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[ CAS No. 320573-10-2 ] {[proInfo.proName]}

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Chemical Structure| 320573-10-2
Chemical Structure| 320573-10-2
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Product Details of [ 320573-10-2 ]

CAS No. :320573-10-2 MDL No. :MFCD32643321
Formula : C22H24N2Si2 Boiling Point : -
Linear Structure Formula :- InChI Key :RHQJPUDVIJICOH-UHFFFAOYSA-N
M.W : 372.61 Pubchem ID :21573440
Synonyms :

Safety of [ 320573-10-2 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501 UN#:
Hazard Statements:H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 320573-10-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 320573-10-2 ]

[ 320573-10-2 ] Synthesis Path-Downstream   1~35

  • 2
  • [ 320573-10-2 ]
  • {3-ethyl-5-[(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene-κN)(4-iodophenyl)methyl]-2,4-dimethyl-1H-pyrrolato-κN}(difluoro)boron [ No CAS ]
  • C62H58B2F4N6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With sodium hydroxide; copper(l) iodide; N-benzyl-N,N,N-triethylammonium chloride In benzene at 60℃;
  • 4
  • [ 134653-69-3 ]
  • [ 320573-10-2 ]
  • C46H26N8 [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% With sodium hydroxide; copper(l) iodide; N-benzyl-N,N,N-triethylammonium chloride In water; benzene at 60℃;
  • 5
  • 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-(4-iodophenyl)-4-bora-3a,4a-diaza-s-indacene [ No CAS ]
  • [ 320573-10-2 ]
  • 3,8-bis{ethynylphenyl-4'-[4'',4''-difluoro-8''-(1'',3'',5'',7''-tetramethyl-2'',6''-diethyl-4''-bora-3''a,4''a-diaza-s-indacene)]-1,10-phenantroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With sodium hydroxide; tetrakis(triphenylphosphine) palladium(0); N-benzyl-N,N,N-triethylammonium chloride In benzene at 60℃; for 24h;
  • 6
  • [ 576-83-0 ]
  • [ 320573-10-2 ]
  • 2-(2,4,6-trimethyl-phenyl)-3,8-bis-trimethylsilanylethynyl-1,2-dihydro-[1,10]phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Stage #1: 2,4,6-trimethylphenyl bromide With n-butyllithium In diethyl ether; pentane at 0℃; for 1h; Stage #2: 3,8-bis(trimethylsilanylethynyl)-[1,10]phenanthroline In diethyl ether; pentane at 20℃; for 19h;
  • 7
  • [ 320573-10-2 ]
  • [ 850374-64-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h
  • 8
  • [ 320573-10-2 ]
  • [ 850374-66-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h 5.1: 98 percent / aq. KOH / tetrahydrofuran; methanol / 16 h
  • 9
  • [ 320573-10-2 ]
  • [ 850374-68-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 78 percent / aq. KOH / tetrahydrofuran; methanol / 22 h 2: 31 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 24 h / 80 °C
  • 10
  • [ 320573-10-2 ]
  • 2,9-bis-(2,4,6-trimethyl-phenyl)-3,8-bis-trimethylsilanylethynyl-1,2-dihydro-[1,10]phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C
  • 11
  • [ 320573-10-2 ]
  • [ 850374-65-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h
  • 12
  • [ 320573-10-2 ]
  • [ 850374-70-8 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h 5.1: 98 percent / aq. KOH / tetrahydrofuran; methanol / 16 h 6.1: 31 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 18 h / 80 °C
  • 13
  • [ 320573-10-2 ]
  • [ 850374-69-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h 5.1: 98 percent / aq. KOH / tetrahydrofuran; methanol / 16 h 6.1: 36 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 28 h / 80 °C
  • 14
  • [ 320573-10-2 ]
  • [ 850374-72-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 7 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h 5.1: 98 percent / aq. KOH / tetrahydrofuran; methanol / 16 h 6.1: 36 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 28 h / 80 °C 7.1: 32 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 24 h / 80 °C
  • 15
  • [ 320573-10-2 ]
  • 3,8-bis{2,3,5,6-tetramethyl-4-([1,10]phenanthrolin-3-ylethynyl)-phenylethynyl}-2,9-bis(2,4,6-trimethylphenyl)-[1,10]phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 7 steps 1.1: n-BuLi / pentane; diethyl ether / 1 h / 0 °C 1.2: pentane; diethyl ether / 19 h / 20 °C 2.1: 896 mg / MnO2 / CH2Cl2 / 3 h 3.1: n-BuLi / hexane; diethyl ether / 3 h / 0 °C 3.2: hexane; diethyl ether / 48 h / 20 °C 4.1: 2.29 g / MnO2 / CH2Cl2 / 2 h 5.1: 98 percent / aq. KOH / tetrahydrofuran; methanol / 16 h 6.1: 36 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 28 h / 80 °C 7.1: 28 percent / Et3N; CuI / [PdCl2(PPh3)2] / benzene / 24 h / 80 °C
