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Chemical Structure| 26340-58-9 Chemical Structure| 26340-58-9

Structure of 26340-58-9

Chemical Structure| 26340-58-9

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Product Details of [ 26340-58-9 ]

CAS No. :26340-58-9
Formula : C4H5ClO2
M.W : 120.53
SMILES Code : O=C(/C=C/CCl)O
MDL No. :MFCD19228094
InChI Key :TVOMCUWVZVBDBG-OWOJBTEDSA-N
Pubchem ID :6433659

Safety of [ 26340-58-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H290
Precautionary Statements:P501-P260-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 26340-58-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 26340-58-9 ]

[ 26340-58-9 ] Synthesis Path-Downstream   1~13

  • 4
  • [ 56-23-5 ]
  • 3,4-dichloro-butyric acid isobutyl ester [ No CAS ]
  • [ 26340-58-9 ]
  • 7
  • [ 26340-58-9 ]
  • [ 24806-06-2 ]
  • 9
  • [ 10479-85-3 ]
  • diluted NaOH [ No CAS ]
  • [ 26340-58-9 ]
  • 10
  • [ 26340-58-9 ]
  • [ 58081-05-3 ]
  • C8H9ClO4 [ No CAS ]
  • 11
  • [ 26340-58-9 ]
  • [ 19444-84-9 ]
  • C8H9ClO4 [ No CAS ]
  • 12
  • [ 26340-58-9 ]
  • [ 75-65-0 ]
  • 4-chloro-but-2-enoic acid tert-butyl ester [ No CAS ]
  • 13
  • [ 26340-58-9 ]
  • [ 5469-16-9 ]
  • honaucin A [ No CAS ]
YieldReaction ConditionsOperation in experiment
With dicyclohexyl-carbodiimide; Honaucin A is a natural product originally isolated from a cyanobacterium, Leptolyngbya crossbyana, found over growing corals on the Hawaiian coast. Honaucin A and its synthetic derivatives were prepared by previously reported synthetic scheme (Choi et al.,2012). Honaucin A was synthesized by Steglich esterification with N,N-dicyclohexylcarbodiimide between (S)-3-hydroxy-gamma-butyrolactone and <strong>[26340-58-9]4-chlorocrotonic acid</strong>. Hex-honaucin A was also prepared by 1-ethyl-3-(3A was allaminopropyl) carbodiimide hydrochloride from (S)-3-hydroxy-gamma-butyrolactone and (E)-4-chlorohex-2-enoic acid, which was obtained by selenocatalyticallylic chlorination by PhSeCl from (E)-hex-3-enoic acid. Br-H A (Fig. 1A) and I-honaucin A were produced from honaucin A by the treatment at 50 C for 5 days with NaBr and NaI, respectively.
 

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