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Chemical Structure| 26321-29-9 Chemical Structure| 26321-29-9

Structure of 26321-29-9

Chemical Structure| 26321-29-9

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Product Details of [ 26321-29-9 ]

CAS No. :26321-29-9
Formula : C14H14O2
M.W : 214.26
SMILES Code : CC1=CC=CC=C1OC2=CC=CC=C2OC

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Application In Synthesis of [ 26321-29-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 26321-29-9 ]

[ 26321-29-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 615-37-2 ]
  • [ 90-05-1 ]
  • [ 26321-29-9 ]
YieldReaction ConditionsOperation in experiment
59% With potassium phosphate; copper(l) iodide; 2-((2-isopropylphenylimino)methyl)phenol; In 1,4-dioxane; at 20 - 101℃; for 24h;Schlenk technique; Inert atmosphere; General procedure: 2-((2-Isopropylphenylimino)methyl)phenol (15mol%), CuI (5mol%), phenol (1.5mmol, 141mg) and K3PO4 (2.0mmol, 425mg) were added to a screw-capped Schlenk tube under argon. The tube was then evacuated and backfilled with argon (three cycles). Iodobenzene (1mmol, 0.11mL) and dry dioxane (0.5mL) were added by syringe at room temperature. The reaction mixture was stirred at needed temperature (101C) for 24h. The reaction mixture was allowed to reach room temperature and then diluted with dichloromethane (10mL). The slurry was filtered, and the filter cake was washed with 10mL of dichloromethane. The solvent was removed in vacuo, and the residue was purified by column chromatography on silica gel to afford the desired product (3aa).
 

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