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Chemical Structure| 33035-41-5 Chemical Structure| 33035-41-5

Structure of 33035-41-5

Chemical Structure| 33035-41-5

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Product Details of [ 33035-41-5 ]

CAS No. :33035-41-5
Formula : C13H17IO4
M.W : 364.18
SMILES Code : CC1=C(I(OC(C)=O)OC(C)=O)C(C)=CC(C)=C1
MDL No. :MFCD00674196
InChI Key :QFVRYGXAHXDPHE-UHFFFAOYSA-N
Pubchem ID :11824637

Safety of [ 33035-41-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H315-H319-H228
Precautionary Statements:P240-P210-P241-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313
Class:4.1
UN#:1325
Packing Group:

Application In Synthesis of [ 33035-41-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 33035-41-5 ]

[ 33035-41-5 ] Synthesis Path-Downstream   1~5

  • 1
  • [ 33035-41-5 ]
  • [ 151414-76-5 ]
  • (2-(2-propenyloxy)phenyl)(2,4,6-trimethylphenyl)iodonium tetrafluoroborate [ No CAS ]
  • 2
  • [ 33035-41-5 ]
  • [ 80500-27-2 ]
  • 4-methyl-3-nitrophenyl(mesityl)iodonium bromide [ No CAS ]
  • 3
  • [ 158937-25-8 ]
  • [ 33035-41-5 ]
  • mesityl(4'-(pentyloxy)-[1,1'-biphenyl]-4-yl)iodonium tetrafluoroborate [ No CAS ]
YieldReaction ConditionsOperation in experiment
To a 250 mL round-bottom flask equipped with a stir bar was added the indicated arylboronic acid (3.5 mmol) and CH2Cl2 (30 mL). The mixture was cooled to 0 C. BF3*OEt2 (0.48 mL, 3.9 mmol) was added and the mixture was stirred for 10 min. Then a solution of 2-(diacetoxyiodo)mesitylene (1.42 g, 3.9 mmol) in CH2Cl2 (15 mL) was added dropwise to the mixture over 2 min. The reaction was allowed to warm to room temperature and stirred for 2 h. Then saturated aqueous NaBF4 (70 mL) was added with vigorous stirring. After stirring for 45 min, the aqueous layer was extracted with CH2Cl2 (3*40 mL). The combined organic layers were dried over Na2SO4. The solvent was removed in vacuo, then Et2O (20 mL) was added and the mixture was cooled to -20C for at least 30 min. The diaryliodonium tetrafluoroborates was filtered, washed with Et2O and dried under vacuum.
  • 4
  • [ 33035-41-5 ]
  • [ 221037-98-5 ]
  • [ 657-84-1 ]
  • 3-iodophenyl(mesityl)iodonium tosylate [ No CAS ]
  • 5
  • [ 33035-41-5 ]
  • [ 80500-27-2 ]
  • [ 657-84-1 ]
  • 4-methyl-3-nitrophenyl(mesityl)iodonium tosylate [ No CAS ]
 

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