (30 ml). The organic layer was washed by 1 N HCl (30 ml), water30 (ml), and brine (30 ml) and dried over Na2SO4. After evaporation of thesolvents under vacuum, product 7a (101 mg, 93%) was isolated by columnchromatography on silica gel using hexane/EtOAc/AcOH=90/9/1 (v/v/v) as eluent.
 

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