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[ CAS No. 31645-35-9 ] {[proInfo.proName]}

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Chemical Structure| 31645-35-9
Chemical Structure| 31645-35-9
Structure of 31645-35-9 * Storage: {[proInfo.prStorage]}
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Product Details of [ 31645-35-9 ]

CAS No. :31645-35-9 MDL No. :MFCD00673247
Formula : C19H16O2 Boiling Point : -
Linear Structure Formula :- InChI Key :MJYSISMEPNOHEG-UHFFFAOYSA-N
M.W : 276.33 Pubchem ID :3618754
Synonyms :

Safety of [ 31645-35-9 ]

Signal Word:Danger Class:8
Precautionary Statements:P280-P305+P351+P338-P310 UN#:1759
Hazard Statements:H318 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 31645-35-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 31645-35-9 ]

[ 31645-35-9 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 1468-95-7 ]
  • [ 920-46-7 ]
  • [ 31645-35-9 ]
YieldReaction ConditionsOperation in experiment
98% With triethylamine In dichloromethane at 0 - 20℃;
90% With triethylamine at 20℃; 2.3. Synthesis of Fluorophore-ContainingMethacrylate Monomers (AntMA: 1 andPyMA: 2) 9-Anthracenemethanol (4.5 g; 0.022 mol) was addedto a solution of triethylamine (9.0 mL; 0.065 mol) in250 mL of anhydrous MC. Methacryloyl chloride (6.3 mL;0.065 mol) was added dropwise under stirring at 0 C.The reaction was then conducted at room temperatureovernight, after which the reaction medium was filtered.The solvent was evaporated, and the solid residue waspurified by recrystallization in 95% ethanol at 40 C(yield = 90%). 1H NMR (CDCl3, ppm: 7.45-8.50(m, 9H, aromatic H), 6.20 (s, 2H, CH2O), 6.05 (s, 1H,CH2= C), 5.56 (s, 1H, CH2= C), 1.97 (s, 3H, CH3 .
80% With dmap; triethylamine In dichloromethane at 0℃; for 4.5h; Inert atmosphere;
73% With pyridine; dmap In chloroform at 0 - 20℃; for 4h;
70% With 4-t-butyl-o-xylene; triethylamine In chloroform at 20℃; Cooling with ice;
70% Stage #1: 9-hydroxymethylanthracene With triethylamine In tetrahydrofuran for 0.5h; Cooling with ice; Stage #2: Methacryloyl chloride In tetrahydrofuran at 0 - 20℃;
65% With triethylamine In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Darkness;
42% With pyridine; triethylamine In tetrahydrofuran at 0 - 20℃; for 1h;
In tetrahydrofuran for 0.75h; Heating;

YieldReaction ConditionsOperation in experiment
9-Chlormethylanthracen, 1.) CH2=C(CH3)-COOH, 80-85grad, 2.) CH3CN, (C2H5)3N;
9-Anthryldiazomethan, Methacrylsaeure;
9-Anthryldiazomethan, Methacrylsaeure, in Petrolether, ZT;
9-Anthryl-diazomethan, Methacrylsaeure (S.1263);
aus 9-anthryldiazomethane, methacrylsaeure;

  • 3
  • [ 31645-35-9 ]
  • [ 105944-63-6 ]
  • poly(N-neopentylmethacrylamide-co-9-anthrylmethyl methacrylate) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In toluene at 60℃;
  • 4
  • [ 31645-35-9 ]
  • [ 105944-63-6 ]
  • polymer; monomer(s): neopentylmethacrylamide; 9-anthrylmethyl methacrylate [ No CAS ]
  • 5
  • [ 31645-35-9 ]
  • [ 80-62-6 ]
  • methyl methacrylate - 9-methylanthryl methacrylate copolymer [ No CAS ]
YieldReaction ConditionsOperation in experiment
With dibenzoyl peroxide In toluene at 99.85 - 104.85℃; for 24h;
YieldReaction ConditionsOperation in experiment
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide at 80℃; for 48h; Schlenk technique; Inert atmosphere;
  • 7
  • [ 79-41-4 ]
  • [ 1468-95-7 ]
  • [ 31645-35-9 ]
YieldReaction ConditionsOperation in experiment
70% With dmap; dicyclohexyl-carbodiimide In acetonitrile for 24h; Inert atmosphere;
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