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Chemical Structure| 32993-05-8 Chemical Structure| 32993-05-8

Structure of 32993-05-8

Chemical Structure| 32993-05-8

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Product Details of [ 32993-05-8 ]

CAS No. :32993-05-8
Formula : C41H35ClP2Ru
M.W : 726.19
SMILES Code : [Cl-][Ru+2]1234([P](C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7)([P](C8=CC=CC=C8)(C9=CC=CC=C9)C%10=CC=CC=C%10)[CH]%11=[CH]1[CH-]2[CH]3=[CH]%114
MDL No. :MFCD00075004

Safety of [ 32993-05-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302+H312+H332-H315-H319-H335
Precautionary Statements:P261-P280-P305+P351+P338

Application In Synthesis of [ 32993-05-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 32993-05-8 ]

[ 32993-05-8 ] Synthesis Path-Downstream   1~5

  • 1
  • [ 32993-05-8 ]
  • [ 71042-55-2 ]
  • {(-)-Norphos}Ru(II)(η5-C5H5)Cl [ No CAS ]
  • 2
  • [ 32993-05-8 ]
  • [ 501-65-5 ]
  • [ 1227476-15-4 ]
  • (η5-C5H5)Ru(phenylazophenyl)(PPh3) [ No CAS ]
  • [ 3469-20-3 ]
  • 3
  • [ 30413-58-2 ]
  • [ 32993-05-8 ]
  • [ 1072161-52-4 ]
  • 4
  • [ 32993-05-8 ]
  • [ 97239-80-0 ]
  • [ 1166399-59-2 ]
  • 5
  • [ 32993-05-8 ]
  • [ 1430837-91-4 ]
  • [ 1430837-97-0 ]
YieldReaction ConditionsOperation in experiment
62% In ethanol; water; for 1.0h;Inert atmosphere; Schlenk technique; Reflux; General procedure: Method A: 102 mg of [Cp(PPh3)2RuCl] (0.14 mmol) was mixed with PTA+C3H6SO3- (39 mg, 0.14 mmol) in 20 mL of ethanol and 2 mL of distilled water. The mixture was refluxed for 1 h. Concentration of the solution to ca. half volume and the addition of diethylether (5 mL) gave [Cp(PPh3)(PTA+C3H6SO3-)RuCl], 7, as a dark yellow solid, which was filtered off and dried with diethyl ether (3 × 2 mL). (50.0% yield).
 

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