  • 16
  • [ 66-71-7 ]
  • [ 320573-10-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 57 percent / sulfur monochloride; bromine; pyridine / various solvent(s) / 13 h / Heating 2: 100 percent / diisopropylethylamine; CuI / PdCl2(PPh3)2 / benzene / 40 h / 95 °C
  • 17
  • [ 320573-10-2 ]
  • 3,8-bis-(4-ethynyl(thioacetal)benzene)-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 67 percent / TBAF / tetrahydrofuran / 0.33 h 2: 21 percent / diisopropylethylamine; CuI / Pd(PPh3)2Cl2 / tetrahydrofuran / 24 h / 90 °C
Multi-step reaction with 2 steps 1: alkali metal carbonate / methanol 2: copper(l) iodide; bis(dibenzylideneacetone)-palladium(0); triphenylphosphine; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 72 h / 60 °C / Inert atmosphere
Multi-step reaction with 2 steps 1: potassium carbonate; methanol / 1 h / 20 °C 2: copper(l) iodide; N-ethyl-N,N-diisopropylamine; bis(dibenzylideneacetone)-palladium(0); triphenylphosphine / tetrahydrofuran / 72 h / 60 °C / Inert atmosphere
  • 18
  • [ 320573-10-2 ]
  • C46H26N8 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 92 percent / KF / methanol / 20 °C 2: 15 percent / iPr2NH / Pd(PPh3)4 / benzene / 80 °C
  • 19
  • [ 320573-10-2 ]
  • 3,8-bis-pyren-1-ylethynyl-[1,10]phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 92 percent / KF / methanol / 20 °C 2: 20 percent / iPr2NH / Pd(PPh3)4 / benzene / 80 °C
  • 20
  • [ 320573-10-2 ]
  • 3,8-bis[2-(4-pyridinyl)ethynyl]-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 95 percent / K2CO3 / methanol / 20 °C 2: 85 percent / Et3N; Pd(PPh3)4; CuI / tetrahydrofuran / 6 h / 60 °C
Multi-step reaction with 2 steps 1: alkali metal carbonate / methanol 2: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 48 h / 60 °C
Multi-step reaction with 2 steps 1: potassium carbonate; methanol / 1 h / 20 °C 2: copper(l) iodide; N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 48 h / 60 °C
  • 21
  • ammonium hexafluorophosphate [ No CAS ]
  • cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate [ No CAS ]
  • [ 320573-10-2 ]
  • bis(2,2'-bipyridine)(3,8-bis(trimethylsilylethynyl)-1,10-phenanthroline)ruthenium(II) hexafluorophosphate [ No CAS ]
YieldReaction ConditionsOperation in experiment
70% In methanol; ethanol under Ar, Schlenk technique; mixt. of Ru-complex and phenanthroline deriv. in EtOH refluxed for 12 h, cooled to room temp., soln. of NH4PF6 in MeOH added, mixt. stirred for 30 min; evapn. to dryness under vac., residue extd. with CH2Cl2, column chromy. (alumina, CH2Cl2/MeOH (100/1); elem. anal.;
  • 22
  • [ 957127-57-0 ]
  • [ 320573-10-2 ]
  • 3,8-bis(Pt(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine)(ethynyl))-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% With KF In methanol; dichloromethane under Ar, Schlenk technique; mixt. of Pt-complex, phenanthroline deriv.,CuI, and KF in CH2Cl2/MeOH (2/1) refluxed for 1 d, cooled to room temp.; evapd. to dryness under vac., column chromy. (alumina, CH2Cl2/MeOH (100/1); elem. anal.;
  • 23
  • [ 14099-01-5 ]
  • [ 320573-10-2 ]
  • [ 1015231-29-4 ]
YieldReaction ConditionsOperation in experiment
72% In toluene under Ar, Schlenk technique; mixt. of Re-complex and phenanthroline deriv. in toluene refluxed for 8 h, cooled to room temp.; solid filtered off, washed with hexane and ether, dried under vac.; elem. anal.;
  • 24
  • [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 [ No CAS ]
  • [ 320573-10-2 ]
  • [ 1260638-58-1 ]
YieldReaction ConditionsOperation in experiment
46% In methanol; dichloromethane stoich. mixt. in CH2Cl2/MeOH (2/1, v/v), refluxed;
  • 25
  • [ 320573-10-2 ]
  • C64H50CuN4O7S2(1+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: alkali metal carbonate / methanol 2.1: copper(l) iodide; bis(dibenzylideneacetone)-palladium(0); triphenylphosphine; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 72 h / 60 °C / Inert atmosphere 3.1: dichloromethane; acetonitrile / 0.5 h / Inert atmosphere 3.2: 3 h / Inert atmosphere
