Alternatived Products of [ 25240-59-9 ]
Alternatived Products of [ 25240-59-9 ]
Product Details of [ 25240-59-9 ]
CAS No. : | 25240-59-9 |
MDL No. : | MFCD15143603 |
Formula : |
C6H13BO3
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | N/A |
M.W : | 143.98 g/mol |
Pubchem ID : | - |
Synonyms : |
|
Application In Synthesis of [ 25240-59-9 ]
- Upstream synthesis route of [ 25240-59-9 ]
- Downstream synthetic route of [ 25240-59-9 ]
- 1
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[ 25240-59-9 ]

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[ 3857-83-8 ]

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[ 256652-04-7 ]
- 2
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[ 25240-59-9 ]

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[ 32578-25-9 ]

-
[ 68716-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
33% |
With triethylamine In 1,4-dioxane Heating; |
|
- 3
-
[ 25240-59-9 ]

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[ 60319-07-5 ]

-
[ 851231-30-6 ]
Yield | Reaction Conditions | Operation in experiment |
93% |
With triethylamine In 1,4-dioxane Heating; |
|
- 4
-
[ 25240-59-9 ]

-
[ 99747-74-7 ]

-
[ 68716-52-9 ]
- 5
-
[ 25240-59-9 ]

-
[ 86364-03-6 ]

-
[ 635305-47-4 ]
- 6
-
[ 25240-59-9 ]

-
[ 108530-10-5 ]

-
[ 190788-61-5 ]
Yield | Reaction Conditions | Operation in experiment |
90% |
With triethylamine In 1,4-dioxane Heating; |
|
- 7
-
[ 25240-59-9 ]

-
[ 79644-40-9 ]

-
[ 356570-53-1 ]
Yield | Reaction Conditions | Operation in experiment |
99% |
With triethylamine In 1,4-dioxane Heating; |
|
- 8
-
[ 25240-59-9 ]

-
[ 154318-75-9 ]

-
[ 214360-66-4 ]
- 9
-
[ 25240-59-9 ]

-
[ 35387-94-1 ]

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2-(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane)-3-methylanisole
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
With pyrographite; triethylamine In acetonitrile Sonication; to a soln. of I-anisole in degassed anhyd. CH3CN, were added Pd-catalyst, triethylamine and B-contg. compd. successively; stirring at 85°C for 2.5 h; cooling to room temp.; activated charcoal was added; the mixt. was sonicated; the mixt. was filtered and filtrate concd. in vac.; not isolated; |
|
- 10
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[ 25015-63-8 ]

-
[ 110-83-8 ]

-
[ 25240-59-9 ]

-
[ 110-82-7 ]

-
[ 10221-56-4 ]

-
[ 87100-15-0 ]

-
[ 141091-37-4 ]
- 11
-
[ 377780-72-8 ]

-
[ 25240-59-9 ]

-
[ 63981-76-0 ]
- 12
-
[ 850567-57-6 ]

-
[ 25240-59-9 ]

-
[ 1447933-56-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1: acetonitrile; ethanol / 12 h / 20 °C
2: dihydrogen peroxide / dimethyl sulfoxide / 20 °C
3: water / dimethyl sulfoxide / 20 °C |
|
- 13
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[ 850567-57-6 ]

-
[ 25240-59-9 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 6 steps
1: dihydrogen peroxide; water / 20 °C
2: toluene / 2 h / Reflux
3: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / acetonitrile / 2 h / 90 °C / Inert atmosphere
4: acetonitrile; ethanol / 12 h / 20 °C
5: dihydrogen peroxide / dimethyl sulfoxide / 20 °C
6: water / dimethyl sulfoxide / 20 °C |
|
|
Multi-step reaction with 7 steps
1: acetonitrile; ethanol / 12 h / 20 °C
2: water-d2; aq. phosphate buffer / 20 °C / pH 8
3: toluene / 2 h / Reflux
4: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / acetonitrile / 2 h / 90 °C / Inert atmosphere
5: acetonitrile; ethanol / 12 h / 20 °C
6: dihydrogen peroxide / dimethyl sulfoxide / 20 °C
7: water / dimethyl sulfoxide / 20 °C |
|
Reference:
[1]Cao, Sheng; Christiansen, Robin; Peng, Xiaohua
[Chemistry - A European Journal, 2013, vol. 19, # 27, p. 9050 - 9058]
[2]Cao, Sheng; Christiansen, Robin; Peng, Xiaohua
[Chemistry - A European Journal, 2013, vol. 19, # 27, p. 9050 - 9058]
- 14
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[ 195062-59-0 ]

-
[ 25240-59-9 ]

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[ 63981-76-0 ]
- 15
-
[ 251-41-2 ]

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[ 25240-59-9 ]

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[ 1004784-50-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
Stage #1: thieno[3,2-b]thiophene With n-butyllithium In tetrahydrofuran at -78℃;
Stage #2: pinacolboronic acid In tetrahydrofuran at -78℃; |
|
Reference:
[1]Lim, Kimin; Ju, Myung Jong; Na, Jongbeom; Choi, Hyeju; Song, Min Young; Kim, Byeonggwan; Song, Kihyung; Yu, Jong-Sung; Kim, Eunkyoung; Ko, Jaejung
[Chemistry - A European Journal, 2013, vol. 19, # 29, p. 9442 - 9446]
- 16
-
[ 302348-51-2 ]

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[ 25240-59-9 ]

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C22H22O6
[ No CAS ]
- 17
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[ 22913-26-4 ]

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[ 25240-59-9 ]

-
[ 1040281-86-4 ]
Yield | Reaction Conditions | Operation in experiment |
|
|
To a mixture of (l,5-cyclooctadiene)(methoxy)iridium(I) dimer (0.264 g, 0.40 mmol) and pinacolborane (4.8 mL, 32.82 mmol) was added 4,4'-di-tert-butyl-2,2'-dipyridyl (218 mg, 0.81 mmol) in hexane (10 mL). N2 was bubbled through the solvent for 5 min, then a solution of <strong>[22913-26-4]methyl 3-thiophenecarboxylate</strong> (3.5 g, 24.62 mmol) in hexane (2 mL) was added. The resulting red solution was stirred for 6 h at 22 C. The solvent was then evaporated and the residue purified by flash column chromatography (silica, heptanes/EtOAc 100/0 to 98/2) to afford impure intermediate 69 (6.09 g), which was used without further purification for the subsequent reaction. |
- 18
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[ 25240-59-9 ]

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[ 5122-94-1 ]

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[ 144432-80-4 ]