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Chemical Structure| 32585-06-1 Chemical Structure| 32585-06-1

Structure of 32585-06-1

Chemical Structure| 32585-06-1

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Product Details of [ 32585-06-1 ]

CAS No. :32585-06-1
Formula : C19H39NO
M.W : 297.52
SMILES Code : O=CNCCCCCCCCCCCCCCCCCC
MDL No. :MFCD00093807

Safety of [ 32585-06-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 32585-06-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 32585-06-1 ]

[ 32585-06-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 623-57-4 ]
  • [ 32585-06-1 ]
  • [ 860799-46-8 ]
YieldReaction ConditionsOperation in experiment
6.5 g With triethylamine; In toluene; at 80℃; for 10h; Weighed 15 g of solid triphosgene and 7.0 g of octadecylamine, both were added to a 250 mL three-necked flask, 100 mL of dichloromethane was added, stir for 5min to make it evenly, and then slowly add saturated sodium carbonate solution to the reaction solution becomes clear and there is a clear stratification. After the addition of saturated sodium carbonate solution, so that the solid three phosgene decomposition completely. After the reaction, separated by a 250 mL separatory funnel, discard the water layer, to the organic layer was added anhydrous Na2SO4 to remove water, wax CH2Cl2 with a rotary evaporator to give 10.5 mL of a pale yellow or yellow transparent liquid. In a 250 mL three-necked flask, 1.5 g of 3-dimethylamino-1,2-propanediol, 10 mL of triethylamine, the above-prepared isocyanate and 60 mL of toluene, the temperature rises to 80 °C, reaction for 10 h, after column chromatography, 6.5 g of the intermediate was obtained. The above-obtained intermediate was added to a 50 mL round bottom flask, 7 g (3-iodopropyl)trimethoxysilane and 20 mL of toluene, slowly heated to 120 ° C, reaction 24h. After the reaction, naturally cooled to room temperature, washed with anhydrous ether several times to give 6.3 g of quaternary ammonium salt.
 

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