  • 26
  • [ 320573-10-2 ]
  • C58H44CuN6O5(1+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: alkali metal carbonate / methanol 2.1: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 48 h / 60 °C 3.1: dichloromethane; acetonitrile / 0.5 h / Inert atmosphere 3.2: 3 h / Inert atmosphere
  • 27
  • [ 64443-05-6 ]
  • [ 320573-10-2 ]
  • F6P(1-)*C44H48CuN4Si4(1+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
79% In dichloromethane; acetonitrile for 1h; Inert atmosphere;
  • 28
  • [ 17084-13-8 ]
  • [ 1628644-40-5 ]
  • [ 6046-93-1 ]
  • [ 320573-10-2 ]
  • C49H61CuN5O4Si2(2+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% Stage #1: C27H37N3O4; copper(II) acetate monohydrate; 3,8-bis(trimethylsilanylethynyl)-[1,10]phenanthroline In methanol for 1h; Stage #2: potassium hexafluorophosphate In methanol
  • 29
  • [ 320573-10-2 ]
  • [ 189190-29-2 ]
  • C42H22N4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
33% With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 72h; Inert atmosphere;
  • 30
  • [ 66228-76-0 ]
  • [ 320573-10-2 ]
  • [ 1612886-54-0 ]
YieldReaction ConditionsOperation in experiment
50% With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 60℃; for 96h; Inert atmosphere;
  • 31
  • cis-dichlorobis(dimethyl sulfoxide)platinum(II) [ No CAS ]
  • [ 320573-10-2 ]
  • C22H24Cl2N2PtSi2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
84% In dichloromethane at 30℃; for 16h; Inert atmosphere; 2.3. Preparation of Pt(3,8-Phen≡TMS)Cl2 Platinum complex Pt(DMSO)Cl2 (422 mg, 1.0 mmol) was dissolvedin dry CH2Cl2 (100 ml). The solution was added 3,8-Phen≡TMS (327 mg, 1.0 mmol) and stirred at 30C for 16 h. Thesolution was added CH3CN (20 ml) and CH2Cl2 was removed byreduced pressure. The precipitate in CH3CN was filtered throughfilter paper and the pale orange powder was obtained. The powderwas dried at 60C under vacuum for 3 h. Yield: 536 mg (84%).FT-IR (KBr, cm1) n(Phen-C≡C): 2159, n(-CH3): 2852, 2923, 2961. UV/VIS (CH2Cl2): labs nm (ε 105), 287 (0.46), 328 (0.31), 362(0.28), 420 (0.03). 1H NMR (CD3Cl, 400 MHz, ppm): d 9.85 (d,J 1.6 Hz, 2H, Phen-H2 and H9), 8.63 (d, J 1.6 Hz, 2H, Phen-H4and H7), 7.95 (s, 2H, Phen-H5 and H6), 0.34 (s, 18H, ≡TMS).
  • 32
  • [ 320573-10-2 ]
  • C40H44N2O6Si2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: n-butyllithium / diethyl ether; hexane / 6 h / 0 - 20 °C / Inert atmosphere 1.2: 12 h / 20 °C / Inert atmosphere 1.3: 3 h / 20 °C 2.1: n-butyllithium / diethyl ether; hexane / 6 h / 0 - 20 °C / Inert atmosphere 2.2: 12 h / 20 °C / Inert atmosphere 2.3: 3 h / 20 °C
  • 33
  • [ 320573-10-2 ]
  • 3,8-diethynyl-2,9-bis(2,4,6-trimethoxyphenyl)-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: n-butyllithium / diethyl ether; hexane / 6 h / 0 - 20 °C / Inert atmosphere 1.2: 12 h / 20 °C / Inert atmosphere 1.3: 3 h / 20 °C 2.1: n-butyllithium / diethyl ether; hexane / 6 h / 0 - 20 °C / Inert atmosphere 2.2: 12 h / 20 °C / Inert atmosphere 2.3: 3 h / 20 °C 3.1: potassium carbonate; methanol / tetrahydrofuran; water / 3 h / 20 °C
  • 34
  • [ 1131-40-4 ]
  • [ 320573-10-2 ]
  • C31H34N2O3Si2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
80% Stage #1: 2-bromo-1,3,5-trimethoxybenzene With n-butyllithium In diethyl ether; hexane at 0 - 20℃; for 6h; Inert atmosphere; Stage #2: 3,8-bis(trimethylsilanylethynyl)-[1,10]phenanthroline In diethyl ether; hexane at 20℃; for 12h; Inert atmosphere; Stage #3: With manganese(IV) oxide In dichloromethane at 20℃; for 3h;
  • 35
  • dimethyl sulfoxide platinum chloride [ No CAS ]
  • [ 320573-10-2 ]
  • [3,8-bis-(trimethylsilylethynyl)-1,10-phenanthroline]platinum dichloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% In acetonitrile at 50℃; for 24h; 1-3 [3,8-Bis-(trimethylsilylethynyl)-1,10-phenanthroline] platinum dichloride preparation: Weigh 3,8-bis-(trimethylsilylethynyl)-1,10-phenanthroline (37mg, 0.1mmol),Dimethyl sulfoxide platinum chloride (42mg, 0.1mmol) and 100mL reaction flask,Add 20 mL of anhydrous acetonitrile, and heat the reaction at 50°C for 24 hours. Drain the reaction solution,The product was extracted with dichloromethane and separated on a silica gel column with a yield of 85%.
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