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Chemical Structure| 320575-24-4 Chemical Structure| 320575-24-4

Structure of 320575-24-4

Chemical Structure| 320575-24-4

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Product Details of [ 320575-24-4 ]

CAS No. :320575-24-4
Formula : C27H29NO
M.W : 383.53
SMILES Code : O=CC1=CC=C(N2C3=C(C4=C2C=CC(C(C)(C)C)=C4)C=C(C(C)(C)C)C=C3)C=C1

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Application In Synthesis of [ 320575-24-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 320575-24-4 ]

[ 320575-24-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 255829-30-2 ]
  • [ 320575-24-4 ]
  • (E)-N,1-bis(4-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)methanimine [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% With trifluoroacetic acid; In ethanol; for 3h;Reflux; Compounds 5 (0.37g, 1.0mmol) and 6 (0.38g, 1.0mmol) were first dispersed in ethanol (20mL). Two drops of trifluoroacetic acid were added and the mixture was refluxed for 3h. Then, the mixture was cooled to room temperature and filtered to afford TPMA (0.65g) as a yellowish powder: Yield: 90%. m.p. >300C. 1H NMR (400MHz, C6D4Cl2) δ (ppm) 8.80 (s, 1H), 8.48 (d, J=9.7Hz, 4H), 8.40 (d, J=8.0Hz, 2H), 7.89 (d, J=7.8Hz, 2H), 7.82 (d, J=8.1Hz, 2H), 7.76 (d, J=8.0Hz, 2H), 7.74-7.67 (m, 8H), 1.68 (s, 36H) (See Fig.S20). 13C NMR (100MHz, C6D4Cl2) δ (ppm) 134.21, 133.27, 132.93, 132.18, 131.57, 131.47, 131.03, 130.84, 130.58, 129.60, 129.38, 129.13, 128.56, 128.30, 128.05, 127.82, 34.76, 32.14, 32.10, 32.04, 25.91 (See Fig.S21). FT-IR (KBr, cm-1): 2961, 1632, 1606, 1508, 1469, 1368, 1328, 1295, 1262, 1240, 1191, 1164, 1105, 1038, 877, 844, 811, 609. MS, m/z: calc.: 735.5, found: 736.9 [M+H]+ (See Fig.S22).
 

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