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[ CAS No. 26042-63-7 ] {[proInfo.proName]}

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Chemical Structure| 26042-63-7
Chemical Structure| 26042-63-7
Structure of 26042-63-7 * Storage: {[proInfo.prStorage]}
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Product Details of [ 26042-63-7 ]

CAS No. :26042-63-7 MDL No. :MFCD00003415
Formula : AgF6P Boiling Point : -
Linear Structure Formula :- InChI Key :SCQBROMTFBBDHF-UHFFFAOYSA-N
M.W : 252.83 Pubchem ID :168464
Synonyms :

Safety of [ 26042-63-7 ]

Signal Word:Danger Class:8
Precautionary Statements:P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P363-P405-P501 UN#:3260
Hazard Statements:H314 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 26042-63-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 26042-63-7 ]
  • Downstream synthetic route of [ 26042-63-7 ]

[ 26042-63-7 ] Synthesis Path-Upstream   1~3

  • 1
  • [ 26042-63-7 ]
  • [ 2926-29-6 ]
  • [ 811-68-7 ]
YieldReaction ConditionsOperation in experiment
86% at 0 - 20℃; for 12 h; Inert atmosphere Under a nitrogen atmosphere, AgPF6 (25.28 g,100 mmol ) and CF3SO2Na (18.73 g,120 mmol) dissolved in anhydrous acetonitrile (400mL), the reaction solution was cooled to 0°C, followed by the addition of Ph3P (62.95 g, 240 mmol). The reaction solution was returned to room temperature and stirred at room temperature for 12 hours. After the reaction, the reaction solution was filtered through celite, the filtrate was cooled to -20 ° C, and crystals were precipitated. The supernatant was purged to remove most of the triphenylphosphine oxide. The supernatant was removed in vacuo to remove the solvent. The residue was washed thoroughly with ether, vacuum-dried and the residual solid was recrystallized from acetonitrile and toluene to give the product trifluoromethylthio silver (I)(17.97 g, yield 86percent).
Reference: [1] Patent: CN105017110, 2016, B, . Location in patent: Paragraph 0041; 0042
  • 2
  • [ 26042-63-7 ]
  • [ 72914-19-3 ]
  • [ 676525-77-2 ]
Reference: [1] Chemistry - A European Journal, 2013, vol. 19, # 20, p. 6340 - 6349
  • 3
  • [ 26042-63-7 ]
  • [ 72914-19-3 ]
  • [ 676525-77-2 ]
Reference: [1] Journal of Materials Chemistry C, 2018, vol. 6, # 24, p. 6385 - 6397
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